A stochastic approach to the freezing of supercooled liquids
We have considered the freezing of a supercooled liquid, in particular water, experimentally found to be describable by the phenomenological deterministic equation dn/dt = κn(1–n), n(t) being the fraction of ice. In order to start the process of nucleation, a white noise fluctuation is invoked. This fluctuation is considered both additively and multiplicatively with respect to the deterministic equation. The mean first passage time, a quantity of direct physical interest, is calculated in both cases. With the multiplicative noise, the Itô–Stratonovich route is avoided through a suitable transformation of the Langevin equation and through the study of the resulting Fokker–Planck equation thereof.