CHEMISTRY OF THE TRIFLUOROMETHYL GROUP: PART III. PHENYLBISTRIFLUOROMETHYLPHOSPHINE AND RELATED COMPOUNDS
Keyword(s):
The reaction of trifluoroiodomethane with tetraphenylcyclotetraphosphine leads to the formation of phenylbistrifluoromethylphosphine and phenyltrifluoromethyliodophosphine. The mechanism of the reaction is discussed and the physical and chemical properties of these compounds are reported. Bromine reacts with phenylbistrifluoromethylphosphine to form phenylbistrifluoromethyldibromophosphorane which is hvdrolyzed to phenyltrifluoromethylphosphinic acid, C6H5(CF3)P(O)OH.
1947 ◽
Vol 66
(6)
◽
pp. 175-182
◽
1966 ◽
Vol 24
◽
pp. 101-110
2016 ◽
Vol 29
(2)
◽
pp. 266-274
2018 ◽
Vol 3
(2)
◽
pp. 167-170