Torsional Potential Function of Glyoxal

1975 ◽  
Vol 53 (19) ◽  
pp. 1832-1837 ◽  
Author(s):  
J. R. Durig ◽  
W. E. Bucy ◽  
A. R. H. Cole
Keyword(s):  
Potential Function ◽  
Raman Spectra ◽  
Molecular Geometry ◽  
Potential Functions ◽  
Infrared And Raman Spectra ◽  
Intensity Data ◽  
Vibrational Assignments ◽  
Torsional Potential ◽  
Trans Conformer ◽  
Infrared Data

We have shown, using the fact that glyoxal exists in the trans conformer and the pseudo stable cis conformer, a potential function can be calculated which fits the infrared data of the trans conformer and the microwave intensity data of the cis conformer. This potential function was extended to the d1 and d2 analogs. A study of the potential function of 1,3-butadiene using a different molecular geometry than was previously used was undertaken. Results are presented with different possible vibrational assignments and potential functions which would be consistent with the observed infrared and Raman spectra.

The single vibronic level fluorescence and Raman spectra of styrene-β-D2 vapor and their use in determining the C(1)-C(α) torsional potential function in the state

1982 ◽  
Vol 94 (2) ◽  
pp. 437-455 ◽  
Author(s):  
J.Michael Hollas ◽  
Hamdan Musa ◽  
Trevor Ridley ◽  
Paul H. Turner ◽  
Klaus H. Weisenberger ◽  
...  
Keyword(s):  
Potential Function ◽  
Raman Spectra ◽  
The State ◽  
Torsional Potential ◽  
Vibronic Level

Infrared and Raman Spectra, Conformational Stability,abInitioCalculations, and Vibrational Assignments for Cyclopropylchlorosilane

1997 ◽  
Vol 101 (46) ◽  
pp. 8614-8624 ◽  
Author(s):  
T. K. Gounev ◽  
Jeffery W. Weston ◽  
Shiyu Shen ◽  
M. Dakkouri ◽  
A. Grunvogel-Hurst ◽  
...  
Keyword(s):  
Raman Spectra ◽  
Conformational Stability ◽  
Infrared And Raman Spectra ◽  
Vibrational Assignments
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