A NOTE ON THE VALIDITY OF THE GIBBS-DALTON LAW AS APPLIED TO DILUTE MIXTURES OF WATER VAPOR WITH HYDROGEN, HELIUM, AND ARGON AT ROOM TEMPERATURES
Keyword(s):
Water vapor at room temperature and at pressures in the neighborhood of 10 mm. Hg behaves as a vacuum to each of the three gases hydrogen, helium, and argon, at pressures up to about 100 mm. Hg. The thermodynamic potentials of constituent gases in such mixtures of water vapor and hydrogen, water vapor and helium, etc. probably do not differ from those of the pure components, at equal volume concentrations, by more than 0.3%. Thus these gas mixtures obey the Gibbs–Dalton Law very closely and accordingly must also obey Dalton's Law. Velocity distribution functions of these gases under our experimental conditions are essentially Maxwellian.
1993 ◽
Vol 19
(4)
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pp. 665-681
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2014 ◽
Vol 24
(1)
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pp. 015018
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1999 ◽
Vol 32
(15)
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pp. 1842-1850
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2021 ◽
2000 ◽
Vol 174
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pp. 412-422