CALCULATIONS IN THE INVESTIGATION OF OILS AND FATS WITH SPECIAL REFERENCE TO FISH OILS: PART I
Equations relating total iodine values and equivalents of mixtures of esters of the fatty acids to those of the individual esters are given. Together with a knowledge of the percentages of saturated esters these equations enable the composition of simple mixtures (refractionations of the lower-boiling fractions) to be deduced from the iodine values and equivalents. In the case of the more highly unsaturated fractions where the data are not sufficient to lead to an estimate of the amounts of the individual esters in the mixture, a partial solution has been given by grouping the esters according to carbon content and calculating the average unsaturations of these groups. The computations are illustrated with data taken from a paper by Guha, Hilditch and Lovern, the results being expressed in percentages by weight, but for the sake of completeness the method of calculating molecular percentages is also illustrated. Also a method of correcting the data of the lower-boiling fractions is suggested and by means of actual data the effect of errors in the data on the estimated composition of a fraction is shown.