EXCHANGE BETWEEN THALLOUS AND THALLIC IONS IN THE PRESENCE OF SULPHATE ION

1958 ◽  
Vol 36 (1) ◽  
pp. 167-170 ◽  
Author(s):  
D. R. Wiles
Keyword(s):  
Exchange Reaction ◽  
Higher Order ◽  
Transfer Mechanism ◽  
Ion Concentration ◽  
First Order ◽  
Order Dependence

The rates of the exchange reaction between thallous and thallic ions have been measured as a function of sulphate ion concentration, at constant acidity. At high sulphate concentrations, the results agree with those of Brubaker and Mickel, indicating second- and higher-order dependence of the rate on sulphate ion concentration. At low sulphate concentrations, pure first-order dependence on sulphate is found. The inhibitive effect found in some systems is absent. A bridge-transfer mechanism is suggested.

Oxidation of Hydrazine by Alkaline Ferricyanide in Water-methanol Mixtures

1970 ◽  
Vol 25 (2) ◽  
pp. 188-190 ◽  
Author(s):  
V. K. Jindal ◽  
M. C. Agrawal ◽  
S. P. Mushran
Keyword(s):  
Ion Concentration ◽  
Hydroxide Ion ◽  
First Order ◽  
Order Dependence ◽  
Buffer Solutions ◽  
Entropy Of Activation ◽  
Alkaline Ferricyanide ◽  
Specific Ion Effect ◽  
Kinetics Of

Kinetics of the oxidation of hydrazine by ferricyanide was investigated in water-methanol mixtures using several buffer solutions. The reaction showed first order dependence in both hydrazine and ferricyanide. The order with respect to hydroxide ion concentration was zero. Increase in concentration of methanol had a retarding influence on the rate while the addition of neutral salts showed a specific ion effect. The energy and entropy of activation were calculated as 12.3 kcals. mole-1 and -20.8 cals. deg-1 mole-1 respectively. A suitable mechanism has been proposed which suggests the primary rate determining reaction between N2H4 and Fe (CN)63⊖. Nitrogen was found to be the product of the reaction.

Kinetics of the oxidation of Pu(IV) by manganese dioxide

2002 ◽  
Vol 90 (2) ◽  
Author(s):  
A. Morgenstern ◽  
Gregory R. Choppin
Keyword(s):  
Manganese Dioxide ◽  
Rate Equation ◽  
Oxidation Reaction ◽  
Hydrogen Ion ◽  
Ion Concentration ◽  
Hydrogen Ion Concentration ◽  
First Order ◽  
Order Dependence ◽  
Ph Range ◽  
Kinetics Of

SummaryThe kinetics of the oxidation of plutonium(IV) by manganese dioxide were studied in 1.0 M NaCl over the pH range from 2.5 to 8.2 with variable concentrations of manganese dioxide from 0.01 mIn the pH range from 2.0 to 3.5, the oxidation of Pu(IV) by manganese dioxide was first order with respect to the concentration of manganese dioxide and −0.21 with respect to the hydrogen ion concentration. Consequently, assuming a first order dependence with respect to the concentration of Pu(IV), the oxidation reaction can be described by the following rate equation:with

Dual systems for all: Higher-order, role-based relational reasoning as a uniquely derived feature of human cognition

2019 ◽  
Vol 42 ◽  
Author(s):  
Daniel J. Povinelli ◽  
Gabrielle C. Glorioso ◽  
Shannon L. Kuznar ◽  
Mateja Pavlic
Keyword(s):  
Temporal Reasoning ◽  
Higher Order ◽  
Important Case ◽  
Human Cognition ◽  
Relational Reasoning ◽  
Dual Systems ◽  
First Order ◽  
Reasoning System ◽  
Role Based

Abstract Hoerl and McCormack demonstrate that although animals possess a sophisticated temporal updating system, there is no evidence that they also possess a temporal reasoning system. This important case study is directly related to the broader claim that although animals are manifestly capable of first-order (perceptually-based) relational reasoning, they lack the capacity for higher-order, role-based relational reasoning. We argue this distinction applies to all domains of cognition.

Challenging the Multidimensional Conception of Perceived Person-Environment Fit

2020 ◽  
pp. 1-9
Author(s):  
Julian M. Etzel ◽  
Gabriel Nagy
Keyword(s):  
Higher Education ◽  
University Students ◽  
Educational Outcomes ◽  
Factor Model ◽  
Higher Order ◽  
Substantial Proportion ◽  
Unique Variance ◽  
First Order ◽  
Person Environment Fit ◽  
Order Factor

Abstract. In the current study, we examined the viability of a multidimensional conception of perceived person-environment (P-E) fit in higher education. We introduce an optimized 12-item measure that distinguishes between four content dimensions of perceived P-E fit: interest-contents (I-C) fit, needs-supplies (N-S) fit, demands-abilities (D-A) fit, and values-culture (V-C) fit. The central aim of our study was to examine whether the relationships between different P-E fit dimensions and educational outcomes can be accounted for by a higher-order factor that captures the shared features of the four fit dimensions. Relying on a large sample of university students in Germany, we found that students distinguish between the proposed fit dimensions. The respective first-order factors shared a substantial proportion of variance and conformed to a higher-order factor model. Using a newly developed factor extension procedure, we found that the relationships between the first-order factors and most outcomes were not fully accounted for by the higher-order factor. Rather, with the exception of V-C fit, all specific P-E fit factors that represent the first-order factors’ unique variance showed reliable and theoretically plausible relationships with different outcomes. These findings support the viability of a multidimensional conceptualization of P-E fit and the validity of our adapted instrument.

Computational Models for Multilayered Composite Shells with Application to Tires

1996 ◽  
Vol 24 (1) ◽  
pp. 11-38 ◽  
Author(s):  
G. M. Kulikov
Keyword(s):  
Type Theory ◽  
Computational Models ◽  
Geometrical Nonlinearity ◽  
Higher Order ◽  
Stress Strain ◽  
Strain Fields ◽  
First Order ◽  
Timoshenko Type ◽  
Joint Influence ◽  
Discrete Layer

Abstract This paper focuses on four tire computational models based on two-dimensional shear deformation theories, namely, the first-order Timoshenko-type theory, the higher-order Timoshenko-type theory, the first-order discrete-layer theory, and the higher-order discrete-layer theory. The joint influence of anisotropy, geometrical nonlinearity, and laminated material response on the tire stress-strain fields is examined. The comparative analysis of stresses and strains of the cord-rubber tire on the basis of these four shell computational models is given. Results show that neglecting the effect of anisotropy leads to an incorrect description of the stress-strain fields even in bias-ply tires.

Collision Induced Microwave Absorption in N2, CH4, and N2–Ar, N2–CH4 Mixtures at 1.1 and 2.3 cm−1

1974 ◽  
Vol 52 (9) ◽  
pp. 821-829 ◽  
Author(s):  
I. R. Dagg ◽  
G. E. Reesor ◽  
J. L. Urbaniak
Keyword(s):  
Microwave Absorption ◽  
Quadrupole Moment ◽  
Linear Dependence ◽  
Relaxation Times ◽  
High Sensitivity ◽  
Higher Order ◽  
Induced Absorption ◽  
High Q ◽  
Order Dependence

Collision induced microwave absorption is reported in pure N2, N2–Ar, N2–CH4, mixtures, and in pure CH4 in the 35 and 70 GHz regions (1.1 and 2.3 cm−1) at a temperature of 22 °C. The measurements are accomplished using overmoded high Q cavities capable of pressurization of up to 5000 p.s.i.g. The apparatus and method are described. With the high sensitivity attained, the results in pure N2 from 30 → 250 amagat reveal terms in the square and cube of the density from which the relaxation times are calculated. The linear dependence on frequency of the collision induced absorption up to 2.3 cm−1 is established. Higher order dependence on the density is observed in the N2–Ar and N2–CH4 mixtures. Various estimates of the quadrupole moment of N2 are given, making use of earlier results in other frequency regions.

scholarly journals Simpson type inequalities and applications

2021 ◽  
Author(s):  
Muhammad Uzair Awan ◽  
Muhammad Zakria Javed ◽  
Michael Th. Rassias ◽  
Muhammad Aslam Noor ◽  
Khalida Inayat Noor
Keyword(s):  
Quadrature Formula ◽  
Convex Functions ◽  
Integral Identity ◽  
Higher Order ◽  
Auxiliary Result ◽  
First Order ◽  
New Class ◽  
Differentiable Functions

AbstractA new generalized integral identity involving first order differentiable functions is obtained. Using this identity as an auxiliary result, we then obtain some new refinements of Simpson type inequalities using a new class called as strongly (s, m)-convex functions of higher order of $$\sigma >0$$ σ > 0 . We also discuss some interesting applications of the obtained results in the theory of means. In last we present applications of the obtained results in obtaining Simpson-like quadrature formula.

scholarly journals Reputations for Resolve and Higher-Order Beliefs in Crisis Bargaining

2021 ◽  
pp. 002200272199554
Author(s):  
Allan Dafoe ◽  
Remco Zwetsloot ◽  
Matthew Cebul
Keyword(s):  
Belief Change ◽  
Higher Order ◽  
Future Research ◽  
Order Effects ◽  
Survey Experiment ◽  
Experimental Setting ◽  
Crisis Bargaining ◽  
First Order ◽  
Qualitative Evidence ◽  
Higher Order Effects

Reputations for resolve are said to be one of the few things worth fighting for, yet they remain inadequately understood. Discussions of reputation focus almost exclusively on first-order belief change— A stands firm, B updates its beliefs about A’s resolve. Such first-order reputational effects are important, but they are not the whole story. Higher-order beliefs—what A believes about B’s beliefs, and so on—matter a great deal as well. When A comes to believe that B is more resolved, this may decrease A’s resolve, and this in turn may increase B’s resolve, and so on. In other words, resolve is interdependent. We offer a framework for estimating higher-order effects, and find evidence of such reasoning in a survey experiment on quasi-elites. Our findings indicate both that states and leaders can develop potent reputations for resolve, and that higher-order beliefs are often responsible for a large proportion of these effects (40 percent to 70 percent in our experimental setting). We conclude by complementing the survey with qualitative evidence and laying the groundwork for future research.

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