Dynamics of the CO2 Atmospheric Pressure Laser with Transverse Pulse Excitation

1972 ◽  
Vol 50 (20) ◽  
pp. 2523-2535 ◽  
Author(s):  
J. Gilbert ◽  
J. L. Lachambre ◽  
F. Rheault ◽  
R. Fortin
Keyword(s):  
Atmospheric Pressure ◽  
Laser Emission ◽  
Initial Conditions ◽  
Energy State ◽  
Laser Action ◽  
Rate Equations ◽  
Pulse Excitation ◽  
Gain Switching ◽  
Strong Current ◽  
Kinetics Of

The dynamical processes responsible for laser emission in the pulsed pumping of a transversely excited atmospheric (TEA) CO2 laser are investigated. An explanation for the formation of the giant pulse is proposed on the basis of a gain-switching mechanism in which it is assumed that with short strong-current pulses a high population inversion can be achieved prior to the onset of laser action. The kinetics of the mechanism are described by means of a set of nonlinear rate equations idealized to a four-energy-state system. With suitable initial conditions on the populations, the transient solution of these equations for the mixtures CO2–He and CO–N2–He appears to be consistent with the major features of experimental observation.

scholarly journals Statistics of the Optical Phase of a Gain-Switched Semiconductor Laser for Fast Quantum Randomness Generation

Photonics ◽  
2021 ◽  
Vol 8 (9) ◽  
pp. 388
Author(s):  
Angel Valle
Keyword(s):  
Semiconductor Laser ◽  
Initial Conditions ◽  
Dynamical Evolution ◽  
Random Number Generation ◽  
Rate Equations ◽  
Optical Phase ◽  
Semiconductor Laser Diode ◽  
Gain Switching ◽  
Kurtosis Coefficient ◽  
Modulation Speed

The statistics of the optical phase of the light emitted by a semiconductor laser diode when subject to periodic modulation of the applied bias current are theoretically analyzed. Numerical simulations of the stochastic rate equations describing the previous system are performed to describe the temporal dependence of the phase statistics. These simulations are performed by considering two cases corresponding to random and deterministic initial conditions. In contrast to the Gaussian character of the phase that has been assumed in previous works, we show that the phase is not distributed as a Gaussian during the initial stages of evolution. We characterize the time it takes the phase to become Gaussian by calculating the dynamical evolution of the kurtosis coefficient of the phase. We show that, under the typical gain-switching with square-wave modulation used for quantum random number generation, quantity is in the ns time scale; that corresponds to the time it takes the system to lose the memory of the distribution of the initial conditions. We compare the standard deviation of the phase obtained with random and deterministic initial conditions to show that their differences become more important as the modulation speed is increased.

Kinetics of the catalytic hydrodesulphurization reaction system; hydrogenolysis of thiophene

1980 ◽  
Vol 45 (10) ◽  
pp. 2728-2741 ◽  
Author(s):  
Pavel Fott ◽  
Petr Schneider
Keyword(s):  
Atmospheric Pressure ◽  
Active Sites ◽  
Flow Reactor ◽  
Kinetic Equations ◽  
Reaction System ◽  
Reaction Products ◽  
Molybdenum Catalyst ◽  
Cobalt Molybdenum Catalyst ◽  
Kinetics Of ◽  
Reaction Schemes

Kinetics have been studied of the reaction system taking place during the reaction of thiophene on the cobalt-molybdenum catalyst in a gradientless circulation flow reactor at 360 °C and atmospheric pressure. Butane has been found present in a small amount in the reaction products even at very low conversion. In view of this, consecutive and parallel-consecutive (triangular) reaction schemes have been proposed. In the former scheme the appearance of butane is accounted for by rate of desorption of butene being comparable with the rate of its hydrogenation. According to the latter scheme part of the butane originates from thiophene via a different route than through hydrogenation of butene. Analysis of the kinetic data has revealed that the reaction of thiophene should be considered to take place on other active sites than that of butene. Kinetic equations derived on this assumption for the consecutive and the triangular reaction schemes correlate experimental data with acceptable accuracy.

Nanostructured Doped Silica Films Application as Sensitive Layers for Chemical Sensors

2013 ◽  
Vol 684 ◽  
pp. 7-11
Author(s):  
Sergey Krutovertsev ◽  
Alla Tarasova ◽  
Olga Ivanova ◽  
Larisa Krutovertseva
Keyword(s):  
Initial Conditions ◽  
Sol Gel ◽  
Silica Films ◽  
Adsorption Activity ◽  
Developed Surface ◽  
Sol Gel Process ◽  
Sensitive Characteristics ◽  
The Right ◽  
Kinetics Of ◽  
Matrix Factors

The sensor behavior of nanostructured doped silica films produced by sol-gel way were examined. Hygroscopic substances and polyoxometalates were used as additives to make more significant sensitive characteristics of initial matrix. Factors that have effect on sol preparation and films forming were investigated. Adsorption activity of the sensitive films was studied and it was shown that the films had a highly developed surface with nano-size pores. Change of initial conditions of sol-gel process gives opportunity to influence on kinetics of gel formation and consequently, on structure and properties of final materials. The study showed that the conditions of the environment affected the sensors characteristics markedly, which can be improved by choosing of the right procedure of forming and treatment. Influence of type and additive substances quantity into doped films was discussed in the paper

Kinetic Study of the Diels-Alder Reaction of Cyclopentadiene with Bis(2-Ethylhexyl) Maleate

2013 ◽  
Vol 634-638 ◽  
pp. 541-545 ◽  
Author(s):  
Jun Seong Park ◽  
Dae Hee Yun ◽  
Tae Won Ko ◽  
Yong Sung Park ◽  
Je Wan Woo
Keyword(s):  
Kinetic Study ◽  
Reaction Temperature ◽  
Atmospheric Pressure ◽  
Arrhenius Equation ◽  
Alder Reaction ◽  
Diels Alder ◽  
Influence Of Temperature ◽  
Diels Alder Reaction ◽  
Influence Of Temperature On ◽  
Kinetics Of

The kinetics of the Diels-Alder reaction of cyclopentadiene with bis(2-ethylhexyl) maleate has been studied at temperatures between 25 and 100 °C and at atmospheric pressure. The influence of temperature on the kinetic constants was determined by fitting the results to the Arrhenius equation. As a result, fitting line similar with the linear curve of the Arrhenius equation at 25, 30 and 40 °C. However, the fitting curve, at 60, 80 and 100 °C, tended towards the outside of the curve in the form of Arrhenius equation. The ratio of endo/exo was a slight change from increase of the reaction temperature.

scholarly journals A Labile Metallo-Porphyrin as Tool to Control J-Aggregates Chiroptical Properties

2020 ◽  
Author(s):  
Luigi Monsù Scolaro ◽  
Ilaria Occhiuto ◽  
Mariachiara Trapani ◽  
ROBERTO ZAGAMI ◽  
Andrea Romeo ◽  
...  
Keyword(s):  
Dipolar Coupling ◽  
Initial Conditions ◽  
Coupling Mechanism ◽  
Precise Control ◽  
Rate Determining Step ◽  
Initial Nucleus ◽  
Acidic Conditions ◽  
J Aggregates ◽  
Kinetics Of ◽  
Autocatalytic Growth

The zinc(II) metal derivative of 5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin (TPPS4) is quite labile and readily demetallates under acidic conditions, affording the parent diacid porphyrin in a monomeric form. The rate of this process is first order on [ZnTPPS4] and second order on [H+], allowing a precise control of the monomer release in solution. Under high ionic strength, this latter species is able to self-assemble into J-aggregates, whose kinetics of growth are largely modulated by pH. The aggregation kinetics have been treated according to a well-established model, in which the formation of an initial nucleus is the rate determining step preceding the autocatalytic growth of the whole assembly. The extinction spectra of the aggregates suggest the occurrence of a dipolar coupling mechanism very similar to that operating in metal nanoparticles. Spontaneous symmetry breaking takes place in these aggregates as evidenced by unusual circular dichroism spectra. The intensity and sign of the effect is controlled by the aggregation rate and therefore can be tuned through a proper choice of initial conditions.

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