THE COMPLEX DIELECTRIC CONSTANT OF SOLUTIONS OF TRIMETHYLPENTANE AND NITROBENZENE NEAR THE CONSOLUTE TEMPERATURE

1961 ◽  
Vol 39 (3) ◽  
pp. 526-534 ◽  
Author(s):  
B. D. Ripley ◽  
R. McIntosh

The complex dielectric constants of three compositions of trimethylpentane and nitrobenzene have been measured as a function of temperature for a range near the consolute temperature. The frequency employed was 3300 Mc/sec. The experimental procedure involved the study of the standing wave established in a coaxial line. The chemical systems showed maxima in both the real and imaginary parts of the complex dielectric constant at temperatures above those at which phase separation occurs. The finding of Semenchenko and Azimov is thus confirmed. A discussion of the validity of applying thermodynamic formulae to dielectrics showing loss is given and some qualitative remarks are offered concerning the change of the systems as they are cooled. These remarks are based upon the effect of the applied field upon the entropy of the solutions.

2001 ◽  
Vol 79 (5) ◽  
pp. 847-855 ◽  
Author(s):  
W Shi ◽  
C Fang ◽  
S Guo ◽  
Q Ren ◽  
Q Pan ◽  
...  

The dielectric properties of polymer composites with inorganic nanoparticles were investigated. In the demonstration of the dielectric constant expression of the nanocomposite polymer, the dielectric contributions of the displacement polarization, the orientation polarization, and the space polarization in the nanocomposite polymer were all considered. In the demonstration, two dielectric relaxation models were used, that of Debye for inorganic nanoparticles and the Havriliak–Negami function model for polymers. Then the expression of the complex dielectric constant of the nanocomposite polymer was obtained by using Onsager's local field theory. Furthermore, the nanocomposite polymer thin films that consist of PbTiO3 nanoparticles and polyetherketone were prepared. The real parts of the dielectric constants were measured and calculated, respectively. It was found that our calculated results are in good agreement with our measured results. PACS Nos.: 77.20, 77.55, 81.20T


1985 ◽  
Vol 25 (04) ◽  
pp. 502-514 ◽  
Author(s):  
Liang C. Shen

Abstract This paper describes an automated laboratory system that can measure accurately the dielectric properties of core samples in the ultrahigh-frequency properties of core samples in the ultrahigh-frequency (UHF) range. The system consists of a precision coaxial-line sample holder, a network analyzer, a plotter, a printer, and a desk computer. The computer is for measurement control, data acquisition, and data analysis. A new method is developed to measure and to compensate for the error of the network analyzer system. This method uses a brass sample and does not require standard terminations. A procedure for core sample preparation is also recommended to ensure accuracy of the data. Introduction The electromagnetic propagation tool (EPT) is a relatively new wireline sonde developed by Schlumberger for detection and quantification of hydrocarbon. It is operated at 1.1 GHz, which is in the UHF band of the electromagnetic spectrum. The EPT sonde measures the dielectric constant of the formation. Because water has a much higher dielectric constant (about 80 units) than oil (about 2 units) and gas (about 1 unit), the EPT sonde can distinguish hydrocarbon-bearing zones from the water-bearing zones even when the formation water is fresh. The dielectric constant of water at UHF is not very sensitive to salinity. Consequently, EPT is particularly useful in situations where the formation water resistivity is variable or unknown, as a result, for example, of water, steam, or chemical flooding. The EPT log displays the travel time and the rate of attenuation of the electromagnetic wave in the formation. From these data, the calculated complex dielectric constant of the formation may be calculated. This complex dielectric constant is related to water saturation, Sw, by an empirical formula called the complex refractive index method (CRIM): ............................(1) where = porosity, = dielectric constant of the water in the rock, = dielectric constant of oil or gas, and = dielectric constant of the rock grain. To verify the validity of the CRIM formula given by Eq. 1, a computer-controlled laboratory system has been set up to measure the dielectric constants of saturated core samples, dry core samples, and oils. The same system is now being used for routine measurements of cores for EPT log interpretation. Measurement Techniques Two basic techniques can be used to measure the complex dielectric constant of a saline-water-saturated rock at frequencies higher than 100 MHz. The first is the coaxial-line and waveguide method, and the other is the resonant-cavity method. We describe these methods and point out their advantages and disadvantages. Fig. 1 shows the configuration of the coaxial-line and waveguide method. In Figs. 1a and 1b, we see that the core sample is machined into a circular cylinder with a circular concentric hole drilled to fit the coaxial line. The line consists of an outer conductor and an inner conductor. In Fig. 1c, we see that the core sample is machined into a rectangular column to fit into a rectangular waveguide. The latter is a rectangular metal pipe without a central conductor. pipe without a central conductor. Longitudinal slots are cut along the outer conductor of the coaxial line (Fig. 1b) or on top of the rectangular waveguide (Fig. 1c) to allow a probe to be inserted partially into the region where electromagnetic fields are present. The probe travels along the length of the structure and detects the amplitude and the phase of the electromagnetic fields present in the structure. During the measurement, an electromagnetic wave of the selected frequency is sent propagating down the line or the waveguide until it encounters the core sample. Reflection occurs so that part of the wave is absorbed, and part is reflected and travels in the reverse direction. The phase and the amplitude of the reflected wave are determined by the complex dielectric constant of the sample. The reflected wave interacts with the incident wave and creates an interference pattern called the standing wave pattern. The complex dielectric constant of the core sample can be determined from the standing wave pattern recorded by the traveling probe. This method was used by Poley et al. for sandstone samples up to 1.2 GHz. It was also used by Tam to test nine dry rocks, mainly sedimentary, in the frequency range 150 to 1000 MHz. The rectangular waveguide was used by Roberts and Von Hippel to measure a variety of materials at 5 GHz. The configuration shown in Fig. 1a was used by Rau and Wharton to measure formation samples in the frequency range 500 MHz to 1.1 GHz. This arrangement calls for placing the sample at the center, rather than at the end, of a coaxial line. The amplitudes and the phases of both the reflected and the transmitted waves are recorded and are called the scattering matrix parameters. parameters. SPEJ p. 502


Author(s):  
Chunfang Song ◽  
Tian Sang ◽  
Haiying Chen ◽  
Li Zhenfeng ◽  
Li Jing

AbstractThe dielectric properties of blackberry samples with a 20.0–80.0 % w.b (web basis) moisture content were determined with a network analyzer and an open-ended coaxial-line probe over a frequency range from 5 to 3000 MHz and a temperature range from 20 to 100 °C. The results showed that the dielectric constant decreased with increasing temperature but increased with increasing moisture content; however, the loss factor increased with increasing temperature and moisture content. The dielectric constant and the loss factor decreased with increasing frequency. The penetration depth decreased with increasing temperature, frequency and moisture content. A large penetration depth at 915 MHz may provide practical large-scale dielectric drying for blackberries. The dielectric constants and loss factors for blackberry by combining the above mathematical model and temperature and moisture of the sample in the microwave drying process were used to analyze and control blackberry drying technology.


1963 ◽  
Vol 41 (10) ◽  
pp. 1679-1685 ◽  
Author(s):  
V. Muralidhara Rao

An interferometric method has been developed for the measurement of ε′ and ε″ at 8.3-mm wavelength. The values obtained by the method are compared with those obtained by the standing-wave method. The agreement is fair.


2005 ◽  
Vol 19 (07n09) ◽  
pp. 1191-1197 ◽  
Author(s):  
D. McNEISH ◽  
K. JUNG ◽  
C. M. BALIK ◽  
H. CONRAD

Determined were the effects of preparation procedure and electric field frequency f = dc to 105 Hz on the dielectric constants and ER response (shear rate [Formula: see text]) of a suspension in silicone oil of 23 wt.% zeolite particles originally containing 19 wt.% H 2 O . Heating the oil and the zeolite particles at 110°C both prior to, and following, mixing decreased the conductivity of the suspension more than simply heating the suspension following mixing. The double heating procedure reduced the complex dielectric constant [Formula: see text] of the particles and the complex mismatch parameter β*. The ER shear stress τ E was proportional to [Formula: see text] for the single heating and [Formula: see text] for the double heating, where [Formula: see text] is the complex dielectric constant of the silicone oil. The lower exponent corresponds to a higher water content and in turn higher conductivity of the suspension. Erratic ER response occurred for f =10 Hz in tests with [Formula: see text], but not in tests with [Formula: see text].


1972 ◽  
Vol 50 (10) ◽  
pp. 1053-1054 ◽  
Author(s):  
Suresh Chandra ◽  
Jai Prakash

The high temperature dielectric constants of RbCl, RbBr, and RbI are measured at 24.6 GHz from room temperature to near melting point. A standing wave technique has been used. The dielectric constant of RbBr is observed to increase at a faster rate than that of RbCl and RbI.


Relevance. The problems of remote non-destructive determination and control of quality indicators of a wide variety of material environments, in particular, household and food products, are relevant practically for all areas of the national economy, science and technology. The relevance of scientific research in the field of dielectrometry in the microwave range is also due to the needs for the development of high technologies in medicine and health care, the national economy in real time. The aim of this work is to develop the method of microwave waveguide dielectrometry based on the application of the theory of multilayer plane-layered dielectric structures to the determination of the complex dielectric constant of a substance from the values ​​of the standing wave ratio of the samples under study in a waveguide at two close frequencies. Materials and methods. The research is based on well-studied phenomena of interference of electromagnetic waves on multilayer plane-layered dielectric structures. By using a mathematical model of the phenomenon of interference of a plane electromagnetic wave on a three-layer dielectric structure, the ambiguity of determining the complex dielectric constant of a substance by the classical method of waveguide dielectrometry in the microwave range by measuring the standing wave ratio of a dielectric sample placed in the waveguide and the phase angle of the reflection coefficient is overcome. Results. A method is proposed for ensuring the unambiguity of determining the complex dielectric constant of a substance in waveguide dielectrometry on the basis of the theory of multilayer plane-layered dielectric structures. The method leads to an explicit expression for the complex reflection coefficient of an electromagnetic wave from the investigated dielectric sample placed in a rectangular waveguide. The complex dielectric constant of a substance is determined from the values ​​of the standing wave ratio at two close frequencies in the microwave range. By the found value of the dielectric constant and the tangent of the dielectric loss angle, the quality parameter of the substance is determined by comparing and optimizing two objective functions, including the arrays of reference values ​​of the complex dielectric constant obtained in the course of measurements and compiled in advance, and by comparing and optimizing the third objective function, previous functions. As an example of an indicator of the quality of a substance, the specific heat of combustion of coal was determined. Conclusions. The proposed method for determining the complex dielectric constant and quality indicators of dielectric materials in the microwave frequency range has been tested in the case of various types of coals, its efficiency has been proven and the reliability of the results has been proven. The method and the devices and software implemented on its basis are promising for non-destructive express control of dielectric materials and media.


1961 ◽  
Vol 39 (3) ◽  
pp. 425-442 ◽  
Author(s):  
J. D. McCowan ◽  
R. McIntosh

The complex dielectric constant of the system Vycor glass – ethyl chloride has been measured at three temperatures in the range +11 °C to −33 °C and in the frequency range between 500 Mc sec−1 and 4000 Mc sec−1 by the use of a coaxial line. The real and imaginary parts of the dielectric constant of the adsorbate have also been evaluated. Appreciable loss in the adsorbed matter is found for small quantities adsorbed, and loss is again detected at the highest frequencies and lowest temperatures for the matter held in multilayers or condensed in capillaries. The frequency range and accuracy of measurement were not sufficient to classify the type of loss curve, but other evidence suggests that the loss for the first quantities adsorbed will turn out to be that for rotational oscillators. In general earlier observations of this system are confirmed and extended.


2020 ◽  
Vol 12 (21) ◽  
pp. 3544
Author(s):  
Xiao Jin ◽  
Wen Yang ◽  
Xiaoqing Gao ◽  
Zhenchao Li

Complex dielectric constant (CDC) of bound water determines the accuracy of the complex dielectric constant of wet soil. According to electrical double-layer structure and dielectric properties, the bound water on clay particle surface is divided into strongly bound water and weakly bound water. Based on this classification, models for the complex dielectric constants of bound water and soil are established taking into consideration factors such as temperature, moisture, texture, and microwave frequency. The results show that the fundamental reason why the complex dielectric constant of bound water is between that of ice and free water is the adsorption force which forms the electrical double-layer structure on the surface of clay particles. Low-concentration cationic solution could exist in free soil water and was found as the reason for the higher salinity and conductivity of free soil water, as compared to the measured soil solution. Results of soil CDC model are in good agreement with measured data across a wide range of microwave frequencies and soil temperature, moisture, and texture. The absolute root mean square error analysis also shows that the soil CDC model in this paper compared to the other models is more accurate.


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