METALLO-ORGANIC COMPOUNDS CONTAINING METAL–NITROGEN BONDS: PART IV. SOME BIS-(PRIMARY AMINO)-TITANIUM COMPOUNDS

D. C. Bradley; E. G. Torrible

doi:10.1139/v63-017

METALLO-ORGANIC COMPOUNDS CONTAINING METAL–NITROGEN BONDS: PART IV. SOME BIS-(PRIMARY AMINO)-TITANIUM COMPOUNDS

Canadian Journal of Chemistry ◽

10.1139/v63-017 ◽

1963 ◽

Vol 41 (1) ◽

pp. 134-138 ◽

Cited By ~ 37

Author(s):

D. C. Bradley ◽

E. G. Torrible

Keyword(s):

General Formula ◽

Organic Compounds ◽

Primary Amines ◽

Nitrogen Compounds ◽

Soluble Polymers ◽

Tert Butyl ◽

Primary Amino ◽

Butyl Amine ◽

Nitrogen Bonds ◽

Titanium Compounds

The aminolysis reactions involving primary amines with either Ti(NMe2)4 or Ti(NEt2)4 have been studied. The primary amines behave as bifunctional reactants, forming colored, insoluble, non-volatile bis-(primary amino)-titanium compounds Ti(NR)2 which (except for R = C6H5) are highly reactive towards water or alcohols. With n-butylamine, some soluble polymers of the general formula Tix(NBun)2x−2(NEt2)4 were isolated. With tert-butyl-amine the dimers Ti2(NBut)2(NMe2)4 and Ti2(NBut)2(NHBut)2(NMe2)2 were obtained. The structures of these polymeric metal–nitrogen compounds are discussed.

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Reactivity of nitrogen containing organic intermediates in the selective catalytic reduction of NOx with organic compounds: a model study with tert-butyl substituted nitrogen compounds

Applied Catalysis B Environmental ◽

10.1016/s0926-3373(98)00053-8 ◽

1998 ◽

Vol 19 (1) ◽

pp. 9-22 ◽

Cited By ~ 30

Author(s):

Akira Obuchi ◽

Clemens Wögerbauer ◽

René Köppel ◽

Alfons Baiker

Keyword(s):

Selective Catalytic Reduction ◽

Organic Compounds ◽

Catalytic Reduction ◽

Nitrogen Compounds ◽

Tert Butyl ◽

Model Study ◽

Reduction Of Nox

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Structural and Bioactive Studies of Halogenated Constituents from Sponges

Current Medicinal Chemistry ◽

10.2174/0929867325666181112092159 ◽

2020 ◽

Vol 27 (14) ◽

pp. 2335-2360 ◽

Cited By ~ 2

Author(s):

Chao Li ◽

Dayong Shi

Keyword(s):

Microbial Communities ◽

Organic Compounds ◽

Biological Activities ◽

Marine Sponges ◽

Nitrogen Compounds ◽

Halogenated Organic Compounds ◽

Bioactive Natural Products ◽

The Past ◽

Tyrosine Derivatives ◽

Polyunsaturated Lipids

: Marine organisms are abundant sources of bioactive natural products. Among metabolites produced by sponges and their associated microbial communities, halogenated natural compounds accounted for an important part due to their potent biological activities. The present review updates and compiles a total of 258 halogenated organic compounds isolated in the past three decades, especially brominated derivatives derived from 31 genera of marine sponges. These compounds can be classified as the following classes: brominated polyunsaturated lipids, nitrogen compounds, brominated tyrosine derivatives and other halogenated compounds. These substances were listed together with their source organisms, structures and bioactivities. For this purpose, 84 references were consulted.

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Molecular polarizability of organic compounds and their complexes: LV. Molar volume and structure of some nitrogen compounds, their structural analogues, and some sterically hindered systems in solution

Russian Journal of General Chemistry ◽

10.1134/s1070363210110204 ◽

2010 ◽

Vol 80 (11) ◽

pp. 2347-2357 ◽

Cited By ~ 1

Author(s):

S. B. Bulgarevich ◽

M. V. Boiko ◽

M. N. Lyashenko ◽

E. E. Akimova

Keyword(s):

Molar Volume ◽

Organic Compounds ◽

Molecular Polarizability ◽

Nitrogen Compounds ◽

Structural Analogues ◽

Sterically Hindered

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Synthesis, Structural Characterization, and Luminescent Properties of Heteroleptic Bismuth-Organic Compounds

CrystEngComm ◽

10.1039/d1ce01242h ◽

2021 ◽

Author(s):

Alyssa K. Adcock ◽

Alexander C Marwitz ◽

Lulio A. Sanz ◽

Russell Lee Ayscue ◽

Jeffery A. Bertke ◽

...

Keyword(s):

General Formula ◽

Organic Compounds ◽

Structural Characterization ◽

Luminescent Properties

Four heteroleptic bismuth-organic phases bearing 2,2';6',2"-terpyridine (terpy) and 2-thenoyltrifluoroacetone (TTA) of the general formula BiXy(TTA)3-y(terpy), where X = NO3 (2), Cl (3), Br (4), Br2 (5), were synthesized at room...

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A plan for assessing the occurrence and distribution of methyl tert-butyl ether and other volatile organic compounds in drinking water and ambient ground water in the Northeast and Mid-Atlantic regions of the United States

Open-File Report ◽

10.3133/ofr99207 ◽

1999 ◽

Cited By ~ 3

Author(s):

Stephen J. Grady ◽

George D. Casey

Keyword(s):

United States ◽

Drinking Water ◽

Volatile Organic Compounds ◽

Ground Water ◽

Organic Compounds ◽

The United States ◽

Methyl Tert Butyl Ether ◽

Butyl Ether ◽

Tert Butyl ◽

Volatile Organic

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Some applications of polarography for investigation of equlibria in aqueous solutions of organic compounds

Collection of Czechoslovak Chemical Communications ◽

10.1135/cccc2009121 ◽

2009 ◽

Vol 74 (11-12) ◽

pp. 1777-1789 ◽

Cited By ~ 2

Author(s):

Petr Zuman

Keyword(s):

Aqueous Solutions ◽

Organic Compounds ◽

Carbonyl Compounds ◽

Limiting Current ◽

Nitroso Compounds ◽

Primary Amines ◽

Acid Base ◽

Fast Reactions ◽

Half Wave

There are two possibilities how to follow equilibria of organic compounds established in aqueous solutions using polarography: for very fast reactions, information can be obtained from shifts of half-wave potentials. For slowly established equilibria, the changes in the limiting current are followed. In both cases variation of the half-wave potentials or limiting currents with concentration of a reactant, present in excess, is followed. The types of reactions, which had been followed in this way, are as follows: hydration–dehydration equilibria, additions of hydroxide ion to carbonyl and nitroso compounds, the role of slowly established acid–base equilibria involving C-acids; further also reactions involving the addition of ammonia, primary amines, hydroxylamine, and hydrazine to carbonyl compounds.

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Substituted Cyclic Sulfur-Nitrogen Compounds from Reaction of Primary Amines with Sulfur Dichloride.

Journal of Chemical & Engineering Data ◽

10.1021/je60019a046 ◽

1963 ◽

Vol 8 (4) ◽

pp. 611-611 ◽

Cited By ~ 2

Author(s):

Louis A. Ross ◽

John S. Roscoe ◽

Anderson Pace

Keyword(s):

Primary Amines ◽

Nitrogen Compounds ◽

Sulfur Dichloride

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Neue Selen-Stickstoff-Verbindungen tert-Butyl-seleninylamin, ButNSeO, und Di(tert-butyl)selendiimid, Se(NBut)2/New Selenium-Nitrogen Compounds tert-Butyl-seleninylamine, ButNSeO, and Di(tert-butyl)selenium Diimide, Se(NBut)2

Zeitschrift für Naturforschung B ◽

10.1515/znb-1986-0202 ◽

1986 ◽

Vol 41 (2) ◽

pp. 144-148 ◽

Cited By ~ 29

Author(s):

Max Herberhold ◽

Wolfgang Jellen

Keyword(s):

Ambient Temperature ◽

Mass Spectra ◽

Nitrogen Compounds ◽

Tert Butyl ◽

Tert Butylamine ◽

New Compounds ◽

C Nmr

The first seleninylamine, tBuNSeO, was prepared from tert-butylamine, tBuNH2, and SeOCl2 (3:1). The selenium diimide Se(NBut)2 was isolated from the corresponding reaction of tBuNH2 and SeCl4 (6:1); it decomposes at ambient temperature to give cyclic Se3(NBut)2. The new compounds were characterized on the basis of their IR , 1H and 13C NMR and mass spectra.

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