Transition metal complexes of 1-substituted tetrazoline-5-thiones

1967 ◽  
Vol 45 (10) ◽  
pp. 1057-1062 ◽  
Author(s):  
Umesh Agarwala ◽  
V. A. Narayan ◽  
S. K. Dikshit
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Infrared Spectra ◽  
Gravimetric Determination ◽  
Analytical Applications

Transition metal complexes of a number of 1-substituted tetrazoline-5-thiones have been prepared and their infrared spectra examined in the 3 600 – 500 cm−1 region. The analytical applications of 1-substituted tetrazoline-5-thiones for the gravimetric determination of cadmium and palladium have been studied.

scholarly journals Characterization of reactive organometallic species via MicroED

2019 ◽  
Author(s):  
Christopher Jones ◽  
Matthew Asay ◽  
Lee Joon Kim ◽  
Jack Kleinsasser ◽  
Ambarneil Saha ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Cryogenic Cooling ◽  
Structural Determination ◽  
X Ray ◽  
X Ray Crystallography ◽  
Diamagnetic Transition

Here we apply microcrystal electron diffraction (MicroED) to the structural determination of transition metal complexes. We find that the simultaneous use of 300 keV electrons, very low electron doses, and an ultra-sensitive camera allows for the collection of data without cryogenic cooling of the stage. This technique reveals the first crystal structures of the classic zirconocene hydride, colloquially known as “Schwartz’s reagent”, a novel Pd(II) complex not amenable to solution-state NMR or X-ray crystallography, and five other paramagnetic or diamagnetic transition metal complexes.

Configuration Determination of Transition Metal Complexes by Multiple Scattering EXAFS Analysis: A Case Study

2014 ◽  
Vol 228 (10-12) ◽  
Author(s):  
Matthias Bauer
Keyword(s):  
Fine Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Multiple Scattering ◽  
Transition Metal Complexes ◽  
X Ray ◽  
Exafs Analysis ◽  
X Ray Absorption

AbstractA multiple scattering extended X-ray absorption fine structure (EXAFS) analysis of Ti(acac)

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