The analysis of the 5s25p2, 5s5p3, 5s25p5d, and 5s25p6s configurations of Te III

1992 ◽  
Vol 70 (9) ◽  
pp. 740-744 ◽  
Author(s):  
Y. N. Joshi ◽  
A. Tauheed ◽  
I. G. Davison

The spectrum of tellurium was photographed in the wavelength region 400–2000 Å (1 Å = 10−10 m) on a 3 m normal incidence spectrograph. The new measurements and configuration interaction calculations lead to major revisions in the earlier analysis of Te III. For the ground state 5s25p2, all but one of the previously known levels have been confirmed. Out of the 26 levels belonging to the three excited configurations, viz. 5s5p3, 5s25p5d, and 5s25p6s, 14 levels have been confirmed, 4 have been rejected, and for 8 of the levels, either the designation, J value or configuration assignments have been revised. Configuration interaction calculations were carried out to interpret the observed spectrum. Seventy-two lines have been classified in the 5s25p2 − (5s5p3 + 5s25p5d + 5s25p6s) transition array.

1995 ◽  
Vol 73 (1-2) ◽  
pp. 63-73
Author(s):  
R. R. Kildiyarova ◽  
Y. N. Joshi ◽  
M. A. Lumsden ◽  
A. J. J. Raassen

The spectrum of bismuth was photographed in the 400–1200 Å (1 Å = 10−1 m) wavelength region on a 3 m normal incidence spectrograph using a triggered spark source. The 5d8, 5d76s, and 5d76p configurations of Bi VIII were analysed. The missing 1S0 level of the 5d8 configuration, 27 of 38 levels of the 5d76s configuration, and 30 additional levels of the 5d76p configuration were established. One previously identified level at 338 016 cm−1 (J = 3) was revised to 338 701 cm−1. Two hundred and sixty-three lines were classified in the 5d76s–5d76p transition array, and 26 additional lines were classified in the 5d8–5d76p transition array. The least-squares-fitted parametric calculations interpret the observed spectrum satisfactorily. The scaling factors of the energy parameters were compared in the isoelectronic sequence from Au IV to Bi VIII.


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