Absorption bands of O2 and OH in a new ultraviolet continuum and in the XeCl laser spectrum
Two excimer lasers of the automatic pre-ionization type have been constructed. To avoid impurities, the two series of condensers were placed outside the discharge chamber. Using one of these devices we have observed a new ultraviolet (UV) continuum from a discharge through a He–O2 mixture at 900 Torr. The continuous nature of this emission was assured by the observation of almost 80 absorption bands of the O2 Schumann-Runge system arising from highly excited vibrational levels and of some OH bands in the A–X system. The same type of discharge through pure He emits no continuum but some OH bands. The time dependence of the light pulses was studied to infer the origin of the continuum. Based on these observations, we show that the strong absorption in the B–X, 0–2 band of the XeCl laser is due to the P11, Q13, and Q13′ lines in the 0–0 band of the OH A–X system; the estimated intensity of this absorption amounting to 5–7% of the total intensity of the XeCl laser. The XeCl spectra were photographed on an E1 quartz spectrograph and in the third order of a 6.65 m grating.