Induced Anisotropy and Light Scattering in Liquids. II.
Keyword(s):
The spectra of light scattered by molecular liquids have been studied in order to obtain information about motions in the liquid on a time scale of 10−11 to 10−13 s. Integrated intensities and polarization ratios were measured. The spectra were decomposed by least squares curve fitting techniques into two components: a narrow component of Lorentzian form with line width approximately constant for all the liquids, and a broad component of the form [Formula: see text] with a line width parameter 1/ν0 equal to 2πγ−1(μ/kT)1/2. The proportionality constant γ−1 has the value of 0.62 Å for all the liquids studied. This interaction length appears to be common to all liquids.