Solute chemistry of inclusion fluids from sparry dolomites and magnesites in Middle Cambrian carbonate rocks of the southern Canadian Rocky Mountains
Middle Cambrian carbonate rocks of the southern Canadian Rocky Mountains are host to widespread units of white, sparry, hydrothermal, replacement, and open-space filling dolomite. Contained within the dolomites are occurrences of talc and Mississippi Valley type Pb-Zn (the former Kicking Horse and Monarch mines) mineralization and economic concentrations of magnesite (Mount Brussilof mine). Results of studies of solute chemistry of saline (18-25 equivalent wt.% NaCl) inclusion fluids reveal distinctly low Na/Br (55-220) and Cl/Br (95-340) values. These values indicate that the brines which formed the dolomite originated from seawater that had deposited large amounts of halite in an evaporitic environment. Low I/Br ratios for the dolomite-magnesite inclusion fluids are consistent with their derivation from seawater and contrast sharply with the high I/Br ratios of Laramide-age fluids, which formed veins throughout the Rocky Mountains. Variations in F/Br ratios between texturally early and late magnesites indicate the involvement of a second fluid in the formation of the late magnesites. Results of the study of solute chemistry of inclusion fluids from hydrothermal dolomites, magnesites, and associated mineralization are consistent with a model of the pre-Laramide formation of these materials from seawater that had undergone extensive evaporation and halite deposition. Distinct differences in I/Br, total salinity, and delta D values between the dolomite-magnesite depositing fluids and Laramide-age vein-forming fluids clearly indicate the lack of the involvement of Laramide-age fluids in the genesis of the dolomites, magnesites, and associated mineralization.