Mesure des intensités des bandes d'absorption rovibrationnelles 0 → 4 et 0 → 5 de l'acide iodhydrique gazeux

1978 ◽  
Vol 56 (6) ◽  
pp. 727-736 ◽  
Author(s):  
P. Niay ◽  
P. Bernage ◽  
C. Coquant ◽  
R. Houdart
Keyword(s):  
Dipole Moment ◽  
White Cell ◽  
Moment Function ◽  
Resolving Power ◽  
Absorption Bands ◽  
Moment Expansion ◽  
Expansion Series ◽  
Experimental Dipole Moment ◽  
Growth Method ◽  
Lorentz Profile

By using a SISAM spectrometer with a 0.03 cm−1 resolving power we have measured the line-strengths for the 4 ← 0 and 5 ← 0 absorption bands of the HI molecule. The pressure in the White cell was important enough to assume the lines to be described through a Lorentz profile, and we have used the 'curve of growth' method. By using all the available data on the 1 ← 0,2 ← 0, and 3 ← 0 bands, we have calculated the first six coefficients of the dipole moment expansion series. The shape of the experimental dipole moment function shows that the HI bond is primarily covalent.

Infrared Line and Band Strengths and Dipole Moment Function in HCl and DCl

1957 ◽  
Vol 26 (6) ◽  
pp. 1671-1677 ◽  
Author(s):  
William S. Benedict ◽  
Robert Herman ◽  
Gordon E. Moore ◽  
Shirleigh Silverman
Keyword(s):  
Dipole Moment ◽  
Moment Function

MCSCF calculation of the dipole moment function of CO

1981 ◽  
Vol 44 (1) ◽  
pp. 111-123 ◽  
Author(s):  
Hans-Joachim Werner
Keyword(s):  
Dipole Moment ◽  
Moment Function

Vibration-rotation bands and rotational constants of dideuteroacetylene

1955 ◽  
Vol 232 (1190) ◽  
pp. 291-309 ◽  
Keyword(s):  
Resolving Power ◽  
Vibrational States ◽  
Absorption Bands ◽  
Rotational Constants ◽  
Vibrational Assignments ◽  
Vibrational Anharmonicity ◽  
A Value ◽  
Vibrational Levels ◽  
Vibration Rotation ◽  
Very High

Nine vibrational absorption bands of dideutero-acetylene have been examined with very high resolving power. The rotational constants have been determined for the vibrational levels concerned, and the coefficients α i have been determined with more convincing accuracy than previously. In some of the bands the Q branches have been resolved, so that the l -doubling coefficients q i could be derived, and details could be established about the doublet components in some II levels. The results emphasize the need of high resolution if the vibrational assignments are to be unambiguous, and if reliable values of the rotational constants are to be derived. A value of B e has been obtained, and the vibrational anharmonicity coefficients have been considered briefly. Estimates of the centrifugal stretching constants D i in different vibrational states have been made, and one anomalous case has been found.

Notizen: The Dipole Moment Function of HF Molecule Using Morse Potential

1977 ◽  
Vol 32 (8) ◽  
pp. 897-898 ◽  
Author(s):  
Y. K. Chan ◽  
B. S. Rao
Keyword(s):  
Wave Equation ◽  
Dipole Moment ◽  
Potential Function ◽  
Electric Dipole ◽  
Morse Potential ◽  
Moment Function ◽  
Matrix Elements ◽  
The Matrix ◽  
Vibration Rotation ◽  
Experimental Values

Abstract The radial Schrödinger wave equation with Morse potential function is solved for HF molecule. The resulting vibration-rotation eigenfunctions are then used to compute the matrix elements of (r - re)n. These are combined with the experimental values of the electric dipole matrix elements to calculate the dipole moment coefficients, M 1 and M 2.

IR Spectra and dipole moment function of the H2S molecule in the gas and liquid phases

2013 ◽  
Vol 7 (6) ◽  
pp. 721-733 ◽  
Author(s):  
Sh. Sh. Nabiev ◽  
L. A. Palkina ◽  
V. I. Starikov
Keyword(s):  
Dipole Moment ◽  
Ir Spectra ◽  
Moment Function ◽  
Liquid Phases
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