Étude expérimentale de propriétés piezo-optiques du CS2 en phase liquide à 273,15 et 298,15 K pour des pressions jusqu'à 140 MPa

1989 ◽  
Vol 67 (10) ◽  
pp. 957-962 ◽  
Author(s):  
A. Guerfi ◽  
J. M. St-Arnaud

Using a Michelson interferometer coupled to a stabilised He–Ne laser, we measured the change of the refractive index of liquid CS2 along two isotherms, 273.15 and 298.15 K for pressures up to 140 MPa. Results show that the classical Lorentz–Lorenz equation versus the pressure varies linearly, as predicted by classical theory. Results also show that for liquid CS2 the experimental value of (8.4 ± 0.5) × 10−24 cm3, for the electronic polarizability in the range studied, is constant with pressure and temperature. Our experimental value of 8.74 × 10−24 cm3 for the electronic polarizability agrees with that found in the literature.

1984 ◽  
Vol 62 (6) ◽  
pp. 548-553 ◽  
Author(s):  
J. M. St-Arnaud ◽  
T. K. Bose

We have developed a measuring system based on the Michelson interferometer for the determination of piezo-optical effects in liquids. The resolution of our system is about 5 parts in 107. We applied our system to the measurement of the variation of the refractive index of CCl4 at 25 °C up to 1.96 × 103 bar. We observe a slight deviation of the Lorentz–Lorenz equation at high pressures.


1974 ◽  
Vol 71 ◽  
pp. 525-532 ◽  
Author(s):  
Claude Pouchan ◽  
Serge Senez ◽  
Jacques Raymond ◽  
Henri Sauvaitre

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