Preferential flow in geosynthetic clay liners exhumed from final covers with composite barriers
Geosynthetic clay liners (GCLs) were exhumed from final covers with composite barriers (geomembrane over GCL) at two municipal solid waste landfills in the USA. Preferential flow and high hydraulic conductivity (>2 × 10−9 m/s) was observed in eight of the 18 GCL samples collected from both sites. At one site, manganese oxide precipitate was concomitant with bundles of needle-punched fibers that conducted preferential flow. Nearly complete replacement of Na by Ca on the bentonite surface occurred in all GCL samples. GCLs with and without preferential flow could not be differentiated by physical and chemical properties commonly used to differentiate GCLs with high and low hydraulic conductivities (exhumed water content, swell index, mole fraction monovalent cations, soluble cation concentrations). The relative abundance of soluble cations in the pore water of GCLs exhibiting preferential flow was comparable to the relative abundance in the subgrade pore water, whereas the pore water in GCLs with distributed flow was more sodic than the pore water in the subgrade. Hydration experiments indicated that bentonite in GCLs initially hydrates in a zone surrounding bundles of needle-punching fibers. Cation exchange during this hydration process may create zones of higher hydraulic conductivity surrounding the fiber bundle, permitting preferential flow.