High resolution spectrum of GdO

1976 ◽  
Vol 54 (24) ◽  
pp. 2429-2434 ◽  
Author(s):  
B. R. Yadav ◽  
S. B. Rai ◽  
D. K. Rai
Keyword(s):  
High Resolution ◽  
Emission Spectrum ◽  
Visible Emission ◽  
High Resolution Spectrum ◽  
First Order ◽  
Isotopic Shifts ◽  
Vibrational Constants ◽  
Dc Arc

The visible emission spectrum of the GdO molecule has been produced in a DC arc source and has been photographed in the first order of a 10.6 m grating spectrograph. Bands are shown to have a six-headed structure and improved vibrational constants have been obtained in this study. Isotopic shifts have been calculated for the various isotopic molecules. Tentative suggestions regarding the nature of the transition have been made.

The emission spectrum of ReO between 375 and 875 nm: A classification based on rotational analysis and Re16O/Re18O isotope shifts

1984 ◽  
Vol 62 (12) ◽  
pp. 1524-1537 ◽  
Author(s):  
Walter J. Balfour ◽  
Ram. S. Ram
Keyword(s):  
High Resolution ◽  
Emission Spectrum ◽  
Electronic States ◽  
Electronic Transitions ◽  
Lower State ◽  
Rotational Analysis ◽  
Isotope Shifts ◽  
Isotopic Shifts

The emission spectrum of the ReO molecule has been photographed under high resolution between 375 and 875 nm. In addition to the 711.9 and 404.5 nm systems previously studied a large number of new electronic transitions have been classified on the basis of Re16O/Re18O isotopic shifts. The rotational structures of 18 bands of Re16O and 1 band of Re18O have been analyzed. Two low-lying electronic states in addition to the known common lower state of the 711.9 and 404.5 nm systems have been identified.

Spectrum of AsS. I. Analysis of the A′2Π3/2–X2Π3/2 Band System

1971 ◽  
Vol 49 (10) ◽  
pp. 1249-1254 ◽  
Author(s):  
Midori Shimauchi
Keyword(s):  
High Resolution ◽  
Emission Spectrum ◽  
Ground State ◽  
Band System ◽  
Vibrational Analysis ◽  
Quartz Tube ◽  
Rotational Analysis ◽  
Vibrational Constants

The emission spectrum of the AsS radical, excited in a quartz tube by a 2450 MHz oscillator, was photographed on a high resolution spectrograph from 2450 to 6900 Å. Seven bands around 6000 Å showing clear rotational structures were chosen for the first rotational analysis of the AsS spectrum. The bands were found to arise from a 2Π3/2–2Π3/2 transition. The rotational and vibrational constants of the two states derived from the present work are consistent with the previous vibrational analysis of the A′2Π3/2–X2Π3/2 system. The constants of the upper doublet component of the ground state, X2Π3/2, are ωe = 562.40 cm−1, ωexe = 2.02 cm−1, re = 2.0216 Å; the constants of the A′2Π3/2 state are ΔG′(1/2) = 403.37 cm−1, ν0,0 = 18 621.21 cm−1, re = 2.2500 Å.

The Ground State and A2Π Excited State of Magnesium Deuteride

1975 ◽  
Vol 53 (15) ◽  
pp. 1477-1482 ◽  
Author(s):  
Walter J. Balfour ◽  
Hugh M. Cartwright
Keyword(s):  
Excited State ◽  
High Resolution ◽  
Emission Spectrum ◽  
Isotope Effect ◽  
Ground State ◽  
Visible Emission ◽  
Molecular Constants ◽  
Dissociation Energies ◽  
First Time ◽  
Π State

The visible emission spectrum of MgD has been reexamined at high resolution. Published analyses of the A2Π → X2Σ+ system have been extended and the data have been combined with observations in the B′2Σ+ → X2Σ+ system to provide information on the ground state levels ν = 3, 4, 5, and 6 for the first time. The following molecular constants (in cm−1) have been determined—for the A2Π state: ωc = 1154.75, ωcxc = 16.675, Bc = 3.2190, Dc = 9.64 × 10−5 and for the X2Σ+ state: ωc = 1077.71, ωcxc = 15.92, Bc = 3.0306, and Dc = 9.39 × 10−5. The dissociation energies in the A2Π and X2Σ+ states have been estimated to be ~ 15 500 cm−1 and ~ 11 500 cm−1 respectively. The MgH/MgD isotope effect and the Λ doubling in the A2Π state are discussed.

The Electronic Spectrum of HF+

1975 ◽  
Vol 53 (11) ◽  
pp. 1097-1108 ◽  
Author(s):  
S. Gewurtz ◽  
H. Lew ◽  
P. Flainek
Keyword(s):  
High Resolution ◽  
Emission Spectrum ◽  
Electronic Spectrum ◽  
Dissociation Energy ◽  
Theoretical Calculations ◽  
Detailed Comparison ◽  
X State ◽  
Vibrational Constants

The A2Σ+–X2Π emission spectrum of HF+, between 3580 and 4830 Å, has been photographed at high resolution and measurements on eight bands are reported. The analysis yields rotational and vibrational constants of the X state for ν = 0 to 2 and of the A state for ν = 0 to 3. A predissociation by rotation in the A2Σ+ state is observed and yields a dissociation energy of 3203 ± 50 cm−1 above the ν = 0, N = 0 level of this state. It is shown that this corresponds to a dissociation into H+(1S) + F(2P1/2). A detailed comparison with previous results obtained from photoelectron and photoionization experiments and from recent theoretical calculations is given.

HIGH RESOLUTION CALORIMETRIC STUDIES AT PHASE TRANSITIONS OF ALKYLCYANOBIPHENYL LIQUID CRYSTALS CONFINED TO SUBMICRON SIZE CYLINDRICAL CAVITIES

1995 ◽  
Vol 09 (18n19) ◽  
pp. 2247-2283 ◽  
Author(s):  
DANIELE FINOTELLO ◽  
GERMANO S. IANNACCHIONE
Keyword(s):  
Phase Transitions ◽  
Liquid Crystals ◽  
High Resolution ◽  
Specific Heat ◽  
Pore Wall ◽  
Isotropic Phase ◽  
First Order ◽  
Smectic A ◽  
Nematic Director ◽  
Scalar Order Parameter

We review results of a high resolution systematic study of the specific heat for alkyl-cyanobiphenyl liquid crystals confined to the 0.2µm diameter cylindrical pores Anopore membranes. The nematic director alignment at the pore wall is varied from homeotropic to tangential by pore surface treatment. Several phenomena are uncovered by these studies which probed the weakly first order nematic to isotropic, the continuous smectic-A to nematic and the first order smectic-A to isotropic phase transitions. The specific heat is strongly dependent on the nematic director configuration, and confinement effects are remarkably distinct according to the order of the phase transition. The influence of elastic distortions and surface ordering and disordering effects are evident. Despite considerable departures from bulk behavior with regards to specific heat peaks size, rounding and width, and transition temperature shifts, a bulk-like critical behavior appears to be retained. The formation of smectic translational order within the pores is hindered for those liquid crystals that also possess a nematic phase. The average scalar order parameter temperature dependence is extracted from the specific heat results using a simplified Landau-de Gennes type of model, and is shown to be consistent with nuclear magnetic resonance results.

Study of the high resolution spectrum of 32 S 16 O 18 O: The ν 1 and ν 3 bands

2016 ◽  
Vol 168 ◽  
pp. 29-39 ◽  
Author(s):  
O.N. Ulenikov ◽  
E.S. Bekhtereva ◽  
Yu.V. Krivchikova ◽  
V.A. Zamotaeva ◽  
T. Buttersack ◽  
...  
Keyword(s):  
High Resolution ◽  
High Resolution Spectrum ◽  
O 18

High resolution Fourier spectroscopy of P2 infrared emission spectrum

1978 ◽  
Vol 72 (2) ◽  
pp. 189-199 ◽  
Author(s):  
C Amiot ◽  
C Effantin ◽  
J d'Incan ◽  
J Verges
Keyword(s):  
High Resolution ◽  
Emission Spectrum ◽  
Infrared Emission ◽  
Fourier Spectroscopy

High resolution spectrum of NO2 loosely bound states: densities of states and long range forces

2001 ◽  
Vol 3 (12) ◽  
pp. 2268-2274 ◽  
Author(s):  
Sylvain Heilliette ◽  
Antoine Delon ◽  
Patrick Dupre´ ◽  
Re´my Jost
Keyword(s):  
High Resolution ◽  
Long Range ◽  
Bound States ◽  
High Resolution Spectrum ◽  
Densities Of States
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