RAMAN SPECTRA OF THE H2SO4–SO3 AND D2SO4–SO3 SYSTEMS: EVIDENCE FOR THE OCCURRENCE OF POLYSULPHURIC ACIDS

1962 ◽  
Vol 40 (4) ◽  
pp. 658-674 ◽  
Author(s):  
R. J. Gillespie ◽  
E. A. Robinson
Keyword(s):  
Sulphuric Acid ◽  
Raman Spectra ◽  
Ionic Species ◽  
The Self ◽  
Experimental Results ◽  
Similar Work ◽  
Stretching Vibrations ◽  
Sulphur Trioxide ◽  
High Concentrations

The Raman spectra of oleums, i.e. mixtures of sulphur trioxide and sulphuric acid, have been re-examined. Similar measurements on the sulphur trioxide – deuterosulphuric acid (D2SO4) system are also reported. The experimental results and conclusions of previous similar work on oleums are discussed. By comparison of the spectra of oleums with those of the polysulphuryl halides it is shown that the polysulphuric acids H2S2O7 and H2S3O10 are present in this system. The increase in the frequency of the SO2 stretching vibrations with increasing concentration of sulphur trioxide gives evidence for the existence of higher polysulphuric acids such as H2S4O13 at high concentrations of sulphur trioxide. In relatively concentrated oleum, sulphur trioxide monomer and trimer are also present. It is shown that the self-dissociation of liquid H2S2O7 gives mainly molecular H2S2O10 and H2SO4 and not ionic species. The conclusions reached from the interpretation of the Raman spectra of the D2SO4–SO3 system are similar to those arrived at for sulphuric acid oleums. The spectra of solutions of NaHSO4 in oleums were also examined, and are discussed.

The interpretation of the infra-red and Raman spectra of the n -paraffins

1954 ◽  
Vol 247 (922) ◽  
pp. 35-58 ◽  
Keyword(s):  
Raman Spectra ◽  
Principal Series ◽  
Experimental Results ◽  
Absorption Bands ◽  
Infra Red ◽  
Complete Set ◽  
Stretching Vibrations

Infra-red spectra of a series of crystalline n -paraffins containing an odd number of carbon atoms have been obtained. The spectrum of oriented crystals of n -nonadecane has also been examined. These new experimental results have been combined with the earlier data on the crystalline n -paraffins containing an even number of carbon atoms, and many series of absorption bands have been identified in the complete set of spectra. These regularities, as well as those present in the Raman spectra, have been interpreted in terms of CH 2 , CH 3 , and C—C stretching vibrations. Very regular distributions of frequencies have been found between 720 and 1030 cm -1 and between 1200 and ca. 1370 cm -1 , which are assigned to CH 2 rocking and wagging vibrations, respectively. The majority of the absorption bands between 1150 and 880 cm -1 can be attributed to C—C stretching or CH 3 rocking modes, and assignments are suggested for the principal series observed in this region.

Lateral Tire Forces on Wet Roads

1977 ◽  
Vol 5 (2) ◽  
pp. 75-82 ◽  
Author(s):  
A. Schallamach
Keyword(s):  
Normal Load ◽  
The Self ◽  
Experimental Results ◽  
Slip Angle ◽  
Tire Model ◽  
Side Force ◽  
Tire Forces

Abstract Expressions are derived for side force and self-aligning torque of a simple tire model on wet roads with velocity-dependent friction. The results agree qualitatively with experimental results at moderate speeds. In particular, the theory correctly predicts that the self-aligning torque can become negative under easily realizable circumstances. The slip angle at which the torque reverses sign should increase with the normal load.

Vibrational spectra of aquadioxotetra; peroxodivanadates(V) M2[V2O2(O2)4(H2O)]·xH2O (M = N(CH3)4, Cs)

1990 ◽  
Vol 55 (6) ◽  
pp. 1485-1490 ◽  
Author(s):  
Peter Schwendt ◽  
Milan Sýkora
Keyword(s):  
Raman Spectra ◽  
Vibrational Spectra ◽  
Normal Coordinate Analysis ◽  
Force Constants ◽  
Infrared And Raman Spectra ◽  
Empirical Correlations ◽  
Normal Coordinate ◽  
Bond Lengths ◽  
Stretching Vibrations

The infrared and Raman spectra of M2[V2O2(O2)4(H2O)]·xH2O and M2[V2O2(O2)4(D2O)]·xD2O (M = N(CH3)4, Cs) were measured. In the region of the vanadium-oxygen stretching vibrations, the spectra were interpreted based on normal coordinate analysis, employing empirical correlations between the bond lengths and force constants.

Raman spectra of CN vibrations of acetonitrile in aqueous and other solutions. Experimental results andab initio calculations

2005 ◽  
Vol 36 (10) ◽  
pp. 932-937 ◽  
Author(s):  
F. H. Tukhvatullin ◽  
A. Jumabaev ◽  
G. Muradov ◽  
H. A. Hushvaktov ◽  
A. A. Absanov
Keyword(s):  
Raman Spectra ◽  
Experimental Results

scholarly journals Evaluation of the kinetics of oxidation and removal of organic matter in the self-purification of a mountain river

DYNA ◽  
2015 ◽  
Vol 82 (191) ◽  
pp. 183-193 ◽  
Author(s):  
Jorge Virgilio Rivera Gutiérrez
Keyword(s):  
Water Quality ◽  
Water System ◽  
The Self ◽  
Organic Load ◽  
Mountain River ◽  
Kinetics Of Oxidation ◽  
Kinetic Rates ◽  
High Concentrations ◽  
Kinetics Of

The study is based on the determination of the kinetic rates and assessment of self-purification of the Frio River, due to the uptake of organic load. The kinetic rates were calculated by applying differential and logarithmic methods on concentrations of water quality determinants present in each of the (7) reach of the river. The water system easily recovers the amount of oxygen, k<sub>d</sub>= 0.4, k<sub>a</sub> 3.2 d<sup>-1</sup>, only receives 27.7 Ton. d<sup>-1</sup>, the organic load, making high concentrations of carbon, ammonium and remain sediment. The length Influence of discharges, LIV- BOD yielded a mean per tranche of 10 km, compared to 3 km each way, means that the river can´t self- purification that need more length of travel. The study illustrates the modeling of the determinants of quality, developed by the QUAL2K, using the calculated rates.

scholarly journals Summertime PM<sub>2.5</sub> ionic species in four major cities of China: nitrate formation in an ammonia-deficient atmosphere

2009 ◽  
Vol 9 (5) ◽  
pp. 1711-1722 ◽  
Author(s):  
R. K. Pathak ◽  
W. S. Wu ◽  
T. Wang
Keyword(s):  
Gas Phase ◽  
Ionic Species ◽  
Mean Value ◽  
Average Concentration ◽  
Phase Reaction ◽  
Gas Phase Reaction ◽  
Particulate Pollution ◽  
Aerosol Acidity ◽  
Low Levels ◽  
High Concentrations

Abstract. Strong atmospheric photochemistry in summer can produce a significant amount of secondary aerosols, which may have a large impact on regional air quality and visibility. In the study reported herein, we analyzed sulfate, nitrate, and ammonium in PM2.5 samples collected using a 24-h filter system at suburban and rural sites near four major cities in China (Beijing, Shanghai, Guangzhou, and Lanzhou). Overall, the PM2.5 mass concentrations were high (with a mean value of 55–68 gμgm−3), which reflects the long-known particulate pollution in China's large urban centers. We observed very high concentrations of sulfate and nitrate at the Beijing and Shanghai sites, and, in particular, abnormally high levels of nitrate (24-h average concentration up to 42 gμgm−3 and contributing up to 25% of the PM2.5 mass) in the ammonium-poor samples. The Beijing and Shanghai aerosols were characterized by high levels of aerosol acidity (~220–390 nmol m−3) and low levels of in-situ pH (−0.77 to −0.52). In these samples, the formation of the observed high concentrations of particulate nitrate cannot be explained by homogeneous gas-phase reaction between ammonia and nitric acid. Examination of the relation of nitrate to relative humidity and aerosol loading suggests that the nitrate was most probably formed via the heterogeneous hydrolysis of N2O5 on the surface of the moist and acidic aerosols in Beijing and Shanghai. In comparison, the samples collected in Lanzhou and Guangzhou were ammonium-rich with low levels of aerosol acidity (~65–70 nmol m−3), and the formation of ammonium nitrate via the homogeneous gas-phase reaction was favored, which is similar to many previous studies. An empirical fit has been derived to relate fine nitrate to aerosol acidity, aerosol water content, aerosol surface area, and the precursor of nitrate for the data from Beijing and Shanghai.

scholarly journals Characteristics, seasonality and sources of carbonaceous and ionic components in the tropical Indian aerosols

2011 ◽  
Vol 11 (2) ◽  
pp. 3937-3976 ◽  
Author(s):  
C. M. Pavuluri ◽  
K. Kawamura ◽  
S. G. Aggarwal ◽  
T. Swaminathan
Keyword(s):  
Organic Carbon ◽  
Atmospheric Aerosols ◽  
Atmospheric Transport ◽  
Indian Subcontinent ◽  
Ionic Species ◽  
Water Soluble ◽  
Carbonaceous Aerosols ◽  
Mass Fractions ◽  
High Concentrations ◽  
Ionic Components

Abstract. To better characterize South and Southeast Asian aerosols, PM10 samples collected from tropical Chennai, India (13.04° N; 80.17° E) were analyzed for carbonaceous and water-soluble ionic components. Concentration ranges of elemental carbon (EC) and organic carbon (OC) were 2.4–14 μg m−3 and 3.2–15.6 μg m−3 in winter samples whereas they were 1.1–2.5 μg m−3 and 4.1–17.6 μg m−3 in summer samples, respectively. Concentration of secondary organic carbon (SOC) retrieved from EC-tracer method was 4.6 ± 2.8 μg m−3 in winter and 4.3 ± 2.8 μg m−3 in summer. SO42- (8.8 ± 2.5 μg m−3 and 4.1 ± 2.7 μg m−3 in winter and summer, respectively) was found as the most abundant ionic species (57% on average, n = 49), followed by NH4+ (15%) > NO3− > Cl− > K+> Na+ > Ca2+ > MSA− > Mg2+. The mass fractions of EC, organic matter (OM) and ionic species varied seasonally, following the air mass trajectories and corresponding source strength. Based on mass concentration ratios of selected components and relations of EC and OC to marker species, we found that biofuel/biomass burning is the major source of atmospheric aerosols in South and Southeast Asia. The high concentrations of SOC and WSOC/OC ratios (ave. 0.45; n = 49) as well as good correlations between SOC and WSOC suggest that the secondary production of organic aerosols during long-range atmospheric transport is also significant in this region. This study provides the baseline data of carbonaceous aerosols for southern part of the Indian subcontinent.

scholarly journals A Self-Supervised Tibetan-Chinese Vocabulary Alignment Method based on Adversarial Learning

2021 ◽  
Author(s):  
Enshuai Hou ◽  
Jie zhu
Keyword(s):  
The Self ◽  
Experimental Results ◽  
Chinese Characters ◽  
Training Method ◽  
Alignment Method ◽  
Adversarial Learning ◽  
Semantic Correlation ◽  
Data Alignment ◽  
Similarity Calculation ◽  
Adversarial Training

Tibetan is a low-resource language. In order to alleviate the shortage of parallel corpus between Tibetan and Chinese, this paper uses two monolingual corpora and a small number of seed dictionaries to learn the semi-supervised method with seed dictionaries and self-supervised adversarial training method through the similarity calculation of word clusters in different embedded spaces and puts forward an improved self-supervised adversarial learning method of Tibetan and Chinese monolingual data alignment only. The experimental results are as follows. First, the experimental results of Tibetan syllables Chinese characters are not good, which reflects the weak semantic correlation between Tibetan syllables and Chinese characters; second, the seed dictionary of semi-supervised method made before 10 predicted word accuracy of 66.5 (Tibetan - Chinese) and 74.8 (Chinese - Tibetan) results, to improve the self-supervision methods in both language directions have reached 53.5 accuracy.

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