On the Stability of Precipitate–Matrix Interfaces in Dilute Ternary Systems

1971 ◽  
Vol 49 (13) ◽  
pp. 1805-1812
Author(s):  
D. E. Coates
Keyword(s):  
Stability Criterion ◽  
Perturbation Methods ◽  
Ternary Systems ◽  
Linear Perturbation ◽  
Matrix Interface ◽  
Interface Stability ◽  
Diffusional Interaction ◽  
General Stability ◽  
The Stability

Using linear perturbation methods, a precipitate–matrix interface stability criterion is obtained for dilute ternary systems. The calculation takes account of capillarity, transport in the precipitate, and ternary diffusional interaction. The general stability criterion contains a term reflecting the destabilizing influence of the solute gradients (i.e., the point effect of diffusion) and a term representing the stabilizing influence of capillarity. Two limiting cases are treated in detail—insignificant transport in the precipitate and negligible ternary diffusional interaction. It is demonstrated that in these two cases the two solutes behave in a cumulative fashion.

scholarly journals Stability of Modified Korteweg?de Vries Waves

1987 ◽  
Vol 40 (5) ◽  
pp. 593 ◽  
Author(s):  
K Murawski
Keyword(s):  
Nonlinear Wave ◽  
Stability Criterion ◽  
Wave Theory ◽  
General Stability ◽  
De Vries ◽  
The Stability

A nonlinear wave theory is developed on the basis of the Infeld-Rowlands method to study the stability of modified Korteweg-de Vries waves. A general stability criterion is derived in order to show that unstable waves exist.

In the stability of paints and varnishes for protective and decorative wood finish

2016 ◽  
Author(s):  
Ю.И. Цой
Keyword(s):  
Organic Solvents ◽  
Evaluation Criteria ◽  
Ternary Systems ◽  
Solubility Parameters ◽  
Formaldehyde Resin ◽  
Film Forming ◽  
The Difference ◽  
Molecular Forces ◽  
The Stability ◽  
Thermodynamic Interaction

Задача получения однородного состава ЛКМ сводится к правильному выбору пленкообразователей и соответствующих растворителей и, в случае необходимости, разбавителей и добавок. На основе положений теории растворимости была проведена оценка совместимости компонентов и стабильности таких систем. Критериями оценки были приняты параметры растворимости и термодинамического взаимодействия. Исследовали совместимость алкидных лаков с аминоформальдегидными смолами в бутаноле, и результаты этих исследований представлены в треугольной фазовой диаграмме. Для оценки совместимости смол по результатам расчета параметров термодинамического взаимодействия были построены спинодали для тройных систем. Как показывает анализ результатов проведенных исследований, даже при большой разности ?? = |?12 – ?13| = 0,2 наблюдается небольшая область несовместимости. С уменьшением разности ?? область несовместимости сужается. При ?23 > ?с область несовместимости расширяется как для ? = 0,2, так и для ?? = 0,1 и ?? = 0. Таким образом, для таких систем на совместимость компонентов, в первую очередь, влияет их взаимодействие между собой – чем оно больше, тем лучше они совместимы. Проведенные исследования показали, что парциальные параметры растворимости, учитывающие природу когезионных сил, более объективно характеризуют растворимость пленкообразующих смол в органических растворителях, чем их общий параметр растворимости. Растворимость пленкообразующих алкидных и этерифицированных аминоформальдегидных смол в органических растворителях обусловлена термодинамическим взаимодействием молекулярных сил различной природы. Стабильность смеси алкидной и этерифицированной аминоформальдегидной смолы в бутаноле обусловлена в большей степени термодинамическим взаимодействием молекулярных сил; при этом степень бутанолизации меламиноформальдегидной смолы оказывает наибольшее влияние на стабильность cистемы. Проведенные исследования по стабильности лакокрасочных смесей из различных пленкообразующих смол на основе рассмотренных критериев оценки могут быть использованы для совершенствования технологии защитно-декоративной отделки древесины. The problem of obtaining a homogeneous composition of the coatings is reduced to the proper selection of film-forming agents, and diluent and, if appropriate, diluents and additives. On the basis of the theory of solubility, we have carried out the assessment of the compatibility of the components and stability of such systems. The evaluation criteria were adopted the parameters of the solubility and thermodynamic interaction. Researched the compatibility with alkyd varnishes aminoformaldehyde resin in butanol, and the results of these studies are presented in the triangular phase diagram. To evaluate the compatibility of the resins according to the results of calculation of thermodynamic parameters of interaction were built spinodal for ternary systems. As the analysis of the results of the studies, even when the difference ??|?12 – ?13| = 0,2 there is a small area of incompatibility. With the decrease of the difference ? ? region incompatibility narrows. When ?23> ?с region incompatibility extends to ?? = 0,2, and for ?? = 0.1 and ?? = 0. Thus, for such systems, compatibility of components, primarily, affects their interaction with each other – the further away it is, the better they are compatible. Studies have shown that the partial solubility parameters, which take into account the nature of cohesive forces, more objectively characterize the solubility of film-forming resins in organic solvents than their total solubility parameter. The solubility and film-forming aminoformaldehyde esterified alkyd resins in organic solvents due to thermodynamic interaction of molecular forces of different nature. Тhe stability of the mixture and aminoformaldehyde esterified alkyd resin in butanol is generated largely by thermodynamic forces of molecular interaction; the degree of butanolate melamine-formaldehyde resin has the greatest effect on the stability of the system. Conducted research on the stability of the paint mixtures of various film-forming resins on the basis of the evaluation criteria can be used to improve the technology of protective and decorative wood finish.

Intrinsic Thermal Stability of Anisotropic Thin-Film Superconductors

1990 ◽  
Vol 112 (1) ◽  
pp. 10-15 ◽  
Author(s):  
M. I. Flik ◽  
C. L. Tien
Keyword(s):  
Thin Film ◽  
Thermal Stability ◽  
Stability Criterion ◽  
High Temperature Superconductors ◽  
Stability Criteria ◽  
Anisotropic Thermal Conductivity ◽  
Operating Current ◽  
Released Energy ◽  
The Stability ◽  
Thermal Stability Of

Intrinsic thermal stability denotes a situation where a superconductor can carry the operating current without resistance at all times after the occurrence of a localized release of thermal energy. This novel stability criterion is different from the cryogenic stability criteria for magnets and has particular relevance to thin-film superconductors. Crystals of ceramic high-temperature superconductors are likely to exhibit anisotropic thermal conductivity. The resultant anisotropy of highly oriented films of superconductors greatly influences their thermal stability. This work presents an analysis for the maximum operating current density that ensures intrinsic stability. The stability criterion depends on the amount of released energy, the Biot number, the aspect ratio, and the ratio of the thermal conductivities in the plane of the film and normal to it.

On the Stability of the Linearly Related Modes of Certain Nonlinear Two-Degree-of-Freedom Systems

1961 ◽  
Vol 28 (1) ◽  
pp. 71-77 ◽  
Author(s):  
C. P. Atkinson
Keyword(s):  
Nonlinear Differential Equations ◽  
Mass Ratio ◽  
Positive Mass ◽  
Fourth Degree ◽  
Real Roots ◽  
General Stability ◽  
The Stability ◽  
The Masses ◽  
Spring Constants ◽  
Two Degree Of Freedom

This paper presents a method for analyzing a pair of coupled nonlinear differential equations of the Duffing type in order to determine whether linearly related modal oscillations of the system are possible. The system has two masses, a coupling spring and two anchor springs. For the systems studied, the anchor springs are symmetric but the masses are not. The method requires the solution of a polynomial of fourth degree which reduces to a quadratic because of the symmetric springs. The roots are a function of the spring constants. When a particular set of spring constants is chosen, roots can be found which are then used to set the necessary mass ratio for linear modal oscillations. Limits on the ranges of spring-constant ratios for real roots and positive-mass ratios are given. A general stability analysis is presented with expressions for the stability in terms of the spring constants and masses. Two specific examples are given.

The flow of a micropolar liquid layer down an inclined plane

1968 ◽  
Vol 64 (2) ◽  
pp. 513-526 ◽  
Author(s):  
A. J. Willson
Keyword(s):  
Thin Films ◽  
Steady State ◽  
Liquid Layer ◽  
Stability Criterion ◽  
Long Waves ◽  
Inclined Plane ◽  
The Stability ◽  
Micropolar Liquid

AbstractConsideration is given to the flow of a micropolar liquid down an inclined plane. The steady state is analysed and Yih's technique is employed in an investigation of the stability of this flow with respect to long waves. Detailed calculations are given for thin films and it is shown that the micropolar properties of the liquid play an important role in the stability criterion.

The Meniscus Instability of a Thin Liquid Film

1988 ◽  
Vol 55 (4) ◽  
pp. 975-980 ◽  
Author(s):  
H. Koguchi ◽  
M. Okada ◽  
K. Tamura
Keyword(s):  
Thin Film ◽  
Analytical Solution ◽  
Liquid Film ◽  
Tilt Angle ◽  
Stability Criterion ◽  
Thin Liquid Film ◽  
Normal Direction ◽  
Wave Number ◽  
The Stability ◽  
Maximum Amplification

This paper reports on the instability for the meniscus of a thin film of a very viscous liquid between two tilted plates, which are separated at a constant speed with a tilt angle in the normal direction of the plates. The disturbances on the meniscus moving with movement of the plates are examined experimentally and theoretically. The disturbances are started when the velocity of movement of the plates exceeds a critical one. The wavelength of the disturbances is measured by using a VTR. The instability of the meniscus is studied theoretically using the linearized perturbation method. A simple and complete analytical solution yields both a stability criterion and the wave number for a linear thickness geometry. These results compared with experiments for the instability show the validity of the stability criterion and the best agreement is obtained with the wave number of maximum amplification.

The stability of elastico-viscous flow between rotating cylinders Part 3. Overstability in viscous and Maxwell fluids

1966 ◽  
Vol 24 (2) ◽  
pp. 321-334 ◽  
Author(s):  
D. W. Beard ◽  
M. H. Davies ◽  
K. Walters
Keyword(s):  
Viscous Flow ◽  
Couette Flow ◽  
Taylor Number ◽  
Linear Perturbation ◽  
Rotating Cylinders ◽  
Initial Value ◽  
Viscous Liquids ◽  
Maxwell Fluids ◽  
Newtonian Liquids ◽  
The Stability

Consideration is given to the possibility of overstability in the Couette flow of viscous and elastico-viscous liquids. The relevant linear perturbation equations are solved numerically using an initial-value technique. It is shown that over-stability is not possible in the case of Newtonian liquids for the cases considered. In contrast, overstability is to be expected in the case of moderately-elastic Maxwell liquids. The Taylor number associated with the overstable mode decreases steadily as the amount of elasticity in the liquid increases, and it is concluded that highly elastic Maxwell liquids can be very unstable indeed.

scholarly journals A General Theorem on the Stability of a Class of Functional Equations Including Quartic-Cubic-Quadratic-Additive Equations

Mathematics ◽  
2018 ◽  
Vol 6 (12) ◽  
pp. 282
Author(s):  
Yang-Hi Lee ◽  
Soon-Mo Jung
Keyword(s):  
Functional Equations ◽  
Direct Method ◽  
General Theorem ◽  
Stability Problems ◽  
General Stability ◽  
Stability Theorems ◽  
Additive Type ◽  
The Stability

We prove general stability theorems for n-dimensional quartic-cubic-quadratic-additive type functional equations of the form by applying the direct method. These stability theorems can save us the trouble of proving the stability of relevant solutions repeatedly appearing in the stability problems for various functional equations.

CONTROLLABLE WRINKLING OF THIN FILMS ON PRE-STRETCHED ELASTOMERS INDUCED BY GRAVITY

2014 ◽  
Vol 06 (03) ◽  
pp. 1450029
Author(s):  
FANG WANG ◽  
KAI LI ◽  
KAI LIU
Keyword(s):  
Gravitational Force ◽  
Periodic Array ◽  
Linear Perturbation ◽  
Tensile Direction ◽  
Elastic Film ◽  
Calculation Results ◽  
Surface Patterns ◽  
The Stability ◽  
Rod Structures ◽  
Soft Elastomer

We study wrinkling instability of a thin elastic film on a pre-stretched soft elastomer induced by the gravity of periodic array of the rods homogenously clamped on the surface of the film. By using linear perturbation analysis, we show that the periodic array of the rods can drive the wrinkling instability of the film when the gravitational force of the rods attains the threshold, and the film will wrinkle into stripes parallel to the tensile direction of the pre-stretched elastomer. Our calculation results give the stability criterion of the system, and the threshold of the gravitational force and the wavelength of the wrinkling patterns are obtained, which can be controlled by tuning the magnitude of the pre-stretch and properties of the thin film and the soft elastomer. These results may provide a regulating strategy for generating precise surface patterns in similar rod structures.

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