The role of solvent in organometallic chemistry — Oxidative addition with dichloromethane or chloroform

2012 ◽  
Vol 90 (1) ◽  
pp. 46-54 ◽  
Author(s):  
Anwar Abo-Amer ◽  
Matthew S. McCready ◽  
Fenbao Zhang ◽  
Richard J. Puddephatt
Keyword(s):  
Organometallic Chemistry ◽  
Oxidative Addition ◽  
Diimine Ligand ◽  
Role Of Solvent

Dimethylplatinum(II) complexes [PtMe2(NN)], with NN = diimine ligand, can react with dichloromethane or chloroform solvent to give the corresponding organoplatinum(IV) complexes [PtClMe2(CH2Cl)(NN)] or [PtClMe2(CHCl2)(NN)], respectively. The products can exist in isomeric forms, corresponding to products of cis or trans oxidative addition. The structures of three dichloromethane adducts and one chloroform adduct are reported.

scholarly journals Dye-Surfactant Interaction: Role of Solvent

2013 ◽  
Vol 25 (18) ◽  
pp. 10499-10503 ◽  
Author(s):  
Ziya Ahmad Khan ◽  
Abdullah S. Al-Bogami
Keyword(s):  
Role Of Solvent

scholarly journals The role of hypervalent iodine(iii) reagents in promoting alkoxylation of unactivated C(sp3)–H bonds catalyzed by palladium(ii) complexes

2021 ◽  
Author(s):  
Payam Abdolalian ◽  
Samaneh K. Tizhoush ◽  
Kaveh Farshadfar ◽  
Alireza Ariafard
Keyword(s):  
Dft Calculations ◽  
Oxidative Addition ◽  
Hypervalent Iodine

This work uses DFT calculations to explore Pd(ii)-catalysed iodine(iii)-mediated alkoxylation of unactivated C(sp3)–H bonds and reveals how important the isomerization is in triggering the oxidative addition of ArIX2 to Pd(ii).

Role of Solvent in Excited-State Proton Transfer in Hypericin

1994 ◽  
Vol 98 (34) ◽  
pp. 8352-8358 ◽  
Author(s):  
F. Gai ◽  
M. J. Fehr ◽  
J. W. Petrich
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Excited State Proton Transfer ◽  
Role Of Solvent

scholarly journals 155 The role of solvent mobility in protein dynamics

2015 ◽  
Vol 33 (sup1) ◽  
pp. 100-101
Author(s):  
Qiong Yang ◽  
Peng Sang ◽  
Shu-Qun Liu
Keyword(s):  
Protein Dynamics ◽  
Role Of Solvent

ChemInform Abstract: THE ROLE OF SOLVENT IN CONJUGATE ADDITIONS LEADING TO CIS- AND TRANS-1-ALKYL-2-ARYL-3-CARBO(AROYL)AZIRIDINES

1977 ◽  
Vol 8 (40) ◽  
pp. no-no
Author(s):  
P. TARBURTON ◽  
P. B. WOLLER ◽  
R. C. BADGER ◽  
E. DOOMES ◽  
N. H. CROMWELL
Keyword(s):  
Conjugate Additions ◽  
Cis And Trans ◽  
Role Of Solvent

Formation of Oriented Nanostructures from Single Molecules of Conjugated Polymers in Microdroplets of Solution:  The Role of Solvent

2004 ◽  
Vol 37 (16) ◽  
pp. 6132-6140 ◽  
Author(s):  
Pradeep Kumar ◽  
Adosh Mehta ◽  
Shannon M. Mahurin ◽  
Sheng Dai ◽  
Mark D. Dadmun ◽  
...  
Keyword(s):  
Conjugated Polymers ◽  
Single Molecules ◽  
Role Of Solvent
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