Background Levels of Dissolved/Dispersed Petroleum Residues in the Gulf of St. Lawrence, 1970–79

1985 ◽  
Vol 42 (3) ◽  
pp. 544-555 ◽  
Author(s):  
E. M. Levy

A 10-yr program of monitoring the incidence and distribution of dissolved/dispersed petroleum residues in the Gulf of St. Lawrence confirmed that the major source is the Atlantic water that enters through Cabot Strait and demonstrated that a substantial decline in the background levels occurred during the mid-1970's. The present level, about 0.4 μg/L, is similar to those of other unpolluted areas off the east coast of Canada and in the Arctic where it appears that the input from atmospheric deposition exceeds those from accidental spills, deliberate discharges, and other point sources.

1986 ◽  
Vol 43 (3) ◽  
pp. 536-547 ◽  
Author(s):  
E. M. Levy

Background levels of petroleum residues in the form of particles floating on the sea and as substances extracted from the surface microlayer, the water column, and the surficial bottom sediments of the Hudson Strait/Foxe Basin and the Labrador shelf regions were measured during 1982 and 1983. No evidence of floating particulate oil was found in either region. Background levels of extractable petroleum residues in the surface microlayer were highly dependent on ambient sea conditions and ranged from 4.1 μg/L at the entrance to Hudson Strait to 28.3 μg/L on the southern Labrador shelf in 1982, and from 4.5 to 20.9 μg/L on the Labrador shelf in 1983 with the general background level at 8.13 μg/L. The background level in the water column in the Hudson Bay/Hudson Strait region was 0.46 μg/L in 1982 whereas that on the Labrador shelf was 0.42 μg/L during 1982 and 0.57 μg/L in 1983 (overall level of 0.51 μg/L). Concentration levels in the surficial bottom sediments depended primarily on the nature of the sediments and ranged from 1.9 μg/g at the eastern end of Hudson Strait to 52.5 μg/g on the continental slope east of Nain Bank with a general background level of 2.04 μg/g. These background levels are similar to those of other areas of the continental shelf off the east coast of Canada and are, presently, well below those known to have adverse biological consequences.


1996 ◽  
Vol 33 (4-5) ◽  
pp. 137-144 ◽  
Author(s):  
Josef Hejzlar ◽  
Vojtech Vyhnálek ◽  
Jirí Kopácek ◽  
Jirí Duras

Export and sources of P in the Vltava basin (subbasin of upper Elbe: total area – 28,093 km2; population density – 115 km−2; forests – 35%, farmland – 51%) were evaluated during 1972–1993. Annual export rates of total P from the basin to the river Elbe ranged between 38 and 68 kg km−2 a−1. Reservoirs with hydraulic retention times longer than 15 days were efficient traps for phosphorus retaining 20 to 30% of total P loading into the watercourses. Point sources (municipal wastewaters) were most important throughout the period and their share varied from approximately 60% in wet years to more than 90% in dry years. Export from diffuse sources (dominated by output from farmland) was highly dependent on discharge and fluctuaded between 5 and 40 kg km−2 a−1 in dry and wet years, respectively. Only about 2% of the P input into the basin from the fertilisation of farmland and from the atmospheric deposition was exported to the watercourses.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Rebecca Jackson ◽  
Anna Bang Kvorning ◽  
Audrey Limoges ◽  
Eleanor Georgiadis ◽  
Steffen M. Olsen ◽  
...  

AbstractBaffin Bay hosts the largest and most productive of the Arctic polynyas: the North Water (NOW). Despite its significance and active role in water mass formation, the history of the NOW beyond the observational era remains poorly known. We reconcile the previously unassessed relationship between long-term NOW dynamics and ocean conditions by applying a multiproxy approach to two marine sediment cores from the region that, together, span the Holocene. Declining influence of Atlantic Water in the NOW is coeval with regional records that indicate the inception of a strong and recurrent polynya from ~ 4400 yrs BP, in line with Neoglacial cooling. During warmer Holocene intervals such as the Roman Warm Period, a weaker NOW is evident, and its reduced capacity to influence bottom ocean conditions facilitated northward penetration of Atlantic Water. Future warming in the Arctic may have negative consequences for this vital biological oasis, with the potential knock-on effect of warm water penetration further north and intensified melt of the marine-terminating glaciers that flank the coast of northwest Greenland.


2021 ◽  
Author(s):  
Joanna Davies ◽  
Anders Møller Mathiasen ◽  
Kristiane Kristensen ◽  
Christof Pearce ◽  
Marit-Solveig Seidenkrantz

<p>The polar regions exhibit some of the most visible signs of climate change globally; annual mass loss from the Greenland Ice Sheet (GrIS) has quadrupled in recent decades, from 51 ± 65 Gt yr<sup>−1</sup> (1992-2001) to 211 ± 37 Gt yr<sup>−1</sup> (2002-2011). This can partly be attributed to the widespread retreat and speed-up of marine-terminating glaciers. The Zachariae Isstrøm (ZI) is an outlet glacier of the Northeast Greenland Ice Steam (NEGIS), one of the largest ice streams of the GrIS (700km), draining approximately 12% of the ice sheet interior. Observations show that the ZI began accelerating in 2000, resulting in the collapse of the floating ice shelf between 2002 and 2003. By 2014, the ice shelf extended over an area of 52km<sup>2</sup>, a 95% decrease in area since 2002, where it extended over 1040km<sup>2</sup>. Paleo-reconstructions provide an opportunity to extend observational records in order to understand the oceanic and climatic processes governing the position of the grounding zone of marine terminating glaciers and the extent of floating ice shelves. Such datasets are thus necessary if we are to constrain the impact of future climate change projections on the Arctic cryosphere.</p><p>A multi-proxy approach, involving grain size, geochemical, foraminiferal and sedimentary analysis was applied to marine sediment core DA17-NG-ST8-92G, collected offshore of the ZI, on  the Northeast Greenland Shelf. The aim was to reconstruct changes in the extent of the ZI and the palaeoceanographic conditions throughout the Early to Mid Holocene (c.a. 12,500-5,000 cal. yrs. BP). Evidence from the analysis of these datasets indicates that whilst there has been no grounded ice at the site over the last 12,500 years, the ice shelf of the ZI extended as a floating ice shelf over the site between 12,500 and 9,200 cal. yrs. BP, with the grounding line further inland from our study site. This was followed by a retreat in the ice shelf extent during the Holocene Thermal Maximum; this was likely to have been governed, in part, by basal melting driven by Atlantic Water (AW) recirculated from Svalbard or from the Arctic Ocean. Evidence from benthic foraminifera suggest that there was a shift from the dominance of AW to Polar Water at around 7,500 cal. yrs. BP, although the ice shelf did not expand again despite of this cooling of subsurface waters.</p>


2021 ◽  
Author(s):  
Helene R. Langehaug ◽  
Pablo Ortega ◽  
Francois Counillon ◽  
Daniela Matei ◽  
Elizabeth Maroon ◽  
...  

<p>In this study we assess to what extent seven different dynamical prediction systems can retrospectively predict the winter sea surface temperature (SST) in the subpolar North Atlantic and the Nordic Seas in the time period 1970-2005. We focus in particular on the region where warm water flows poleward, i.e., the Atlantic water pathway, and on interannual-to-decadal time scales. To better understand why dynamical prediction systems have predictive skill or lack thereof, we confront them with a mechanism identified from observations – propagation of oceanic anomalies from low to high latitudes – on different forecast lead times. This observed mechanism shows that warm and cold anomalies propagate along the Atlantic water pathway within a certain time frame. A key result from this study is that most models have difficulty representing this mechanism, resulting in an overall poor prediction skill after 1-2 years lead times (after applying a band-pass filter to focus on interannual-to-decadal time scales). There is a link, although not very strong, between predictive skill and the representation of the SST propagation. Observational studies demonstrate predictability several years in advance in this region, thus suggesting a great potential for improvement of dynamical climate predictions by resolving the causes for the misrepresentation of the oceanic link. Inter model differences in simulating surface velocities along the Atlantic water pathway suggest that realistic velocities are important to better circulate anomalies poleward, and hence, increase predictive skill on interannual-to-decadal time scales in the oceanic gateway to the Arctic.</p>


2019 ◽  
Vol 49 (1) ◽  
pp. 227-246 ◽  
Author(s):  
Igor V. Polyakov ◽  
Laurie Padman ◽  
Y.-D. Lenn ◽  
Andrey Pnyushkov ◽  
Robert Rember ◽  
...  

AbstractThe diffusive layering (DL) form of double-diffusive convection cools the Atlantic Water (AW) as it circulates around the Arctic Ocean. Large DL steps, with heights of homogeneous layers often greater than 10 m, have been found above the AW core in the Eurasian Basin (EB) of the eastern Arctic. Within these DL staircases, heat and salt fluxes are determined by the mechanisms for vertical transport through the high-gradient regions (HGRs) between the homogeneous layers. These HGRs can be thick (up to 5 m and more) and are frequently complex, being composed of multiple small steps or continuous stratification. Microstructure data collected in the EB in 2007 and 2008 are used to estimate heat fluxes through large steps in three ways: using the measured dissipation rate in the large homogeneous layers; utilizing empirical flux laws based on the density ratio and temperature step across HGRs after scaling to account for the presence of multiple small DL interfaces within each HGR; and averaging estimates of heat fluxes computed separately for individual small interfaces (as laminar conductive fluxes), small convective layers (via dissipation rates within small DL layers), and turbulent patches (using dissipation rate and buoyancy) within each HGR. Diapycnal heat fluxes through HGRs evaluated by each method agree with each other and range from ~2 to ~8 W m−2, with an average flux of ~3–4 W m−2. These large fluxes confirm a critical role for the DL instability in cooling and thickening the AW layer as it circulates around the eastern Arctic Ocean.


The Arctic Mediterranean Seas constitute an oceanic region in which the thermohaline circulation has a strong advective component and deep ventilation processes are very active relative to other oceanic areas. Details of the nature of these circulation and ventilation processes have been revealed through use of Cs and Sr isotopes from bomb-fallout and nuclear-waste sources as ocean tracers. In both cases, their regional input is dominated by advective supply in the Norwegian Atlantic Current and Norwegian Coastal Current, respectively. The different temporal, spatial, and compositional input patterns of these tracers have been used to study different facets of the regional circulation. These input differences and some representative applications of the use of these tracers are reviewed. The data discussed derive from samples collected both from research vessels and from Arctic ice camps. The topics addressed include: ( a ) the role of Arctic Intermediate Water as source, supplying recent surface water to North Atlantic Deep Water via the Denmark Strait overflow; ( b ) deep convective mixing in the Greenland Sea; ( c ) circulation or recirculation of Atlantic water in the Arctic basins; and ( d ) the role of Arctic shelfwaters in the ventilation of intermediate and deep water in the Eurasian and Canadian basins.


2020 ◽  
Vol 33 (18) ◽  
pp. 8107-8123 ◽  
Author(s):  
Igor V. Polyakov ◽  
Tom P. Rippeth ◽  
Ilker Fer ◽  
Matthew B. Alkire ◽  
Till M. Baumann ◽  
...  

AbstractA 15-yr duration record of mooring observations from the eastern (>70°E) Eurasian Basin (EB) of the Arctic Ocean is used to show and quantify the recently increased oceanic heat flux from intermediate-depth (~150–900 m) warm Atlantic Water (AW) to the surface mixed layer and sea ice. The upward release of AW heat is regulated by the stability of the overlying halocline, which we show has weakened substantially in recent years. Shoaling of the AW has also contributed, with observations in winter 2017–18 showing AW at only 80 m depth, just below the wintertime surface mixed layer, the shallowest in our mooring records. The weakening of the halocline for several months at this time implies that AW heat was linked to winter convection associated with brine rejection during sea ice formation. This resulted in a substantial increase of upward oceanic heat flux during the winter season, from an average of 3–4 W m−2 in 2007–08 to >10 W m−2 in 2016–18. This seasonal AW heat loss in the eastern EB is equivalent to a more than a twofold reduction of winter ice growth. These changes imply a positive feedback as reduced sea ice cover permits increased mixing, augmenting the summer-dominated ice-albedo feedback.


2021 ◽  
Author(s):  
Eleftherios Ioannidis ◽  
Kathy S. Law ◽  
Jean-Christophe Raut ◽  
Tatsuo Onishi ◽  
Louis Marelle ◽  
...  

<p>The wintertime Arctic is influenced by air pollution transported from mid-latitudes, leading to formation of Arctic Haze, as well as local emissions such as combustion for heating and power production in very cold winter conditions. This contributes to severe air pollution episodes, with enhanced aerosol concentrations, inter-dispersed with cleaner periods. However, the formation of secondary aerosol particles (sulphate, organics, nitrate) in cold/dark wintertime Arctic conditions, which could contribute to these pollution episodes, is poorly understood.</p><p>In this study, which contributes to the Air Pollution in the Arctic: Climate, Environment and Societies - Alaskan Layered Pollution and Arctic Chemical Analysis (PACES-ALPACA) initiative, the Weather Research Forecasting Model with chemistry (WRF-Chem) is used to investigate wintertime pollution over central Alaska focusing on the Fairbanks region, during the pre-ALPACA campaign in winter 2019-2020. Fairbanks is the most polluted city in the United States during wintertime, due to high local emissions and the occurrence of strong surface temperature inversions trapping pollutants near the surface.</p><p>Firstly, different WRF meteorological and surface schemes were tested over Alaska with a particular focus on improving simulations of the wintertime boundary layer structure including temperature inversions. An optimal WRF set-up, with increased vertical resolution below 2km, was selected based on evaluation against available data.</p><p>Secondly, a quasi-hemispheric WRF-Chem simulation, using the improved WRF setup, was used to assess large-scale synoptic conditions and to evaluate background aerosols originating from remote anthropogenic and natural sources affecting central Alaska during the campaign. The model was run with Evaluating the Climate and Air Quality Impacts of Short-Lived Pollutants (ECLIPSE) v6b anthropogenic emissions and improved sea-spray aerosol emissions. Discrepancies in modelled aerosols compared available data are being investigated (e.g. missing dark formation mechanisms, treatment of removal processes).</p><p>Thirdly, fine resolution simulations, using high resolution emissions (e.g. 2019 CAMS inventory), including local point sources, over the Fairbanks region, were used to investigate chemical and dynamical processes influencing aerosols under different meteorological conditions observed during the field campaign including a cold stable episode and a period with possible mixing of air masses from aloft. The model was evaluated against available aerosol, oxidant (ozone) and aerosol precursor data from surface monitoring sites and collected during the pre-campaign, including vertical profile data collected in the lowest 20m. The sensitivity of modelled aerosols to meteorological factors, such as relative humidity, temperature gradients and vertical mixing under winter conditions are investigated.</p>


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