Temporal Relation between Soluble Reactive Phosphorus and Factors in Stream Water and Sediments in Hoxie Gorge Creek, New York

1991 ◽  
Vol 48 (1) ◽  
pp. 84-90 ◽  
Author(s):  
R. L. Klotz

Temporal changes in soluble reactive phosphorus (SRP) were associated with sediment and streamwater factors in Hoxie Gorge Creek. Over the annual cycle, streamwater SRP was positively correlated with the zero equilibrium phosphate concentration (EPC0) of the sediments at two disparate sites. Phosphate release during biological decomposition of organic matter in the sediments may have been an important source of SRP at times of high temperature and low discharge at an upstream site. At a downstream site, with lower sediment organic content and ATP, geochemical processes in the sediments as influenced by Ca may have been partly responsible for long-term SRP variations. Short-term SRP changes measured during a storm event were linked by field and laboratory analyses to variation in streamwater Ca. During the storm, streamwater Ca and SRP were negatively correlated (r = −o 791; p < 0 05). Laboratory sorption experiments showed that EPC0 increased by 3.1 μg∙L−1 as Ca decreased by 4 mg∙L−1, simulating the change found during the storm. When streamwater Ca was experimentally increased by spiking with CaCl2 in the field, SRP decreased. Some temporal changes in streamwater SRP can be explained by interactions between sediments and streamwater Ca.

1988 ◽  
Vol 45 (11) ◽  
pp. 2026-2034 ◽  
Author(s):  
R. L. Klotz

Stream sediments were found to regulate the soluble reactive phosphorus (SRP) of stream water by geochemical processes. This conclusion was based on sediment analysis, laboratory sorption experiments, and measurement of the equilibrium phosphorus concentration (EPC). EPC is the concentration of P in the water at which there is neither sorption nor desorption of P by the sediments. At low flow conditions, streamwater SRP was highly correlated with EPC at six sites along Hoxie Gorge Creek (r = 0.979). EPC was inversely related to the ionic strength of the equilibrating solution, with Ca2+ producing larger changes than Na+. Minimum EPC values occurred near the neutral pH of the stream water and increased sharply in acidic and basic solutions. Also, EPC was negatively correlated with the exchangeable Al content of the sediments at the six sites. These data are consistent with a mechanism previously verified for soils in which solution cations displace exchangeable Al(III) from sediments; hydrolyzed Al(III) reacts with phosphate and removes it from solution. EPC and streamwater SRP were lower at sites with sediments that had higher concentrations of P-binding sites, despite also having higher sediment P.


Water ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 328 ◽  
Author(s):  
Laura B. Klaiber ◽  
Stephen R. Kramer ◽  
Eric O. Young

Quantifying the influence of tile drainage on phosphorus (P) transport risk is important where eutrophication is a concern. The objective of this study was to compare P exports from tile-drained (TD) and undrained (UD) edge-of-field plots in northern New York. Four plots (46 by 23 m) were established with tile drainage and surface runoff collection during 2012–2013. Grass sod was terminated in fall 2013 and corn (Zea mays L.) for silage was grown in 2014 and 2015. Runoff, total phosphorus (TP), soluble reactive phosphorus (SRP), and total suspended solids (TSS) exports were measured from April 2014 through June 2015. Mean total runoff was 396% greater for TD, however, surface runoff for TD was reduced by 84% compared to UD. There was no difference in mean cumulative TP export, while SRP and TSS exports were 55% and 158% greater for UD, respectively. A three day rain/snowmelt event resulted in 61% and 84% of cumulative SRP exports for TD and UD, respectively, with over 100% greater TP, SRP and TSS exports for UD. Results indicate that tile drainage substantially reduced surface runoff, TSS and SRP exports while having no impact on TP exports, suggesting tile drains may not increase the overall P export risk.


2004 ◽  
Vol 13 (1) ◽  
pp. 27 ◽  
Author(s):  
Scott L. Stephens ◽  
Thomas Meixner ◽  
Mark Poth ◽  
Bruce McGurk ◽  
Dale Payne

Before Euro-American settlement fire was a common process in the forests of the Lake Tahoe Basin. The combination of drought, fire suppression, and past harvesting has produced ecosystems that are susceptible to high-severity wildfires. Consequently, a program of prescribed fire has been recommended but there is incomplete understanding of the ecological effects of fuels treatments, especially with regard to how treatments will affect the flow of nutrients to Lake Tahoe. Nitrogen and phosphorus are the most important nutrients affecting algal growth, and thus lake clarity. Existing data demonstrate a long-term shift from a co-limitation by both nitrogen and phosphorus to phosphorus limitation. Two high-consumption, moderate-intensity prescribed fires were conducted to determine their effects on soil and stream water chemistry. Stream water calcium concentrations increased in burned watersheds whereas soluble reactive phosphorus concentrations were not significantly different. Prescribed fires released calcium and raised soil pH and this may have resulted in the incorporation of phosphorus into insoluble forms. Stream monitoring data indicates water quality effects last for ~3 months. Prescribed fires did not significantly increase the amount of soluble reactive phosphorus in stream waters. However, additional research is needed to determine if prescribed fire increases erosion or movement of particulate P, particularly in areas with steep slopes.


1991 ◽  
Vol 48 (8) ◽  
pp. 1460-1467 ◽  
Author(s):  
R. L. Klotz

The phosphorus fraction made available to organisms by the action of alkaline phosphatase, here termed phosphatase hydrolyzable phosphorus (PHP), was studied in central New York State streams. Annual mean PHP concentrations were <2.0 μg P∙L−1 for each of the four streams studied and were low relative to concentrations for lentic systems from the literature. The PHP to soluble reactive phosphorus (SRP) ratio, a measure of the relative importance of PHP for aquatic organisms, was typically in the 0.09–1.00 range, indicating that PHP could supply a significant amount of P at certain locations. Laboratory sorption experiments with varying ionic strength solutions and with Ca2+ versus Na+ suggested that PHP was probably bound to sediments by a different mechanism than SRP, one probably mediated by the organic moiety. Fine-grained sediments higher in organic matter sorbed excess PHP from solution at a greater rate than coarse-grained sediments, but also released more into PHP-depleted solutions.


Water ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 1947
Author(s):  
Ling Su ◽  
Chen Zhong ◽  
Lei Gan ◽  
Xiaolin He ◽  
Jinlei Yu ◽  
...  

The application of lanthanum modified bentonite (Phoslock®) and polyaluminium chloride (PAC) is popular in the restoration of European temperate lakes; however, the effects of the application on the concentrations of phosphorus (P) in both the water and the sediments have been poorly evaluated to date. We studied the effects of the application of Phoslock® + PAC on the concentrations of total phosphorus (TP), particulate phosphorus (PP), soluble reactive phosphorus (SRP), total suspended solids (TSS) and chlorophyll a (Chla) in the water, and different P forms in the sediments, in an isolated part of Lake Yanglan. The results showed that the concentrations of TP, PP, SRP, TSS and Chla decreased significantly after the addition of Phoslock® + PAC. Moreover, the concentrations of labile-P, reductant-soluble-P and organic-P in the sediments were also significantly decreased after the Phoslock® + PAC application. However, the concentrations of both the stable apatite-P and residual-P in the sediments after application of Phoslock® + PAC were much higher than the pre-addition values, while the concentrations of metal-oxide-P did not differ significantly between the pre- and post- application conditions. Our findings imply that the combined application of Phoslock® and PAC can be used in the restoration of subtropical shallow lakes, to reduce the concentrations of P in the water and suppress the release of P from the sediments.


2021 ◽  
Vol 772 ◽  
pp. 145494
Author(s):  
Ignacio Peralta-Maraver ◽  
Rachel Stubbington ◽  
Shai Arnon ◽  
Pavel Kratina ◽  
Stefan Krause ◽  
...  

2019 ◽  
Vol 2019 ◽  
pp. 1-9
Author(s):  
Qing Xu ◽  
Xiaoping Yu ◽  
Yafei Guo ◽  
Tianlong Deng ◽  
Yu-Wei Chen ◽  
...  

Overlying sediment and pore waters were collected in summer and winter at upstream (Jintang) and downstream (Neijiang) sites of the Tuohe River, which is one of the five largest tributaries of the Yangtze River in China. Phosphorus species, including soluble reactive phosphorus (SRP), soluble unreactive phosphorus (SUP), and total dissolved phosphorus (TDP), and some diagenetic constituents including dissolved Fe(II), Mn(II), and sulfide in overlying and pore waters, were measured systematically. The seasonal variations and vertical distributions of phosphorus species in overlying and pore waters at both sampling sites were obtained to elucidate some aspects of the transport and transformations of phosphorus. Based on the profiles of pore and overlying waters as well as the TDN/TDP data during an algal bloom in 2007, it was clearly demonstrated that phosphorus was the main factor limiting the phytoplankton growth in the Tuohe River.


2014 ◽  
Vol 122 (2-3) ◽  
pp. 229-251 ◽  
Author(s):  
Lauriane Vilmin ◽  
Najla Aissa-Grouz ◽  
Josette Garnier ◽  
Gilles Billen ◽  
Jean-Marie Mouchel ◽  
...  

1984 ◽  
Vol 41 (6) ◽  
pp. 985-988 ◽  
Author(s):  
A. H. El-Shaarawi ◽  
M. A. Neilson

Water samples were collected on Lake Ontario during April and November, filtered (0.45 μm), and immediately analyzed onboard ship for the nutrients soluble reactive phosphorus, nitrate-plus-nitrite, and ammonia. Replicates were stored in glass bottles at 4 °C and reanalyzed within 8 d. Statistical analysis showed that soluble reactive phosphorus decreased by 11 and 13% and nitrate-plus-nitrite by 7 and 6%, whereas ammonia increased by 75% on one cruise and decreased by 37% on the other.


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