Collision-induced absorption in the far infrared region in ethylene – rare gas mixtures

1982 ◽  
Vol 60 (10) ◽  
pp. 1431-1441 ◽  
Author(s):  
I. R. Dagg ◽  
L. A. A. Read ◽  
W. Smith
Keyword(s):  
Fourier Transform ◽  
Far Infrared ◽  
Infrared Region ◽  
Gas Mixtures ◽  
Laser Source ◽  
Rare Gas ◽  
Fourier Transform Spectrometer ◽  
Rare Gases ◽  
Absolute Value ◽  
Far Infrared Laser

The collision-induced spectra of mixtures of ethylene and each of the rare gases He, Ne, Ar, Kr, and Xe in the 40–360 cm−1 region has been obtained using a Michelson Fourier transform spectrometer. In addition, improved results for the collision-induced spectrum of pure ethylene gas are reported using this spectrometer as well as a far infrared laser source. All the results from the pure gas and gas mixtures have been analyzed according to the theory for quadrupolar-induced translation–rotational absorption. From this analysis the following values for the components of the quadrupolar tensor are: Qxx = −3.12, Qvy = 1.55, and Qzz = 1.57 B, which are somewhat lower estimates (in absolute value) than previously reported by us. Evidence for induction by other mechanisms (other than quadrupolar) has been obtained for the He–C2H4 and Ne–C2H4 mixtures.

Collision-induced absorption in ethane–rare gas mixtures

1983 ◽  
Vol 61 (4) ◽  
pp. 633-640 ◽  
Author(s):  
I. R. Dagg ◽  
L. A. A. Read ◽  
A. Anderson
Keyword(s):  
Fourier Transform ◽  
Temperature Dependence ◽  
Quadrupole Moment ◽  
Gas Mixtures ◽  
Rare Gas ◽  
Fourier Transform Spectrometer ◽  
Rare Gases ◽  
Induced Absorption ◽  
Absolute Value ◽  
The Absolute

The collision-induced spectra of mixtures of ethane and each of the rare gases He, Ar, Kr, and Xe in the 40–360 cm−1 region have been obtained using a Michelson Fourier transform spectrometer. In addition, the temperature dependence of the absorption in ethane and ethane–xenon mixtures is reported. All results have been analyzed according to the theory for quadrupole induced rotation–translation absorption. The absolute value of the quadrupole moment of ethane is estimated to be less than 1.0 B and most likely less than 0.5 B. Various speculations are made concerning the induction mechanisms (other than quadrupolar) for each of the mixtures.

Imaging Fourier transform spectrometer with photoconductive detector arrays: an application to the AKARI far-infrared instrument

2008 ◽  
Author(s):  
Mitsunobu Kawada ◽  
Hidenori Takahashi ◽  
Noriko Murakami ◽  
Yoko Okada ◽  
Akiko Yasuda ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Far Infrared ◽  
Fourier Transform Spectrometer ◽  
Detector Arrays ◽  
Photoconductive Detector

Design of an efficient broadband far-infrared fourier-transform spectrometer

1999 ◽  
Vol 38 (18) ◽  
pp. 3945 ◽  
Author(s):  
Bruno Carli ◽  
Alessandra Barbis ◽  
John E. Harries ◽  
Luca Palchetti
Keyword(s):  
Fourier Transform ◽  
Far Infrared ◽  
Fourier Transform Spectrometer

Ozone yields from the Febetron radiolysis of oxygen – rare gas mixtures

1977 ◽  
Vol 55 (2) ◽  
pp. 203-209 ◽  
Author(s):  
A. W. Boyd ◽  
O. A. Miller ◽  
E. B. Selkirk
Keyword(s):  
Excited State ◽  
Gas Mixtures ◽  
Rare Gas ◽  
Rare Gases

Ozone yields have been measured from the Febetron irradiation of mixtures containing 1–50 mol% oxygen and each of the five rare gases. The maximum values of G(O3) calculated using the energy absorbed only in the rare gas are obtained with the addition of less than 10% oxygen and are for: He, 16; Ne, 14; Ar, 11; Kr, 10; Xe, 12; each with an uncertainty of less than ±10%. On the addition of 0.2 mol% SF6 these yields are reduced to 6,5,1,2, and 2.5 respectively.These values are compared with those derived from ion and excited state yields and the contributions of subexcitation electrons.

COLLISION-INDUCED ABSORPTION OF COMPRESSED GASES IN THE FAR INFRARED, PART I

1965 ◽  
Vol 43 (5) ◽  
pp. 729-750 ◽  
Author(s):  
D. R. Bosomworth ◽  
H. P. Gush
Keyword(s):  
Fourier Analysis ◽  
Infrared Absorption ◽  
Michelson Interferometer ◽  
Far Infrared ◽  
Gas Mixtures ◽  
Experimental Techniques ◽  
Rare Gas ◽  
Absorption Coefficients ◽  
Induced Absorption ◽  
Separate Paper

A study is being made of the far infrared absorption occurring in compressed rare-gas mixtures, and compressed homonuclear diatomic gases. The region investigated lies between 20 and 400 cm−1. The spectra are obtained from the Fourier analysis of interferograms produced by a dynamic Michelson interferometer. It is possible to obtain accurate absolute absorption coefficients for broad bands using this method provided care is exercised in the analysis of the interferograms. The necessary precautions are discussed in detail. The precision of the method obtained in practice is demonstrated using the far infrared bands of hydrogen and nitrogen as examples. Only the experimental techniques are discussed in this paper; the detailed results follow in a separate paper.

Far-infrared high-resolution Fourier transform spectrometer

1987 ◽  
Vol 26 (18) ◽  
pp. 3818 ◽  
Author(s):  
Bruno Carli ◽  
Massimo Carlotti ◽  
Francesco Mencaraglia ◽  
Enzo Rossi
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Far Infrared ◽  
Fourier Transform Spectrometer

Collision-induced microwave absorption in gaseous mixtures of various rare gases at 2.3 cm−1

1980 ◽  
Vol 58 (5) ◽  
pp. 633-641 ◽  
Author(s):  
I. R. Dagg ◽  
W. D. Leckie ◽  
L. A. A. Read
Keyword(s):  
Microwave Absorption ◽  
Room Temperature ◽  
Infrared Region ◽  
Exponential Model ◽  
Rare Gas ◽  
Rare Gases ◽  
Gaseous Mixtures ◽  
Induced Dipole ◽  
Upper Limits ◽  
Density Ratios

Collision-induced microwave absorption has been observed at 2.3 cm−1 for the rare gas mixtures Ne–Kr, Ar–Kr, Ar–Xe, and Kr–Xe. The absorption coefficient has been measured at room temperature for density products up to 8000 amagat2 and for various density ratios. These results have been used in conjunction with those of the infrared region to determine more accurately the zeroth moment for each of the spectra and hence have allowed improved values for the induced dipole moment parameters for the exponential model. Upper limits to the absorption in He–Xe and He–Ar mixtures in the microwave region have also been established.

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