ABSORPTION CORRECTIONS FOR RADIUM STANDARDIZATION

1951 ◽  
Vol 29 (4) ◽  
pp. 301-309 ◽  
Author(s):  
G. M. Keyser

The absorption corrections necessary for radium standardization have been redetermined. The measuring equipment and technique have been investigated to find the conditions necessary for minimum error. A lead filtered, aluminum walled chamber was found to have the best characteristics. The electronic absorption coefficients measured with this chamber fit an empirical formula depending only on the atomic number. This formula gives a value for the absorption coefficient of radium salts which was compared with a direct experimental value.

1947 ◽  
Vol 25a (6) ◽  
pp. 303-314 ◽  
Author(s):  
W. V. Mayneord ◽  
A. J. Cipriani

Measurements of the absorption of gamma-rays from Co60 and radium have been made in a number of materials. Variation of absorption coefficient of the gamma-rays from radium with thickness of lead absorber is in agreement with recent experimental determinations. The gamma-rays from Co60 are approximately monochromatic and are therefore suitable for testing theoretical absorption formulae. The absorption coefficient per electron for materials of atomic number equal to or less than that of aluminium was in agreement with the Klein–Nishina formula, assuming the cobalt radiation to consist of two lines at 1.10 and 1.30 Mev. respectively. The photoelectric absorption coefficients per electron for heavy elements are in good agreement with the theory developed by Hulme, McDougall, Buckingham, and Fowler. This coefficient varies approximately as Z3.5.


Author(s):  
John Read ◽  
John Cunningham McLennan

In a previous paper an account has been given of the measurement of the absorption of monochromatic X-ray beams of wave-length in the region 50 to 20 x -units, in carbon and aluminium. The relation of the measured coefficient of absorption to the wave-Iength did not differ from that predicted by the Klein-Nishina formula by more than 1%. The method used in that experiment has been improved, and used to measure the absorption coefficients of lead, tin, copper, and iron for similar monochromatic beams. Because lead has been used very extensively for absorption measurements the primary aim has been to measure as accurately as possible the dependence of its absorption coefficient on the wave-length of the radiation. It has not been possible to make such accurate measurements on tin, copper, and iron, but enough data has been obtained to determine the variation of the photoelectric absorption coefficient per electron with the atomic number of the absorbing element, with fair accuracy, for radiation in this region of wave-lengths. Since these absorption coefficients may find considerable application, it is considered well to give a more detailed account of the method of measurement, so that an independent judgment of their reliability may be made.


Introduction . —Previous to the discovery of the behaviour of X-rays with regard to crystals, the most homogeneous radiation obtainable was that of the characteristic radiation of an element which is excited when that element is exposed to X-radiation of suitable hardness. These characteristic radiations are now found, however, by the new method of analysis, to be constituted of a number of radiations of different wave-lengths. Moseley, shortly after the discovery of the reflection of X-rays, showed that the characteristic radiations of most of the metals he examined consisted of two prominent wave-lengths; Bragg later found that, in the case of rhodium, palladium and silver, each of these lines could be further resolved into two components. Hence the spectra of the characteristic radiation of the K series of these elements consist of at least four different wave-lengths. The analysis of a beam of X-rays into its constituent radiations by reflection at a crystal face provides a means, therefore, of obtaining radiation of a definite wave length and of such intensity as to enable its absorption coefficient in different materials to be accurately measured. Bragg and Pierce have already measured the absorption coefficients of the two most prominent lines in the spectra of the elements Rh, Pd and Ag, in a number of metals. To make the absorption coefficient more directly comparable with other atomic characteristics, they gave their results in the form of atomic absorption coefficients: the atomic absorption coefficient expresses the proportion of the energy of an X-ray pencil which is absorbed in crossing a surface on which lies one atom to every square centimetre. The ordinary mass absorption coefficient can be calculated from this quantity by dividing it by the mass of the absorbing atom. The experimental results showed that the ratio of two absorption coefficients is independent of the wave-length of the radiation over considerable ranges, a result previously deduced by Barkla from his experiments; also, that the atomic absorption coefficient is proportional to the fourth power of the atomic number of the absorber.


Author(s):  
Robert E. Ogilvie

The search for an empirical absorption equation begins with the work of Siegbahn (1) in 1914. At that time Siegbahn showed that the value of (μ/ρ) for a given element could be expressed as a function of the wavelength (λ) of the x-ray photon by the following equationwhere C is a constant for a given material, which will have sudden jumps in value at critial absorption limits. Siegbahn found that n varied from 2.66 to 2.71 for various solids, and from 2.66 to 2.94 for various gases.Bragg and Pierce (2) , at this same time period, showed that their results on materials ranging from Al(13) to Au(79) could be represented by the followingwhere μa is the atomic absorption coefficient, Z the atomic number. Today equation (2) is known as the “Bragg-Pierce” Law. The exponent of 5/2(n) was questioned by many investigators, and that n should be closer to 3. The work of Wingardh (3) showed that the exponent of Z should be much lower, p = 2.95, however, this is much lower than that found by most investigators.


2020 ◽  
Vol 64 (3) ◽  
pp. 30502-1-30502-15
Author(s):  
Kensuke Fukumoto ◽  
Norimichi Tsumura ◽  
Roy Berns

Abstract A method is proposed to estimate the concentration of pigments mixed in a painting, using the encoder‐decoder model of neural networks. The model is trained to output a value that is the same as its input, and its middle output extracts a certain feature as compressed information about the input. In this instance, the input and output are spectral data of a painting. The model is trained with pigment concentration as the middle output. A dataset containing the scattering coefficient and absorption coefficient of each of 19 pigments was used. The Kubelka‐Munk theory was applied to the coefficients to obtain many patterns of synthetic spectral data, which were used for training. The proposed method was tested using spectral images of 33 paintings, which showed that the method estimates, with high accuracy, the concentrations that have a similar spectrum of the target pigments.


2014 ◽  
Vol 875-877 ◽  
pp. 467-471
Author(s):  
Ning Wang ◽  
Xiao Xia Li

The electrically controlled birefringence of nematic liquid crystal BL-009 was measured by polarized interference method. The influence of LC absorption effect, the birefringence variation, is discussed in this paper. The experiments results showed the influence to birefringence is big in infrared region. Not only the birefringence value is greatly different with that of unconsidering absorption effect, but also the gradient changing of birefringence curves is obvious. Furthermore, the electrically controlled birefringences of two conditions are compared when the absorption coefficients of ordinary light and the extraordinary light are nearly same and greatly different. The analysis demonstrated the approximate method of absorption coefficient is feasible.


1989 ◽  
Vol 43 (1) ◽  
pp. 148-153 ◽  
Author(s):  
Dane Bićanić ◽  
Siegfried Krüger ◽  
Paul Torfs ◽  
Bruno Bein ◽  
Frans Harren

An experimental setup for performance of reverse mirage spectroscopy at CO2 laser wavelengths on liquid samples having high values of absorption coefficients is described. One and the same liquid is used as both the absorbing and deflecting medium. The Rosencwaig-Gersho theory has been applied, and the choice of experimental conditions that would enable determination of absorption coefficient β from the magnitude of photothermal signals measured at two different probe beam distances (probing locations) is discussed. The usefulness of this technique (essentially not inhibited by the requirements imposed on the sample's thickness) is tested on methanol having absorption coefficients β close to 300 cm−1 in the wavelength region covered by CO2 laser emission.


1975 ◽  
Vol 19 ◽  
pp. 381-391 ◽  
Author(s):  
F. Bazan ◽  
N. A. Bonner

The discovery of a very simple and useful relationship between the absorption coefficient of a particular element and the ratio of incoherent to coherent scattering by the sample containing the element is discussed. By measuring the absorption coefficients for a few elements in a few samples, absorption coefficients for many elements in an entire set of similar samples can be obtained.


2021 ◽  
Vol 263 (1) ◽  
pp. 5571-5577
Author(s):  
Reiji Tomiku ◽  
Noriko Okamoto ◽  
Toru Otsuru ◽  
Shun Iwamoto ◽  
Shoma Suzuki

The absorption coefficients in a reverberation room are most representative measure for evaluating absorption performance of architectural materials. However, it is well known that measurement results of the coefficient vary according to a room shape of the measurement and area of the specimen. Numerical analyses based on wave acoustics are effective tools to investigate these factors on absorption coefficient measurement in reverberation room. In this study, sound fields for the measurement of absorption coefficient in reverberation room are analyzed by time domain finite element method (TDFEM). This study shows effectiveness of the analysis for investigation on causes of variation in the measurement results and improvement methods of the measurement. First, some measurement sound fields for absorption coefficient in reverberation rooms the walls of which are incline or decline are analyzed by the TDFEM. Next, reverberation times in each sound fields are calculated from the results obtained by TDFEM and the absorption coefficients are evaluated from the reverberation time of the room with and without specimen. Finally, the relationships among room shape, degree of inclination of the wall, the sound absorption coefficient of the specimen, frequencies and the measurement absorption coefficient are investigated.


The X-ray inelastic scattering phenomena during the time-dependent perturbations are described with the aid of dynamical dispersion equations coupled with charge current in the Maxwell equations towards the appearance of the Debye-Waller factor driving the absorption coefficient, either for inelastic thermal diffusion and the Compton scattering, respectively.


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