IONIZATION POTENTIALS OF METHYL-SUBSTITUTED BENZENES AND CYCLOPENTADIENES

1964 ◽  
Vol 42 (10) ◽  
pp. 2256-2261 ◽  
Author(s):  
F. Meyer ◽  
A. G. Harrison
Keyword(s):  
Electron Impact ◽  
Experimental Results ◽  
Ionization Potentials ◽  
Orbital Method ◽  
Substituted Benzenes ◽  
Group Orbital

The ionization potentials of a number of methyl-substituted benzenes and cyclopentadienes have been measured by electron impact. The experimental results are compared to calculations based on a group orbital method.

Multiple ionization of argon by positron impact

1996 ◽  
Vol 74 (7-8) ◽  
pp. 373-375 ◽  
Author(s):  
R. Hippler ◽  
S. Helms ◽  
U. Brinkmann ◽  
J. Deiwiks ◽  
H. Schneider ◽  
...  
Keyword(s):  
Electron Impact ◽  
Cross Sections ◽  
Experimental Results ◽  
Positronium Formation ◽  
Positron Impact ◽  
Single Ionization ◽  
Multiple Ionization

Recent experimental results for the multiple ionization of argon by positron impact have been reanalysed. Absolute cross sections for the double and triple ionization of argon were obtained from measured ratios of double-to-single and triple-to-single ionization, using known cross sections for single ionization and for positronium formation. Distinct differences compared to similar results for electron impact are noted.

scholarly journals The Electron Impact Ionization Cross Sections of Methanol, Ethanol and 1-Propanol

Atoms ◽  
2019 ◽  
Vol 7 (3) ◽  
pp. 60 ◽  
Author(s):  
Yogesh Kumar ◽  
Manoj Kumar ◽  
Sachin Kumar ◽  
Rajeev Kumar
Keyword(s):  
Electron Impact ◽  
Cross Sections ◽  
Impact Ionization ◽  
Experimental Results ◽  
Oscillator Strengths ◽  
Ionization Cross ◽  
Total Ionization ◽  
Plane Wave Born Approximation ◽  
Ionization Cross Sections ◽  
Good Agreement

In the present investigation, the plane-wave Born approximation was employed to calculate the total ionization cross sections by electron impact of methanol, ethanol and 1-propanol from the threshold of ionization to 10 MeV. This method requires continuum generalized oscillator strengths (CGOSs). The two different semi-phenomenological expressions of CGOS, given by Mayol and Salvat and Weizsacker and Williams, along with approximated form of the continuum optical oscillator strength (COOS) by Khare et al. were used. Furthermore, the average of the above two CGOSs was also used. The calculated ionization cross sections were compared to the available previous theoretical results and experimental data. Out of three CGOSs, the present results with the average CGOS were found in good agreement with the available experimental results for all the considered molecules. Collision parameters CRP were also calculated from 0.1 to 100 MeV and the calculations were found to be in excellent agreement with the experimental results of Reike and Prepejchal.

FREE RADICALS BY MASS SPECTROMETRY: X. THE IONIZATION POTENTIALS OF METHYL SUBSTITUTED ALLYL RADICALS

1956 ◽  
Vol 34 (3) ◽  
pp. 345-353 ◽  
Author(s):  
C. A. McDowell ◽  
F. P. Lossing ◽  
I. H. S. Henderson ◽  
J. B. Farmer
Keyword(s):  
Mass Spectrometry ◽  
Free Radicals ◽  
Electron Impact ◽  
Heat Of Formation ◽  
Ionization Potentials ◽  
Bond Dissociation Energies ◽  
Allyl Radical ◽  
Dissociation Energies ◽  
Allyl Halides ◽  
Vertical Ionization Potentials

The vertical ionization potentials of the β- and γ-methyl substituted allyl radicals as measured by electron impact are 8.03 ± 0.05 v. and 7.71 ± 0.05 v, respectively. From appearance potential data the following bond dissociation energies can be derived, assuming the dissociation processes to be free from complications:[Formula: see text]With assumptions about the structure of the ions produced by electron impact from the corresponding butenes the dissociation energies of the C4H7—H bonds in these latter compounds can be estimated, and the heats of formation of the corresponding radicals derived, namely:[Formula: see text]From data on the allyl halides we evaluate the heat of formation of the allyl radical to be:[Formula: see text]

FREE RADICALS BY MASS SPECTROMETRY: VII. THE IONIZATION POTENTIALS OF ETHYL, ISOPROPYL, AND PROPARGYL RADICALS AND THE APPEARANCE POTENTIALS OF THE RADICAL IONS IN SOME DERIVATIVES

1955 ◽  
Vol 33 (5) ◽  
pp. 861-869 ◽  
Author(s):  
J. B. Farmer ◽  
F. P. Lossing
Keyword(s):  
Mass Spectrometry ◽  
Thermal Decomposition ◽  
Free Radicals ◽  
Kinetic Energy ◽  
Electron Impact ◽  
Ionization Potentials ◽  
Bond Dissociation Energies ◽  
Radical Ions ◽  
Dissociation Energies ◽  
Propargyl Radicals

The ionization potentials of ethyl, isopropyl, and propargyl radicals have been measured by electron impact on radicals produced by thermal decomposition of appropriate compounds. The values are:ethyl 8.78±0.05 ev., isopropyl 7.90±0.05 ev., and propargyl 8.25±0.08 ev. From the appearance potentials of these ions in various compounds, the following values of bond dissociation energies were obtained:[Formula: see text][Formula: see text] assuming no kinetic energy of the products.

THE IONIZATION POTENTIALS OF MONOSUBSTITUTED PYRIDINES BY ELECTRON IMPACT

1963 ◽  
Vol 67 (7) ◽  
pp. 1551-1554 ◽  
Author(s):  
Michael R. Basila ◽  
Donald J. Clancy
Keyword(s):  
Electron Impact ◽  
Ionization Potentials

Excitation of the Resonance Lines of Ar by Electrons

1973 ◽  
Vol 51 (9) ◽  
pp. 914-921 ◽  
Author(s):  
J. W. McConkey ◽  
F. G. Donaldson
Keyword(s):  
Energy Range ◽  
Electron Impact ◽  
Oscillator Strength ◽  
Cross Sections ◽  
Experimental Results ◽  
Impact Excitation ◽  
Electron Impact Excitation

'Polarization-free' measurements are presented of the electron impact excitation of the 1048 Å and 1067 Å resonance lines of argon in the energy range 10–2000 eV. Cross sections are made absolute by normalizing to the optical oscillator strength of the 1048 Å line. Cascade is shown to play a major role in the excitation of the 4s levels. Comparison is made with other experimental results and with theory where available.

Total cross section for electron-impact ionization from the ground state of atomic hydrogen using the distorted-wave polarized orbital method

1988 ◽  
Vol 66 (5) ◽  
pp. 399-401 ◽  
Author(s):  
K. K. Mukherjee ◽  
P. S. Mazumdar ◽  
S. Brajamani
Keyword(s):  
Total Cross Section ◽  
Electron Impact ◽  
Cross Section ◽  
Ground State ◽  
Atomic Hydrogen ◽  
Impact Ionization ◽  
Electron Impact Ionization ◽  
Orbital Method ◽  
Present Calculation ◽  
Distorted Wave

The total cross-section for electron-impact ionization from the ground state of atomic hydrogen is studied by using the distorted-wave polarized orbital method. In the present calculation we have taken into account the matrix elements arising from the distorted part of the target wave function. The present results are in good agreement with experimental findings.

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