Glyphosate degradation by immobilized bacteria: laboratory studies showing feasibility for glyphosate removal from waste water

1992 ◽  
Vol 38 (9) ◽  
pp. 921-928 ◽  
Author(s):  
Michael A. Heitkamp ◽  
William J. Adams ◽  
Laurence E. Hallas
Keyword(s):  
Industrial Effluent ◽  
Liquid Waste ◽  
Industrial Effluents ◽  
High Volume ◽  
Waste Streams ◽  
Immobilized Bacteria ◽  
Production Wastes ◽  
Aminomethylphosphonic Acid ◽  
Low Levels ◽  
Glyphosate Degradation

To evaluate immobilized bacteria technology for the removal of low levels of glyphosate (N-phosphonomethylglycine) from aqueous industrial effluents, microorganisms with glyphosate-degrading activity obtained from a fill and draw enrichment reactor inoculated with activated sludge were first exposed to glyphosate production wastes containing 500–2000 mg glyphosate/L. The microorganisms were then immobilized by adsorption onto a diatomaceous earth biocarrier contained in upflow Plexiglas® columns. The columns were aerated, maintained at pH 7.0–8.0, incubated at 25 °C, supplemented with NH4NO3 (50 mg/L), and exposed to glyphosate process wastes pumped upflow through the biocarrier. Glyphosate degradation to aminomethylphosphonic acid was initially >96% for 21 days of operation at flows yielding hydraulic residence times (HRTs) as short as 42 min. Higher flow rate studies showed >98% removal of 50 mg glyphosate/L from the waste stream could be achieved at a HRT of 23 min. Glyphosate removal of >99% at a 37-min HRT was achieved under similar conditions with a column inoculated with a pure culture of Pseudomonas sp. strain LBr, a bacterium known to have high glyphosate-degrading activity. After acid shocking (pH 2.8 for 18 h) of a column of immobilized bacteria, glyphosate-degrading activity was regained within 4 days without reinoculation. Although microbial growth and glyphosate degradation were not maintained under low organic nutrient conditions in the laboratory, the low levels of degradable carbon (45–94 mg/L) in the industrial effluent were sufficient to support prolonged glyphosate-degrading activity. The results demonstrated that immobilized bacteria technology is effective in removing low levels of glyphosate in high-volume liquid waste streams. Key words: glyphosate, degradation, immobilized bacteria technology.

scholarly journals The emergence of coercive federal Australian labour law, 1901–2020

2021 ◽  
pp. 002218562110039
Author(s):  
Eugene Schofield-Georgeson
Keyword(s):  
Industrial Relations ◽  
High Volume ◽  
Union Power ◽  
Labour Law ◽  
Industrial Environment ◽  
The Past ◽  
Low Levels ◽  
Labour Legislation ◽  
Employment Legislation

Over the past two decades, industrial relations scholarship has observed a trend towards an increasingly punitive industrial environment along with the ‘re-regulation’ of labour law. Absent from much of this literature, however, has been an empirical and historical measurement or comparison of the scale and quality of this systemic change. By surveying coercive and penal federal industrial legislation over the period 1901–2020, this study shows empirically that over the last 40 years, there has been a steep increase in the amount of coercive federal labour legislation in Australia. It further measures and compares the volume of coercive labour legislation enacted specifically against ‘labour’ and ‘capital’ or both throughout the same period (1901–2020). Analysis reveals a correlation between a high volume of coercive labour legislation with low levels of trade union power and organisation. Argued here is that coercive labour legislation has been crucial to transitioning from a liberal conciliation and arbitration model of Australian industrial relations towards a neoliberal framework of employment legislation. In the former, regulation was more collective, informal and egalitarian (embodied by the sociological concept of ‘associative democracy’). Under a neoliberal framework, regulation is now more individualised, technical, punitive and rarely enforced, resulting in less equal material outcomes.

Directional predictability between returns and volume in cryptocurrencies markets

2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Panos Fousekis ◽  
Vasilis Grigoriadis
Keyword(s):  
High Volume ◽  
Stationary Time Series ◽  
Temporal Association ◽  
Informational Efficiency ◽  
Content Type ◽  
Low Levels ◽  
The Cross ◽  
Trading Volumes ◽  
Directional Predictability ◽  
The Empirical Analysis

Purpose This paper aims to identify and quantify directional predictability between returns and volume in major cryptocurrencies markets. Design/methodology/approach The empirical analysis relies on the cross-quantilogram approach that allows one to assess the temporal (lag-lead) association between two stationary time series at different parts of their joint distribution. The data are daily prices and trading volumes from four markets (Bitcoin, Ethereum, Ripple and Litecoin). Findings Extreme returns either positive or negative tend to lead high volume levels. Low levels of trading activity have in general no information content about future returns; high levels, however, tend to precede extreme positive returns. Originality/value This is the first work that uses the cross-quantilogram approach to assess the temporal association between returns and volume in cryptocurrencies markets. The findings provide new insights about the informational efficiency of these markets and the traders’ strategies.

scholarly journals Environmental Pollution Around Dhaka EPZ and its Impact on Surface and Groundwater

1970 ◽  
Vol 46 (2) ◽  
pp. 153-162 ◽  
Author(s):  
MKA Khan ◽  
M Alam ◽  
MS Islam ◽  
MQ Hassan ◽  
MA Al-Mansur
Keyword(s):  
Waste Water ◽  
Water Samples ◽  
Industrial Effluent ◽  
Industrial Effluents ◽  
Industrial Sector ◽  
Background Concentration ◽  
Physical Parameters ◽  
Clay Layer ◽  
Surrounding Area ◽  
Surface And Groundwater

Industrial sector is gradually playing a more important role in Bangladesh economy and EPZs have provided a good platform of industrial establishment. Dhaka EPZ since its establishment has altered the fragile environment of the surrounding area. Huge amount of effluents discharged from Dhaka EPZ has been polluting the surface and groundwater. Surface water contamination by industrial effluents released from Dhaka Export Processing Zone (DEPZ) and the ramification to groundwater have been estimated. The study involves analyzing physicochemical properties along with major Anionic contaminants in waste water samples. Conversely their potential transmission into groundwater has been evaluated by analyzing HTW water samples from the surrounding area. Some important physical parameters were measured while collecting the sample in field condition. The suite of 6 major anions (F-, Cl-, NO2-, NO3-, SO4-2 and HCO3-) have been measured in ppm level of concentration by analyzing with chemically suppressed Ion Chromatograph while HCO3- content was determined by Titration method. Analysis reveals pH maximum 9.55, DO maximum 2.40 mg/L, TDS maximum 1280 mg/L, Bi-carbonate maximum 891 mg/L, Sulfate maximum 452 mg/L, Chloride maximum 179 mg/L, Nitrate maximum 44 mg/L and Fluoride not above detection limit. Higher concentration of Cl-, SO4-2, NO3- in waste water samples compared to the standard by DOE (Department of Environment) as well as background concentration from uncontaminated water can be correlated with industrial effluent discharge. On the other hand low level of concentration found in groundwater samples indicates that groundwater is still safe. This phenomenon is explained by the presence of impervious clay layer. Key words: Dhaka EPZ; Effluent; Madhupur Tract; Contaminants; DOE; Environment; Clay layer DOI: http://dx.doi.org/10.3329/bjsir.v46i2.8181 Bangladesh J. Sci. Ind. Res. 46(2), 153-162, 2011

scholarly journals Growth and leaf epidermal response of three Sesamum indicum varieties to industrial effluent irrigation

2017 ◽  
Vol 52 (1) ◽  
pp. 1-6 ◽  
Author(s):  
AA Abdul Rahaman ◽  
OM Olaniran ◽  
FA Oladele
Keyword(s):  
Seedling Growth ◽  
Stomatal Density ◽  
Industrial Effluent ◽  
Industrial Effluents ◽  
Sesamum Indicum ◽  
Proper Treatment ◽  
Trichome Density ◽  
Stomatal Index ◽  
Stomatal Size ◽  
Epidermal Features

The effect of industrial effluents was studied with respect to growth and leaf anatomy of three Sesamum indicum varieties (NGB 00931, NGB 00937 and NGB 00939). Industrial effluents (25%, 50%, 75% and 100%) from two industries are used to irrigate the plants. Although, the control plants possessed larger leaves and longer stems than the effluent-treated plants, at lower concentration, the plant growth is relatively higher. Gradual decrease in the germination of seeds and seedling growth with increase in effluent concentration was observed. The best germination and seedling growth was observed at the 25% concentration. Leaf epidermal features (stomatal density, stomatal index, stomatal size, trichome density, tricome index, trichome size and number of epidermal cells) are more influenced in the effluent-treated plants than in the control plants from the Peace Standard Pharmaceutical Industry than in the effluent from the Global Soap & Detergent Industry. Thus the industrial effluents can be safely used for irrigation purposes with proper treatment and dilution at 25%.Bangladesh J. Sci. Ind. Res. 52(1), 1-6, 2017

scholarly journals Production of fibrinogenolytic and fibrinolytic enzymes by a strain of Penicillium sp. isolated from contaminated soil with industrial effluent

2019 ◽  
Vol 41 (1) ◽  
pp. 40606 ◽  
Author(s):  
Lillian Maria Baggio ◽  
Luciano Aparecido Panagio ◽  
Fabiana Guillen Moreira Gasparin ◽  
Daniele Sartori ◽  
Maria Antonia Pedrine Colabone Celligoi ◽  
...  
Keyword(s):  
Cardiovascular Diseases ◽  
Industrial Effluent ◽  
Skim Milk ◽  
Industrial Effluents ◽  
Media Composition ◽  
Lytic Enzymes ◽  
Fibrinolytic Enzymes ◽  
Health Area ◽  
Tissue Plasminogen ◽  
Selection Of

Cardiovascular diseases associated with thrombosis are one of the main causes of death all around the world. Urokinase, streptokinase, and tissue plasminogen activator are the major thrombolytic agents used to treat thrombosis. However, the fact that these agents have several side effects and high prices has driven the search for safer and more economically viable compounds for the treatment of cardiovascular diseases. Thus, the aim of this study was to evaluate the potential of fungi isolated from industrial effluents to produce fibrino(geno)lytic enzymes. The selection of the protease-producing strains showed that only the BF20 strain was able to produce proteolytic halos in milk agar. This strain identified as belonging to the genus Penicillium was cultivated in submerged fermentation. Different media composition were tested to evaluate proteolytic activity, and the results showed that the medium containing 0.1% yeast extract and 1% skim milk, pH 5.0, present higher azocaseinolytic activity (0.24 U mL-1 min.-1). This sample also showed the ability to degrade fibrinogen and fibrin after 15 and 120 min. of incubation, respectively. These results indicate that the BF20 strain has a thrombolytic potential, effectively degrading fibrinogen and fibrin, having great application in the health area.

Toxicity Identification and Reduction Evaluation in Petrochemical Effluents – SITEL Case

1992 ◽  
Vol 25 (3) ◽  
pp. 73-84 ◽  
Author(s):  
A. Brandelli ◽  
M. L. Baldasso ◽  
E. P. Goettems
Keyword(s):  
Aquatic Toxicity ◽  
Pimephales Promelas ◽  
Industrial Effluent ◽  
Liquid Waste ◽  
Toxicity Testing ◽  
Treatment System ◽  
Dissolved Air Flotation ◽  
Industrial Plants ◽  
Toxicity Reduction ◽  
Toxicity Identification

SITEL, Integrated Wastewater Treatment System of South Petrochemical Complex,has been processing liquid waste from this industrial area since November, 1982. The complex consists of an olefins plant and some second-generation plants that produce mainly thermoplastic resins. The raw industrial effluent is segregated in the plants in two main streams: organic and inorganic. The organic treatment consists of water-oil separator, equalization basin and dissolved air flotation (primary treatment), activated sludge and multi-media filters (secondary treatment) and stabilization ponds (tertiary treatment). The final effluent is applied on land by perforated PVC pipelines and sprinklers. In 1986, an aquatic toxicity test laboratory was implemented. It uses fish (Pimephales promelas) and crustaceans (Daphnia similis), according to methodology reported by EPA. A three-step protocol has been developed to characterize the whole effluent toxicity reduction in a, treatment system as well as to identify the sources of toxicity in industrial plants. The first step consists of toxicity identification and characterization of effluents at several monitoring points of SITEL. After analysing the results of the first step, it is possible to evaluate the toxicity reduction obtained by the treatment system and environmental toxicity evaluation. The second step consists of identification of the sources of toxicity in industrial plants through comparative study of organic and inorganic effluents of the complex, prioritizing the most toxic effluents. The last step consists of a toxic fraction identification, based on sequential physico/chemical fractionations of the effluent with associated toxicity testing using aquatic organisms. This paper presents the results that have been obtained so far and a previous evaluation of the main contributors for the toxicity of the effluents.

Sources of Pollution of the Estuary of the River Nervion, Spain – A Case Study

1984 ◽  
Vol 16 (5-7) ◽  
pp. 95-125 ◽  
Author(s):  
A Azkona ◽  
S H Jenkins ◽  
H M G Roberts
Keyword(s):  
Fresh Water ◽  
Hydrogen Sulphide ◽  
Industrial Wastewater ◽  
Industrial Effluent ◽  
Oxygen Demand ◽  
Industrial Effluents ◽  
Domestic Sewage ◽  
Septic Tank ◽  
Safety Level ◽  
Sulphide Concentration

This paper describes part of a comprehensive multidisciplinary study of the pollution of the estuary of the River Nervion, Bilbao, Spain. The objectives of the study were to determine the sources and loads of pollution from domestic sewage and industrial wastewater; provide information on the extent of pollution; formulate hydrodynamic and predictive models capable of forecasting the effects on the estuary of the anticipated growth of population and industry; determine the amount of polluting matter that would have to be removed in order to reach defined estuary water quality standards; arrive at suitable technical methods able to attain these standards at minimum cost; determine the treatability of wastewater discharges and recommend methods for controlling industrial wastewater. These objectives necessitated a survey of the pollution loads from domestic sources and industry which were discharged to the fresh water and tidal reaches of four major tributaries in addition to the main river Nervion; the results of this part of the survey are described in this paper. The presence of iron in discharges from iron ore mining and metal processing was found to aid flocculation of organic matter and the consequent deposition of sludge in the estuary. This action and the rate of oxygen uptake during the decomposition of such deposits are also described. The domestic sewage of the study area receives treatment in septic tanks before discharging to rivers or the estuary. In spite of free hydrogen sulphide and high concentrations being present in the septic tank effluents, odour nuisance does not occur, because, as is shown in the paper, of the formation of ferrous sulphide. The hydrogen sulphide concentration in the atmosphere at a pumping station was found to be above the safety level. The industrial load of impurity was estimated to be approximately 15% higher than the domestic load, but it is extremly difficult to find a rational basis on which comparisons may be made between domestic sewage and a mixture of industrial effluents containing substances inimical to biological activity. The industrial effluent was contained in a very large volume of water, much of it taken from the estuary for cooling or process water. It is calculated that if the industrial pollutants had been contained only in the fresh water used by industry the COD of the mixture would have been 1317 mg/l; the suspended solids 2143 mg/l; the ammonia nitrogen 191 mg/l; iron 1037 mg/l; other heavy metals 118 mg/l; fluoride as F 14.5 mg/l; cyanide as CN 8.1 mg/l; oil 196 mg/l; phenols 8.1 mg/l; mercury 0.13 mg/l; and the mixture would have had an excess of acidity of 5188 mg/l. An estimate of the load of substances having an oxygen demand indicated that of the total oxygen demand discharged to the system of rivers and estuary approximately 50% entered the estuary from the main tributaries, the remainder being discharged directly to the estuary. An outline is given of the methods that would be used to determine the treatability of industrial effluents which were rendered acceptable for discharge into public sewers.

scholarly journals Adsorptive Removal of Copper Ions from Polluted Water Using Sorbents Derived from Cordia dichotoma, Albizia thompsonii and Polyalthia cerasoides Plants

2020 ◽  
Vol 32 (10) ◽  
pp. 2653-2659
Author(s):  
Tumma Prasanna Kumar Reddy ◽  
Sayana Veerababu ◽  
Malireddy Venkata Sai Mohan Reddy ◽  
Kunta Ravindhranath
Keyword(s):  
Activated Carbons ◽  
Copper Ions ◽  
Industrial Effluent ◽  
Industrial Effluents ◽  
Liquid Interface ◽  
Polluted Water ◽  
Physico Chemical ◽  
Solid Liquid Interface ◽  
Solid Liquid ◽  
Direct Applicability

Three different activated carbons as effective adsorbents were prepared by digesting the stems of Cordia dichotoma, Albizia thompsonii and Polyalthia cerasoides plants in conc. H2SO4 for Cu2+ removal from wastewater. The sorption natures of these sorbents are optimized with respect to various physico-chemical characteristics for the maximum Cu2+ removal using simulated waters. Cordia dichotoma (CDAC), Albizia thompsonii (ATAC) and Polyalthia cerasoides (PCAC) activated carbons show good sorption capacities of values: 97.0, 76.8 and 66.7 mg/g, respectively in a wide pH ranges. Unlike that of other two activated carbons, Cordia dichotoma activated carbon is effective even in acid conditions, indicting its direct applicability to Cu-based industrial effluents which are generally acidic in nature. Interference of two fold excess of co-ions is minimal. The established extraction conditions for the removal of more than 95.0% from 10 ppm Cu2+ solution at room temperature (303 K) using CDAC as sorbent are: pH: 3-9; time of equilibration: 1 h; sorbent dosage: 0.100 g/100 mL; with ATAC: pH: 6-9; time of equilibration: 1.5 h and sorbent dosage: 0.125 g/100 mL; and with PCAC: pH: 6-9; time of equilibration: 2.0 h and sorbent dosage 0.50 g/100 mL. Spent adsorbents can be regenerated and reused until four cycles with minimal loss of adoption capacities. Thermodynamic studies revealed that the sorption is spontaneous and endothermic in nature. Further, the ΔH value for CDAC is 30.156 KJ/mol; it indicates the strong chemisorption and may be through reduction to Cu+/Cu and/or complex formation between Cu2+ and functional groups of the adsorbent. The ΔH values of other two activated carbons, ATAC and PCAC, indicated that the sorption is mainly physical with strong inclination towards chemical nature. Positive ΔS values of all the three sorbents, emphasizes the disorder or randomness at the solid-liquid interface and hence favourable conditions for more penetration of Cu2+ into the surface layers of the adsorbent and hence, more removal of Cu2+ ions. The negative ΔG values indicate that the sorption forces are good enough to cross the potential barrier at the solid-liquid interface and hence the process is spontaneous. The prepared three activated carbons were also successfully applied to industrial effluent and polluted lake samples.

scholarly journals Salinity and pH effects on floating and emergent macrophytes in a constructed wetland

2018 ◽  
Vol 2017 (1) ◽  
pp. 270-275 ◽  
Author(s):  
H. R. Hadad ◽  
M. M. Mufarrege ◽  
G. A. Di Luca ◽  
M. A. Maine
Keyword(s):  
Constructed Wetland ◽  
Eichhornia Crassipes ◽  
Industrial Effluent ◽  
Industrial Effluents ◽  
Pistia Stratiotes ◽  
Ph Effects ◽  
Emergent Macrophytes ◽  
High Ph ◽  
Salvinia Herzogii ◽  
Floating Macrophytes

Abstract Salvinia herzogii, Pistia stratiotes and Eichhornia crassipes (floating species) were the dominant macrophytes in a constructed wetland (CW) over the first years of operation. Later, the emergent Typha domingensis displaced the floating species, becoming dominant. The industrial effluent treated at this CW showed high pH and salinity. The aim of this work was to study the tolerance of floating species and T. domingensis exposed to different pH and salinity treatments. Treatments at pH 8, 9, 10 and 11 and salinities of 2,000; 3,000; 4,000; 6,000; and 8,000 mg L−1 were performed. Floating macrophytes were unable to tolerate the studied pH and salinity ranges, while T. domingensis tolerated higher pH and salinity values. Many industrial effluents commonly show high pH and salinity. T. domingensis demonstrated to be a suitable macrophyte to treat this type of effluents.

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