A CONVENIENT METHOD FOR THE PREPARATION OF OPTICALLY ACTIVE BENZYL-α-d ALCOHOL

1966 ◽  
Vol 44 (21) ◽  
pp. 2591-2593 ◽  
Author(s):  
Saul Wolfe ◽  
Arvi Rauk
Keyword(s):  
Convenient Method ◽  
Optically Active

not available

Studies of the optically active compounds of Anacardiaceae exudates. V. Further investigation of the exudate from Campnosperma auriculata Hook. F

1959 ◽  
Vol 12 (2) ◽  
pp. 224 ◽  
Author(s):  
JA Lamberton
Keyword(s):  
Convenient Method ◽  
Aldol Reaction ◽  
Optically Active ◽  
Improved Method ◽  
Alcoholic Alkali ◽  
Active Compounds ◽  
Hydrogenated Oil ◽  
Alkyl Phenols ◽  
Long Chain

Distillation of the hydrogenated oil from Campnosperma auriculata Hook. f. yields n-pentacosane-2,6-dione (IV), which is formed from (+)-3-hydroxy-3-nonadecylcyclohexanone (II) by a retro-aldol reaction. In alcoholic alkali, IV is recyclized to 3-nona-decylcyclohex-2-enone (III), and on Wolff-Kishner reduction the disemicarbazone of IV yields n-pentacosane. Oxidation of 3-nonadecylcyclohex-2-enone (III) yields 5-ketotetracosanoic acid, which has been synthesized by an improved method. The synthesis of III and of 3-heptadecylcyclohex-2-enone is described and a convenient method is given for the preparation of 3-methylcyclohex-2-enone. Examination of the mixture of phenols obtained by the action of alkali on C. auriculata oil has shown the presence of 3-nonadecyl phenol and a mixture composed predominantly of cis-monoethylenic C,, alkyl phenols. The phenols are admixed with a small amount of certain long-chain quinols which are also present in the original oils. Nonadecylquinol, one component, has been characterized by conversion into nonadecyl-benzoquinone. The exudate from Campnosperma macrophylla Hook. f. (also Malayan) is unlike that from C. auriculata and contains little oil.

A Convenient Method for Synthesis of Optically Active Methylphenidate from N-Methoxycarbonylpiperidine by Utilizing Electrochemical Oxidation and Evans Aldol-type Reaction

Tetrahedron ◽  
2000 ◽  
Vol 56 (38) ◽  
pp. 7411-7422 ◽  
Author(s):  
Yoshihiro Matsumura ◽  
Yasuhisa Kanda ◽  
Kimihiro Shirai ◽  
Osamu Onomura ◽  
Toshihide Maki
Keyword(s):  
Electrochemical Oxidation ◽  
Convenient Method ◽  
Optically Active ◽  
Type Reaction

ChemInform Abstract: A Convenient Method for Synthesis of Optically Active 2,3-Methanopipecolic Acid.

ChemInform ◽  
2010 ◽  
Vol 31 (36) ◽  
pp. no-no
Author(s):  
Yoshihiro Matsumura ◽  
Mayumi Inoue ◽  
Yosuharu Nakamura ◽  
Idi Ludwig Talib ◽  
Toshihide Maki ◽  
...  
Keyword(s):  
Convenient Method ◽  
Optically Active

A convenient method for synthesis of optically active β-hydroxyamines from primary amines through enecarbamates as key intermediates

Tetrahedron ◽  
1997 ◽  
Vol 53 (13) ◽  
pp. 4579-4592 ◽  
Author(s):  
Yoshihiro Matsumura ◽  
Takahiro Ohishi ◽  
Chihiro Sonoda ◽  
Toshihide Maki ◽  
Mitsuaki Watanabe
Keyword(s):  
Convenient Method ◽  
Optically Active ◽  
Primary Amines
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