High Field Stark Effects in CH and NH

1974 ◽  
Vol 52 (15) ◽  
pp. 1429-1437 ◽  
Author(s):  
E. A. Scarl ◽  
F. W. Dalby
Keyword(s):  
Dipole Moment ◽  
Electric Fields ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
High Field ◽  
Dipole Moments ◽  
Optical Spectra ◽  
Vibrational States ◽  
Stark Effects

A LoSurdo discharge was used to apply electric fields of up to 290 kV/cm to a mixture of cyanogen and hydrogen, and to ammonia, permitting the observation of Stark effects in the optical spectra of the CH and NH molecules, respectively. These experiments yielded the following values of the molecular electric dipole moment in the ground vibrational states: μ(CH, A2Δ) = 0.887 ± 0.045 D, and μ(NH, X3Σ) = 1.389 ± 0.075 D. A table of experimental and theoretical dipole moments of first-row hydrides is included.

scholarly journals DERIVATION OF GENERALIZED THOMAS–BARGMANN–MICHEL–TELEGDI EQUATION FOR A PARTICLE WITH ELECTRIC DIPOLE MOMENT

2013 ◽  
Vol 28 (29) ◽  
pp. 1350147 ◽  
Author(s):  
TAKESHI FUKUYAMA ◽  
ALEXANDER J. SILENKO
Keyword(s):  
Dipole Moment ◽  
Electromagnetic Fields ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Dipole Moments ◽  
Classical Equation ◽  
Spin Motion ◽  
Electric Dipole Moments ◽  
Momentum Direction ◽  
Telegdi Equation

General classical equation of spin motion is explicitly derived for a particle with magnetic and electric dipole moments in electromagnetic fields. Equation describing the spin motion relative to the momentum direction in storage rings is also obtained.

scholarly journals Динамика фотоиндуцированного вращения сферической частицы в постоянном электрическом поле

2019 ◽  
Vol 89 (1) ◽  
pp. 5
Author(s):  
А.И. Грачев
Keyword(s):  
Dipole Moment ◽  
Electric Field ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Dipole Moments ◽  
Constant Electric Field ◽  
Rotation Effect ◽  
General Terms ◽  
Nonspherical Shape ◽  
Rotation Dynamics

AbstractThe rotation of a spherical particle in a constant electric field (an effect found earlier) has been analyzed. The particle is illuminated to induce the electric dipole moment of the sphere. The dynamics of the rotation effect has been considered in general terms to refine conditions for adiabatic rotation. The features of the particle’s nonadiabatic rotation have been demonstrated with a sphere placed in a medium with an infinitesimal viscosity. It has been shown that the nonadiabatic rotation dynamics to a great extent depends on a relationship between the electrical and photoinduced dipole moments of the sphere. The rotation dynamics of a particle with a slightly nonspherical shape has been briefly analyzed.

Elektrisches Dipolmoment von TlBr und TlJ

1971 ◽  
Vol 26 (11) ◽  
pp. 1809-1812 ◽  
Author(s):  
E. Tiemann
Keyword(s):  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Vibrational State ◽  
Stark Effect ◽  
Dipole Moments ◽  
Electric Dipole Moments ◽  
Ground Vibrational State ◽  
Rotational Transitions

Stark-effect measurements on pure rotational transitions of TlBr and Til are described. The derived electric dipole moments of the most abundant isotopic molecules on the ground vibrational state are:205TL79Br : | μ0| = (4.493 ± 0.050) D , 205Tl127 I | μ 0| =(4.607 ± 0.070) D .The electric dipole moment of 205Tl19F | μ 0|=4.2282 (8) D was used as standard.

Electronic structure of POPC phospholipids under constant electric field

2017 ◽  
Vol 31 (22) ◽  
pp. 1750157
Author(s):  
Jaciéli Evangelho de Figueiredo ◽  
Leandro Barros da Silva
Keyword(s):  
Electronic Structure ◽  
Dipole Moment ◽  
External Field ◽  
Electric Field ◽  
Electric Fields ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Constant Electric Field ◽  
Ab Initio Study ◽  
Electronic And Structural Properties

We report in the present paper an ab initio study on the electronic and structural properties of phospholipidic membranes under the influence of electric fields. We show that the external field alters the charge distribution of the molecule leading to a modification in the electric dipole moment. The torque on the phospholipid may then cause a transmembranar stress, which by its turn, weakens the membrane allowing to the formation of a pore.

Probing new CP-odd thresholds with electric dipole moments

2007 ◽  
Vol 85 (6) ◽  
pp. 597-606
Author(s):  
A Ritz
Keyword(s):  
Dipole Moment ◽  
Cp Violation ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Dipole Moments ◽  
New Physics ◽  
Electric Dipole Moments ◽  
Higher Dimensional ◽  
The Status ◽  
Generic Class

We dicuss the utility of precision probes for flavour-diagonal CP-violation, namely, searches for electric dipole moments of nucleons, atoms, and molecules, in looking for new physics thresholds that manifest themselves primarily through higher dimensional operators. After reviewing the status of the electric dipole moment (EDM) constraints, we consider first the sensitivity to a generic class of dimension-five operators generated at a supersymmetric threshold, through their contribution to CP- and flavour-violating observables. Such thresholds can be probed by EDMs up to a scale of order 108 GeV depending on the flavour structure. We then turn to consider the possibility that electroweak baryogenesis is made feasible by the introduction of dimension-six operators at a TeV-scale threshold. The EDM costraints on dimension-six couplings of the Higgs to the fermions currently still allow a reasonable window in parameter space for these models, but the next generation of experiments should provide a conclusive test. PACS Nos.: 11.30.Er, 12.60.Fr, 12.60.Jv

High-Field Stark Effects on the Near Ultraviolet Spectrum of the Hydroxyl Radical

1971 ◽  
Vol 49 (22) ◽  
pp. 2825-2832 ◽  
Author(s):  
Ethan A. Scarl ◽  
F. W. Dalby
Keyword(s):  
Dipole Moment ◽  
Hydroxyl Radical ◽  
Electric Fields ◽  
High Field ◽  
Transition Probability ◽  
Ultraviolet Spectrum ◽  
Vibrational Transition ◽  
Near Ultraviolet ◽  
Stark Effects ◽  
Π State

Spectra due to the A2Σ+–X2Π transition of the hydroxyl radical in electric fields of over 300 000 V per cm have been obtained. The dipole moment of the A2Σ+ ν = 0 state of OH has been determined to be (1.98 ± 0.08) D. From the variation of the dipole moment with vibrational quantum number in the 2Π state, the transition probability for the pure vibrational transition ν = 1 →ν = 0 has been estimated to be A10 = 80s−1.

Molecular g-Values, Magnetic Susceptibility Anisotropies, Molecular Quadrupole Moments and Second Moments of the Electron Charge Distribution in Ethyleneoxide and Pyridine Isotopes. An Attempt to Determine the Sign of the Electric Dipole Moment

1976 ◽  
Vol 31 (3-4) ◽  
pp. 265-271 ◽  
Author(s):  
E. Hamer ◽  
D. H. Sutter
Keyword(s):  
Dipole Moment ◽  
Electric Dipole ◽  
High Field ◽  
Dipole Moments ◽  
Zeeman Effect ◽  
Quadrupole Moments ◽  
Electron Charge ◽  
Electric Dipole Moments ◽  
Second Moments ◽  
Electron Charge Distribution

The high-field first and second order Zeeman effect has been observed in Ethyleneoxidein order to determine the sign of the electric dipole moments from the g-values of different isotopes. The experimental data indicate that in Ethyleneoxide the negative end is at the Oxygen while in Pyridine the result is not conclusive. The effect of vibrations is discussed in some detail and it is concluded that the vibrational dependance of the g-values should be accounted for if the sign of the dipole moment is determined from Zeeman data (at least if H ↔ D substitutions are involved).

Electric Dipole Moment Investigation of Buttressing in Alkyl Duryl Ketones

1975 ◽  
Vol 53 (13) ◽  
pp. 2024-2030 ◽  
Author(s):  
A. George Pinkus ◽  
Herman C. Custard Jr.
Keyword(s):  
Dipole Moment ◽  
Carbonyl Group ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Alkyl Group ◽  
Dipole Moments ◽  
Electron Delocalization ◽  
Methyl Groups ◽  
Method Of Calculation

Dipole moments (D) determined for the following alkyl duryl ketones in benzene at 30° were: Me, 2.83; Et, 2.80; i-Pr, 2.74; t-Bu, 2.65. The decrease in the series is explained by increasing rotational restriction about the carbonyl group due to an increasing interference by the ortho methyl groups with the alkyl group. This results in a greater twist from coplanarity between the ring and carbonyl and less π-electron delocalization and consequently a lower dipole moment as the size of the alkyl increases. The increase observed for the duryl ketone moments over those of corresponding mesityl ketones is tentatively explained as due to a higher duryl group moment relative to the mesityl moment. The interplanar angles (angles of twist) for the duryl ketones calculated with the Braude–Sondheimer equation were slightly larger than those calculated for the mesityl ketones, the magnitude depending on the method of calculation. It is tentatively concluded that evidence from dipole moment data indicates that a small buttressing effect exists in the duryl ketone system.

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