Influence of pH and hardness on toxicity of ammonia to the amphipod Hyalella azteca

1995 ◽  
Vol 52 (10) ◽  
pp. 2078-2083 ◽  
Author(s):  
G. T. Ankley ◽  
M. K. Schubauer-Berigan ◽  
P. D. Monson
Keyword(s):  
Water Quality ◽  
North America ◽  
Sediment Toxicity ◽  
Water Hardness ◽  
Hyalella Azteca ◽  
Ammonia Toxicity ◽  
Total Ammonia ◽  
Baseline Values ◽  
Ph Dependent ◽  
Influence Of Ph

The amphipod Hyalella azteca is frequently used for freshwater sediment tests throughout North America. A common potential toxicant in sediments is ammonia. Our objective was to characterize the influence of two key water quality variables, pH and hardness, on toxicity of ammonia to the amphipod. Ninety-six hour, water-only exposures of H. azteca to ammonia were conducted using three different water types with hardnesses of 42, 100, and 270 mg/L as CaCO3 and three levels of pH (ca. 6.5, 7.5, and 8.5). In the soft water, toxicity of total ammonia was constant across test pH. As water hardness increased, toxicity of ammonia (on a total basis) to the amphipod decreased and became more pH dependent. Our data suggest that in softer water the amphipod was quite sensitive to the ionized (NH4+) form of ammonia. This contrasts with most other species that have been tested, which typically are more sensitive to un-ionized (NH3) ammonia than to NH4+. These data provide baseline values for interpreting the possible contribution of ammonia to sediment toxicity in tests conducted with H. azteca and also indicate that in some situations NH4+ may be important in determining ammonia toxicity.

scholarly journals Toxicity of Ammonia to Benthic Amphipod Grandidierella bonnieroides: Potential as Confounding Factor in Sediment Bioasssy (Toksisitas ammonia terhadap amphipod bentik Grandidierella bonnieroides : Potensi sebagai faktor pengganggu dalam bioassay sedimen)

2015 ◽  
Vol 20 (4) ◽  
pp. 215
Author(s):  
Dwi Hindarti ◽  
Zainal Arifin ◽  
Tri Prartono ◽  
Harpasis S. Sanusi
Keyword(s):  
Toxicity Test ◽  
Confounding Factor ◽  
Sediment Toxicity ◽  
Ammonia Toxicity ◽  
Toxicity Tests ◽  
Ammonia Content ◽  
Sediment Toxicity Tests ◽  
Effect Concentration ◽  
Total Ammonia ◽  
Grandidierella Bonnieroides

Toxicity of ammonia was evaluated using amphipod Grandidierella bonnieroides to describe its role as confounding factor in sediment quality assessment. Ammonia is a toxic compound that is found naturally in seawater and sediment. High ammonia content in the pore water sediment can be potentially toxic to benthic biota, so that it will interfere with the results of sediment toxicity tests. Laboratory production amphipod was used in this ammonia toxicity test. Water-only toxicity tests was conducted to produce new toxicity data of ammonia, and is expressed as LC50, LOEC and NOEC for benthic amphipod G.bonnieroides. The study resulted the 96-h median lethal concentration (LC50) of ammonia for G. bonnioerides was 65.5 mg.L-1. While the value LOEC (low observed effect concentration) is 56 mg.L-1 and NOEC value (no observed effect concentration) was 32 mg.L-1 . This shows that ammonia has a relatively low toxicity to amphipod and ammonia does not act as a confounding factor in the sediment toxicity test, because the ammonia content in sediment does not pose any significant effect on amphipod survival. It can be concluded that the amphipod has a potential useful as test organism in sediment bioassay for assessing the quality of marine sediment. Moreover, the high dependence of total ammonia toxicity indicates that it is necessary to measure the total ammonia and pH of the medium when testing environmental samples. Keywords: ammonia, amphipod, toxicity, confounding factor, bioasssay Toksisitas ammonia dievaluasi menggunakan amphipod Grandidierella bonnieroides untuk menggambarkan perannya sebagai faktor pengganggu dalam penilaian kualitas sedimen. Amonia merupakan senyawa beracun yang ditemukan secara alami dalam air laut dan sedimen. Kandungan amonia yang tinggi dalam air pori sedimen dapat berpotensi racun bagi biota bentik, sehingga akan mengganggu hasil uji toksisitas sedimen. Amphipod hasil produksi laboratorium digunakan dalam uji amonia. Uji toksisitas dilakukan untuk menghasilkan data toksisitas baru ammonia, dan dinyatakan sebagai LC50, LOEC dan NOEC untuk G.bonnieroides amphipod bentik. Studi ini menghasilkan nilai konsentrasi median letal 96-jam (LC50) ammonia untuk G. bonnioerides adalah 65.5 mg.L-1. Sedangkan nilai LOEC (konsentrasi terendah yang menyebabkan dampak secara signifikan) adalah 56 mg.L-1 dan nilai NOEC (konsentrasi tertinggi yang tidah menyebabkan dampak secara signifikan) 32 mg.L-1. Hal ini menunjukkan bahwa ammonia memiliki toksisitas relatif rendah untuk amphipod dan ammonia tidak bertindak sebagai pengganggu dalam untuk uji toksisitas sedimen, karena kandungan ammonia dalam sedimen tidak menimbulkan pengaruh yang nyata pada survival amphipod. Dapat disimpulkan bahwa amphipod memiliki potensi sebagai biota uji dalam sedimen bioassay untuk menilai kualitas sedimen laut. Selain itu, terdapat ketergantungan yang tinggi toksisitas amoniak terhadap pH, sehingga perlu untuk memantau total amonia dan pH saat melakukan pengujian sampel lingkungan. Kata kunci : ammonia, amphipod, toksisitas, faktor pengganggu, bioassay

DIP quality influenced by process water quality

TAPPI Journal ◽  
2014 ◽  
Vol 13 (9) ◽  
pp. 51-60
Author(s):  
DENNIS VOSS ◽  
HANS-JOACHIM PUTZ ◽  
SAMUEL SCHABEL
Keyword(s):  
Water Quality ◽  
Surface Tension ◽  
Ph Value ◽  
Water Hardness ◽  
Process Water ◽  
Test Results ◽  
Negative Effects ◽  
Water Parameters ◽  
Effects Of Ph ◽  
Contamination Levels

The need for deinking mills to reduce their fresh water consumption has resulted in higher loads of various contaminants in the process water. Lower recovered paper quality also leads to higher contamination levels in the mills. This higher load has an influence on achievable target brightness. The objective of the work was to determine and explain the main reasons for relatively poor deinked pulp quality or poor deinking potential based on the influence of recovered paper composition and process water quality. The process water parameters significantly affect the deinking potential of recovered paper. The test results showed the negative effects of increased water hardness. For standard recovered paper mixtures, flotation selectivity is higher with increasing flotation pH-value. Good results were realized for standard recovered paper with low hardness, low surface tension, and high pH-value. The results for recovered paper containing flexo newsprint could be slightly improved with low hardness, low surface tension, and low pH-value. The results of the test program using design of experiments showed interacting effects of pH-value and surface tension on luminosity and flotation selectivity.

Sediment toxicity testing with the freshwater amphipod Hyalella azteca: Relevance and application

Chemosphere ◽  
2005 ◽  
Vol 61 (11) ◽  
pp. 1740-1743 ◽  
Author(s):  
Uwe Borgmann ◽  
Lee Grapentine ◽  
Warren P. Norwood ◽  
Glen Bird ◽  
D. George Dixon ◽  
...  
Keyword(s):  
Sediment Toxicity ◽  
Toxicity Testing ◽  
Hyalella Azteca ◽  
Sediment Toxicity Testing

scholarly journals Study of Biofilter Planted with Basil for Removal of Ammonia in Aquaponic Water

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Bharat Nandkumar Mulay ◽  
Konda Rajasekhar Reddy
Keyword(s):  
Water Quality ◽  
Ammonia Nitrogen ◽  
Quality Parameters ◽  
Coarse Aggregates ◽  
Total Ammonia Nitrogen ◽  
Coconut Husk ◽  
Significant Difference ◽  
Total Ammonia ◽  
Water Recirculation ◽  
Aquaculture Water

Abstract This experimental investigation of a laboratory scale aquaponic system included testing of a biofilter with basil plant as the biofilter part on aquaculture water quality. Irridescent shark was selected as aquaculture species. The biofilter consist of natural biomaterials such as coconut husk, coco peat, and coarse aggregates. The experiment was carried out for three short water recirculation durations of 2, 3, and 4 h/day. The influent and effluent ammonia NH3, total ammonia nitrogen (TAN), nitrites NO2 and nitrates NO3 levels were measured and analysed. The results showed that the biofilter effectively removed NH3 (65 - 71 %), TAN (34 - 58 %), and NO2 (60 - 67 %) from the aquaculture water. The dissolved oxygen (DO) levels were maintained between 3 - 7.0 mg/l during all the recirculation durations. The significance of water recirculation period was assessed by calculating the differences between the means of water quality parameters with a statistical test named one-way analysis of variance (ANNOVA) with significant level P taken as 5 %, i.e., P ≤ 0.5. The effluent mean NH3 levels 0.030 mg/l, 0.033 mg/l, and 0.022 mg/l exhibited significant difference at 4 h/d periods while effluent TAN levels 0.81, 0.77, and 0.77 showed no difference with varying periods.

Variabilities of Surface Water Quality of Degraded Post-mining Areas in Bytom

2021 ◽  
Vol 23 ◽  
pp. 318-331
Author(s):  
Aleksandra Czajkowska ◽  
Łukasz Gawor
Keyword(s):  
Water Quality ◽  
Surface Water ◽  
Ph Value ◽  
Surface Water Quality ◽  
Water Hardness ◽  
Total Content ◽  
Mining Area ◽  
Physicochemical Analysis ◽  
High Concentration ◽  
Mining Areas

In the paper there is presented an evaluation of variability of surface water quality (reservoirs and watercourses), on the area of degraded post-mining area in Bytom. The physicochemical analysis of water and compared with archival data obtained in 2009 and 2014. There were done analysis of following parameters: reaction, total content of substances dissolved in water, water hardness and the content of: Cl-, SO42-, HCO3-, Ca2+, Mg2+, K+, Na+, NH4+, NO3-, NO2-, PO4- ions as well as Fe and Mn. The examined surface waters were characterised by high content of solutes. Anions were dominated by chlorides, the sodium proved to be the dominating cation, the examined water samples were characterised by high concentration of sulphates. In all analyzed reservoirs, permissible concentrations of chlorides and sulphates were exceeded. In all sample points there was observed a decrease of pH value in long term period, the concentration of chlorides lowered, however concentrations of sulphates increased in the majority of sampling points.

PERFORMANCE EVALUATION OF A DEVELOPED PADDLE AERATOR ON CATFISH EFFLUENTS IN LAGOS STATE, NIGERIA

2017 ◽  
Vol 16 (1) ◽  
pp. 75-85
Author(s):  
O. E. OMOFUNMI ◽  
J. K. . ADEWUMI ◽  
A. F. ADISA ◽  
S. O. ALEGBELEYE
Keyword(s):  
Water Quality ◽  
Suspended Solids ◽  
Oxygen Demand ◽  
Total Suspended Solids ◽  
Dilution Ratio ◽  
Paddle Wheel ◽  
Lagos State ◽  
Total Ammonia ◽  
The Impact ◽  
Natural Purification

Catfish production is one of the largest segments of fish culture in Lagos State, Nigeria. However, catfish effluents, which usually deteriorate the environment, need to be controlled. The effect of paddle-wheel aerator in catfish effluent was evaluated. The volume of catfish effluent was collected into two basins and diluted at given ratios. The paddle-wheel aerator was installed in one basin, while another basin served as control in determining the impact of paddle wheel aerator on catfish effluents. Water qualities such as Total Suspended Solids (TSS), Total Nitrogen (TN), Total Phosphorus (TP), Total Ammonia (TNH3) and Nitrite (NO2-N) and Biochemical oxygen demand (BOD5) examined and ana-lysed. Results indicated that paddle-wheel aerator reduced TSS (24.4±1.5 %), TN2-N (53.3±1.2 %) , TNH3-N (65.2±1.2 %) , NO2-N (97.1±1.1 %) , TP (61.8±1.1 %) and BOD5 (54 ±1.5 %). com-pared with natural purification 33.9±1.6 % of TSS, 22.7±1.4 % of TN2-N, 29.3±1.6 % of TNH3-N, 53.9±1.2 % of NO2-N, 21.6±1.5 % of TP and 15.4±1.6 % of BOD5 at the same dilution ratio There were significant different (P ≤0.05) between paddle wheel aerator and natural purification in concen-trations reduction. The paddle wheel aerator was found to be relevant in the water quality improve-ment and thus recommend for small and medium scale fish farmers in controlling effluents.

scholarly journals Evaluation of water quality parameters for monitoring natural, urban, and agricultural areas in the Brazilian Cerrado

2012 ◽  
Vol 23 (3) ◽  
pp. 307-317 ◽  
Author(s):  
Daphne Heloisa de Freitas Muniz ◽  
Aline Silva Moraes ◽  
Ingrid de Souza Freire ◽  
Carlos José Domingos da Cruz ◽  
Jorge Enoch Furquim Werneck Lima ◽  
...  
Keyword(s):  
Water Quality ◽  
Sewage Treatment Plant ◽  
Treatment Plant ◽  
Water Hardness ◽  
Federal District ◽  
Ceriodaphnia Dubia ◽  
Fecal Coliforms ◽  
Total Hardness ◽  
E Coli ◽  
Ecotoxicological Evaluation

INTRODUCTION: Brazil's Federal District (FD) has seen steep population growth in recent years, and this has increased demand for high-quality water. AIM: The present work aims to evaluate the quality of surface water from two water bodies in the FD at six sampling points, three of which are in the Sobradinho River (the receiving body of a sewage treatment plant effluent) and three in the Jardim River (located in an agricultural region). METHODS: Analyses were carried out every thirty days, for twelve months, covering rainy and dry seasons. Parameters were analyzed such as temperature, pH, dissolved oxygen (DO), conductivity, turbidity, total hardness, main ions, total and fecal coliforms (E. coli) in water. Ecotoxicological evaluation was also performed, using the micro-crustacean Ceriodaphnia dubia. RESULTS: Data of physical and chemical determinations showed DO, conductivity, Cl-, NO3-, SO4(2-) and Na+ to be important in indicating contamination by urban effluents. On the subject of biological parameters - E. coli and ecotoxicological evaluation - the former was seen to be more effective in the urban area. However, in the countryside, the assay with C. dubia proved to be the most sensitive, although less than ideal, because the organism is very sensitive to low water hardness. CONCLUSIONS: The fecal coliform indicator (E. coli) was the most effective one for comparing water quality in the two basins, mainly for the urbanized one, while ecotoxicity assays with C. dubia were harmed by the natural chemical composition of the water.

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