CIS AND TRANS 1-ACETOXY-1,3-BUTADIENE: PHYSICAL AND CHEMICAL PROPERTIES, INFRARED AND ULTRAVIOLET SPECTRA
Keyword(s):
1-Acetoxy-1,3-butadiene was prepared by the reaction of crotonaldehyde with acetic anhydride in the presence of potassium or sodium acetate. The product was found to consist of two forms which, from their physical properties and infrared spectra, appear to be cis and trans. Mass and ultraviolet spectra, and methods of analysis are also reported. The cis form was found to be a substantially stronger inhibitor than the trans in the bulk polymerization of vinyl acetate using benzoyl peroxide as catalyst.
1978 ◽
Vol 26
(11)
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pp. 3419-3425
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1966 ◽
Vol 24
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pp. 101-110
2016 ◽
Vol 29
(2)
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pp. 266-274
2018 ◽
Vol 3
(2)
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pp. 167-170