An equation of state for unsaturated soils
The enthalpy within a soil system under equilibrium conditions is investigated theoretically. Terzaghi's effective stress equation for a saturated soil is first examined and the approach extended to determine the enthalpy associated with the air, water, and solid phases, and the interactions between the phases, in an unsaturated soil. An equation of state is developed which links the stress state variables (p ua) and (ua uw) to the specific volume (v) and specific water volume (vw) and thus to the volumes of the phases. The equation is shown to provide a logical interpretation of the average volumetric "coupling" stress p'c within unsaturated soils which highlights the significance of the dual stress regime and bimodal structure. The new equation is compared with previously reported experimental data on kaolin and a lateritic gravel. The agreement is good and it provides insight into unsaturated soil strength and deformation behaviour and clarifies various previously identified anomalies.Key words: partial saturation, unsaturated soils, thermodynamics, effective stress, equation of state, critical state.