Effets de l'ozonation et de la filtration biologique sur la demande en chlore et sur les précurseurs de trihalométhanes et des composés organo-halogénés totaux

1995 ◽  
Vol 22 (5) ◽  
pp. 945-954
Author(s):  
Hélène Baribeau ◽  
Michèle Prévost ◽  
Raymond Desjardins ◽  
Pierre Lafrance ◽  
Bernard Legube
Keyword(s):  
Activated Carbon ◽  
Organic Carbon ◽  
Biological Treatment ◽  
Residual Chlorine ◽  
Short Term ◽  
Biological Activated Carbon ◽  
Organic Halides ◽  
Chlorine Demand ◽  
Carbon Filtration ◽  
By Products

The effects of biological treatment (ozonation followed by biological activated carbon filtration (BAC)) on chlorine demand and on formation of trihalomethanes (THM) and total organic halides compounds (TOH) were studied at the Sainte-Rose water treatment facility, Laval. The plant influent is a surface water with a dissolved organic carbon of 6–7 mg/L. Results showed that ozonation marginally reduced (0–6%) short term chlorine demand but that BAC filtration reduced it by 40–55%. Ozonation versus BAC filtration was found to effect THM and TOH formation differently from the removal of the chlorine demand. THM (4-h contact with chlorine) and TOH formations were reduced by 48–60% and 39%, respectively, via ozonation. With BAC filtration, THM and TOH formations were reduced by 20–34% and 16%, respectively, with respect to the ozonated influent. For all essays, an initial significant decrease in residual chlorine was followed by an increase in TOH and subsequently in THM. The initial chlorine doses used for measuring the chlorine demand were found to have an effect on the final results. An increase in the initial chlorine dose resulted in a higher chlorine demand as well as in higher THM and TOH formations. The effect was found to be more profound at chlorine doses less than 3 mg Cl2/mg total organic carbon. Key words: chlorine demand, chlorination by-products, trihalomethane, total organic halides, ozonation, filtration, biological activated carbon.

Dissolved Organic Carbon Removal from a Prairie Water Supply Using Ozonation and Biological Activated Carbon

1999 ◽  
Vol 34 (4) ◽  
pp. 615-632 ◽  
Author(s):  
Joanne Sketchell ◽  
Hans G. Peterson ◽  
Nick Christofi
Keyword(s):  
Activated Carbon ◽  
Organic Carbon ◽  
Dissolved Organic Carbon ◽  
Water Source ◽  
Drinking Water Source ◽  
Biological Activated Carbon ◽  
Chlorine Demand ◽  
Biodegradable Dissolved Organic Carbon ◽  
Carbon Filtration ◽  
By Products

Abstract Large quantities of dissolved organic carbon in prairie surface water reservoirs make sustainable treatment quite challenging. Organic material is a precursor for the formation of disinfection by-products. Here, ozonation and biological activated carbon filtration were used as methods for removing dissolved organic carbon from the water of a small prairie reservoir used as a drinking water source. Biofiltration alone yielded significant reductions in dissolved organic carbon, colour, total trihalomethanes and chlorine demand. When ozonation preceded biofiltration, the increased proportion of biodegradable dissolved organic carbon allowed for significantly greater (p<0.05

pH and Mg/Ca control for biological treatment of an offensive flavour (2-MIB)

1998 ◽  
Vol 37 (10) ◽  
pp. 101-106
Author(s):  
H. Sumitomo
Keyword(s):  
Activated Carbon ◽  
Water Supply ◽  
Biological Treatment ◽  
Raw Water ◽  
Removal Rates ◽  
Biological Activated Carbon ◽  
Effects Of Ph ◽  
Carbon Filtration

From a series of experimental observations, it was found that removal rates of the offensive flavor 2-methyl-isoborneol(2-MIB) and ammonia by a biological treatment for water supply were rather unstable and that the removal rates of them often became reverse such as low removal in 2-MIB and high removal of ammonia. One reason for the reverse phenomenon was found that the affinities of sludge around bacteria with 2-MIB and ammonia often became reversed. The affinities of sludge with 2-MIB and ammonia were found to be changeable depending upon pH along with magnesium (Mg) and calcium (Ca) concentrations in sludge. From these findings, control of pH and magnesium calcium ratio (Mg/Ca) of raw water was recommended for simultaneous and stable removal of 2-MIB and ammonia. From plant scale experiments equipped with automatic pH controller, the effects of pH and Mg/Ca control for biological treatment of 2-MIB and ammonia were observed in a biological activated filtration. Here, a biological activated carbon filtration means a longer filtration than 40 to 50 days from the beginning. The obtained results were almost as expected, showing high removal rates of both 2-MIB and ammonia.

scholarly journals Control of disinfection by-products and biodegradable organic matter through biological treatment

2005 ◽  
Vol 5 ◽  
pp. 1-15 ◽  
Author(s):  
H. M. Shukairy ◽  
R. J. Miltner ◽  
R. S. Summers
Keyword(s):  
Organic Matter ◽  
Organic Carbon ◽  
River Water ◽  
Biological Treatment ◽  
Ohio River ◽  
Formation Potential ◽  
Ozone Dose ◽  
Chlorine Demand ◽  
By Products ◽  
Biodegradable Organic Matter

The optimal use of ozonation as a pretreatment process prior to biological treatment of Ohio River water was investigated at both the bench (batch) and pilot-plant (continuous flow) scale. The study focused on disinfection by-products (DBPs) and DBP precursor compounds and on the production of biologically stable water. Biotreatment was achieved using a bench-scale fixed-film reactor with sand acclimated to the raw Ohio River water. Ozonation was found to create a number of aldehydes, in particular formaldehyde, methyl glyoxal, glyoxal and acetaldehyde. With the exception of formaldehyde, a plateau in the aldehyde yield occurred at an ozone to total organic carbon (03/TOC) ratio of 0,7 mg/mg, while formaldehyde increased with increasing ozone dose. After biotreatment, the concentration of aldehydes were below 1 µg/1. Increasing ozone doses were also found to increase the assimilable organic carbon (AOC), by both NOX and P17 procedures, and the biodegradable dissolved organic carton (BDOC). The AOC values showed a maximum at about an 03/TOC ratio of 2 mg/mg, white the BDOC continued to increase with the highest ozone dose : an 03/TOC ratio of 2,8 mg/mg. Both ozonation and biotreatment were fond to decrease the chlorine demand by up to 75 % for ozonation and 55 % for biotreatment. Similar trends were found for the impact of ozonation and biotreatment on the precursor compounds for total organic halogen (TOX), total trihalomethanes (TTHMs) and total haloacetic acids (THAAs), as measured by the formation potential (FP) test : 12 mg/l chlorine, 7 days, 25 °C, 6.5-7.2 pH. An ozone dose of 0.4 03/DOC (mg/mg) decreased the TOXFP, TTHMFP and THAAFP by 28 %, 23 % and 33 %, respectively. Further increases in ozone only marginally increased the amount of the TOXFP and TTHMFP removed, white a maximum removal of 53 % of the THAAFP occurred at 03/DOC ratio of 0.87 mg/mg. Biotreatment of the nonozonated samples yielded 39 %, 38 % and 73 % removal of the TOXFP, TTHMFP and THAAFP, respectively. Biotreatment of the ozonated sample yielded a 30 to 50 % reduction in TOXFP and TTHMFP, while a constant level of 30 to 40 µg/l of THAAFP was achieved. Chloropicrin formation potential increased with ozone dose, but subsequent biotreatment reduced it to below 0.2 µg/l. Ozonation was Pound to oxidize chorine demand and the precursors for TOX, THM and HAAs. However, it created chloropicrin precursors, aldehydes and other biodegradable organic matter. Biotreatment was found to further reduce the chlorine demand, the precursors for TOX, THMs and HAAs and reduce the ozone created disinfection by-products.

Evaluating ozone dose for AOC removal in two-step GAC filters

1998 ◽  
Vol 37 (9) ◽  
pp. 113-120 ◽  
Author(s):  
R. Vahala ◽  
T. Ala-Peijari ◽  
J. Rintala ◽  
R. Laukkanen
Keyword(s):  
Activated Carbon ◽  
Organic Carbon ◽  
Second Step ◽  
Humic Lake ◽  
Short Term ◽  
Feasible Method ◽  
Assimilable Organic Carbon ◽  
Water Treatment Plants ◽  
Ozone Dose ◽  
Ozonated Water

Upgrading an existing post-ozonation plant with two-step granular activated carbon (GAC) filtration for assimilable organic carbon (AOC) removal was studied. The effects of ozone dose on AOC formation and its removal in the subsequent two-step GAC filtration was studied using chemically pretreated 2 to 14° C humic lake water. Two parallel pilot-plant trains with different ozone doses (0 to 1.2 mgO3/mgTOC) and a short-term ozonation study were performed. The optimum ozone dose for maximum AOC formation was 0.4–0.5 mgO3/mgTOC. The AOC-P17 of ozonated water was three-fold higher and AOC-NOX over ten-fold higher than in non-ozonated water, while the following biofiltration (first step) removed 51% and 72% of AOC-P17 and AOC-NOX, respectively. The adsorber (second step) contributed to less than 10% of the overall AOC reduction. It appeared that biofiltration is a feasible method in upgrading water treatment plants for AOC removal even when treating cold humic waters, while the subsequent adsorber seems to have less significance for AOC removal.

New Biology for Advanced Wastewater Treatment

1999 ◽  
Vol 40 (4-5) ◽  
pp. 137-144 ◽  
Author(s):  
K. Miserez ◽  
S. Philips ◽  
W. Verstraete
Keyword(s):  
Wastewater Treatment ◽  
Activated Carbon ◽  
Organic Carbon ◽  
Genetically Modified Organisms ◽  
New Technologies ◽  
Chemical Oxidation ◽  
Advanced Treatment ◽  
Biological Activated Carbon ◽  
Catabolic Potential ◽  
New Biology

A number of new technologies for the advanced treatment of wastewater have recently been developed. The oxidative cometabolic transformation by methanotrophs and by nitrifiers represent new approaches in relation to organic carbon. The Biological Activated Carbon Oxidative Filters characterized by thin biofilms are also promising in that respect. Moreover, implementing genetically modified organisms with improved catabolic potential in advanced water treatment comes into perspective. For very refractory effluents chemical support techniques, like e.g. strong chemical oxidation, can be lined up with advanced biology.

scholarly journals Effect of advanced oxidation on N-nitrosodimethylamine (NDMA) formation and microbial ecology during pilot-scale biological activated carbon filtration

2017 ◽  
Vol 113 ◽  
pp. 160-170 ◽  
Author(s):  
Dong Li ◽  
Ben Stanford ◽  
Eric Dickenson ◽  
Wendell O. Khunjar ◽  
Carissa L. Homme ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Microbial Ecology ◽  
Advanced Oxidation ◽  
Pilot Scale ◽  
Biological Activated Carbon ◽  
Carbon Filtration
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