THE SOLID–LIQUID EQUILIBRIUM BETWEEN ANHYDROUS MAGNESIUM CHLORIDE AND N,N-DIMETHYLFORMAMIDE

1960 ◽  
Vol 38 (11) ◽  
pp. 2143-2146 ◽  
Author(s):  
Denys Cook

The solid–liquid equilibrium between anhydrous magnesium chloride and N,N-dimethylformamide has been investigated between −58° and +97 °C, and up to 25 mole% in magnesium chloride by the techniques of thermal analysis. The following compounds and their melting points have been noted: MgCl2.12DMF, 8.7°; MgCl2.6DMF, 35.0° (incongruent); MgCl2.5DiMF, 51.0°; MgCl.4DMF, 69.0 °C. Infrared examination of some of the compounds suggests that co-ordination is through the carbonyl group.

2012 ◽  
Vol 57 (10) ◽  
pp. 2855-2862 ◽  
Author(s):  
Mark I. Pownceby ◽  
David H. Jenkins ◽  
Roman Ruzbacky ◽  
Sophia Saunders

2021 ◽  
Vol 325 ◽  
pp. 115113
Author(s):  
Zhicheng Gao ◽  
Ying Li ◽  
Xunqiu Wang

2013 ◽  
Vol 339 ◽  
pp. 58-66 ◽  
Author(s):  
Maria Dolores Robustillo ◽  
Deise Fernanda Barbosa ◽  
Antonio José de Almeida Meirelles ◽  
Pedro de Alcântara Pessôa Filho

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