THE SOLID–LIQUID EQUILIBRIUM BETWEEN ANHYDROUS MAGNESIUM CHLORIDE AND N,N-DIMETHYLFORMAMIDE
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The solid–liquid equilibrium between anhydrous magnesium chloride and N,N-dimethylformamide has been investigated between −58° and +97 °C, and up to 25 mole% in magnesium chloride by the techniques of thermal analysis. The following compounds and their melting points have been noted: MgCl2.12DMF, 8.7°; MgCl2.6DMF, 35.0° (incongruent); MgCl2.5DiMF, 51.0°; MgCl.4DMF, 69.0 °C. Infrared examination of some of the compounds suggests that co-ordination is through the carbonyl group.
2019 ◽
Vol 64
(8)
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pp. 3367-3374
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2012 ◽
Vol 57
(10)
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pp. 2855-2862
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2019 ◽
Vol 136
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pp. 180-181
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1961 ◽
Vol 6
(3)
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pp. 328-330
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