Nd–Sr isotope systematics of Nicola Group volcanic rocks, Quesnel terrane

1995 ◽  
Vol 32 (4) ◽  
pp. 437-446 ◽  
Author(s):  
Alan D. Smith ◽  
Alan D. Brandon ◽  
Richard StJ. Lambert
Keyword(s):  
Mantle Wedge ◽  
Source Region ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Late Triassic ◽  
Island Arcs ◽  
Early Mesozoic ◽  
High K ◽  
Low K ◽  
Isotope Systematics

Volcanic rocks of the Nicola Group belong to an arc built on the western margin of the Quesnel terrane in the Late Triassic to Early Jurassic. Low-K – high-K compositional types define a Rb–Sr isochron of 222 ± 15 Ma with initial 87Sr/86Sr = 0.70367 ± 2. The corresponding Nd isotopic compositions of these samples (εNd(222 Ma) = +5.1 to +7.8) fall within the range for early Mesozoic island arcs. A comparable range of εNd(222 Ma) (+5.0 to +7.9) in picrite–shoshonite samples precludes generation of increasingly potassic magmas by progressive metasomatism of the mantle wedge alone. Source-region heterogeneity, possibly imparted by changes in the composition of subducted slab components or interaction with amphibole or phlogopite in the source remnant of an earlier (Permian) arc on the Quesnel terrane, is required to account for geochemical differences between these rock suites. Crustal contamination is severely limited from the high εNd values, such that continental basement now underlying the Quesnel terrane is likely an artifact of later terrane obduction.

Sr and O isotope constraints on source and crustal contamination in the high-K calc-alkaline and shoshonitic neogene volcanic rocks of SE Spain

Lithos ◽  
1999 ◽  
Vol 46 (4) ◽  
pp. 773-802 ◽  
Author(s):  
R. Benito ◽  
J. López-Ruiz ◽  
J.M. Cebriá ◽  
J. Hertogen ◽  
M. Doblas ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Calc Alkaline ◽  
Se Spain ◽  
High K ◽  
O Isotope

Geochemistry and origin of Mesoproterozoic metavolcanic rocks from Fisher Massif, Prince Charles Mountains, East Antarctica

1996 ◽  
Vol 8 (1) ◽  
pp. 85-104 ◽  
Author(s):  
E. V. Mikhalsky ◽  
J. W. Sheraton ◽  
A. A. Laiba ◽  
B. V. Beliatsky
Keyword(s):  
Tectonic Setting ◽  
Active Continental Margin ◽  
Volcanic Rocks ◽  
Granulite Facies ◽  
Island Arc ◽  
Crustal Component ◽  
Basaltic Rocks ◽  
Metavolcanic Rocks ◽  
High K ◽  
Low K

Fisher Massif consists of Mesoproterozoic (c. 1300 Ma) lower amphibolite-facies metavolcanic rocks and associated metasediments, intruded by a variety of subvolcanic and plutonic bodies (gabbro to granite). It differs in both composition and metamorphic grade from the rest of the northern Prince Charles Mountains, which were metamorphosed to granulite facies about 1000 m.y. ago. The metavolcanic rocks consist mainly of basalt, but basaltic andesite, andesite, and more felsic rocks (dacite, rhyodacite, and rhyolite) are also common. Most of the basaltic rocks have compositions similar to low-K island arc tholeiites, but some are relatively Nb-rich and more akin to P-MORB. Intermediate to felsic medium to high-K volcanic rocks, which appear to postdate the basaltic succession, have calc-alkaline affinities and probably include a significant crustal component. On the present data, an active continental margin with associated island arc was the most likely tectonic setting for generation of the Fisher Massif volcanic rocks.

Petrology and geochemistry of volcanic rocks of the Cerro Galan caldera, northwest Argentina

1989 ◽  
Vol 126 (5) ◽  
pp. 515-547 ◽  
Author(s):  
P. W. Francis ◽  
R. S. J. Sparks ◽  
C. J. Hawkesworth ◽  
R. S. Thorpe ◽  
D. M. Pyle ◽  
...  
Keyword(s):  
Fractional Crystallization ◽  
Source Region ◽  
Crustal Contamination ◽  
Crustal Material ◽  
Magma Chambers ◽  
Northwest Argentina ◽  
Incompatible Elements ◽  
High K ◽  
Uniform Region ◽  
Compositional Zonation

AbstractAt least 2000 km3 of relatively uniform dacitic magma have been erupted from the Cerro Galan caldera complex, northwest Argentina. Between 7 and 4 Ma ago several composite volcanoes predominantly of dacitic lava were constructed, and several large high-K dacitic ignimbrites were erupted. 2.2 Ma ago the > 1000km3 Cerro Galan ignimbrite was erupted. The predominant mineral assemblage in the ignimbrites is plagioclase-biotite-quartz-magnetite-ilmenite; the Cerro Galan ignimbrite also contains sanidine. Fe-Ti oxide minerals in the Cerro Galan ignimbrite imply temperatures of 801–816 °C. Plagioclase phenocrysts in the ignimbrites typically have rather homogeneous cores surrounded by complex, often oscillatory zoned, rims. Core compositions show a marked bimodality, with one population consisting of calcic cores surrounded by normally zoned rims, and a second of sodic cores surrounded by reversely zoned rims. The older ignimbrites do not show systematic compositional zonation, but the Cerro Galan ignimbrite exhibits small variations in major elements (66–69% SiO2) and significant variations in Rb, Sr, Ba, Th and other trace elements, consistent with derivation from a weakly zoned magma chamber, in which limited fractional crystallization occurred. The ignimbrites have 87Sr/86Sr = 0.7108–0.7181; 143Nd/144Nd = 0.51215–0.51225, and δ18O = + 10 to + 12.5, consistent with a significant component of relatively non-radiogenic crust with high Rb/Sr and enriched in incompatible elements. Nd model ages for the source region are about 1.24 Ga. 87Sr/86Sr measurements of separated plagioclases indicate that Anrich cores have slightly lower 87Sr/86Sr than less calcic plagioclases, suggesting a small degree of isotopic heterogeniety in different components within the magmas. Pb isotope data for plagioclase show restricted ranges (206Pb/204Pb, 207Pb/204Pb and 208Pb/204Pb = 18.87–18.92, 15.65–15.69 and 39.06–39.16 respectively), and suggest derivation from Proterozoic crustal material(> 1.5 Ga).Contemporaneous satellite scoria cones and lavas are high-K basalts, basaltic andesites and andesites with SiO2 = 51–57%; K2O = 2–3% and normative plagioclase compositions of An37–48, and may be derived from a mantle source containing both ‘subduction zone’ and ‘within plate’ components. 87Sr/86Sr ranges from 0.7055 to 0.7094 and 143Nd/144Nd from 0.51250 to 0.51290. Variation diagrams such as MgO: SiO2 show two trends, one indicating closed system fractional crystallization and the other crustal contamination. AFC modelling of the open system rocks indicates a parental mantle-derived mafic magma which is itself enriched in K, Rb, Ba, U, Ta/Sm, Ta/Th and Sr, and has 87Sr/86Sr = 0.705–0.706, while the contaminant need not be more radiogenic than the dacitic ignimbrites.The Cerro Galan dacitic magmas are interpreted in terms of a deep and uniform region of the central Andean continental crust repeatedly melted by emplacement of incompatible-element-enriched, mantle-derived mafic magmas, a proportion of which may also have mixed with the dacite magmas. A component of the crustal material had a Proterozoic age. The magmas derived by crustal melting were also enriched in incompatible elements either by crystal/liquid fractionation processes, or by metasomatism of their source regions just prior to magma generation. Much of the crystallization took place in the source region during the melting process or in mid-crustal magma chambers. The magmas may have re-equilibrated at shallow levels prior to eruption, but only limited compositional zonation developed in high-level magma chambers.

scholarly journals The alkaline intraplate volcanism of the Antalya nappes (Turkey): a Late Triassic remnant of the Neotethys

2008 ◽  
Vol 179 (4) ◽  
pp. 397-410 ◽  
Author(s):  
René C. Maury ◽  
Henriette Lapierre ◽  
Delphine Bosch ◽  
Jean Marcoux ◽  
Leopold Krystyn ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Late Triassic ◽  
Primitive Mantle ◽  
Heavy Rare Earth Element ◽  
Alkali Basalts ◽  
Crustal Component ◽  
Ocean Island ◽  
Ocean Island Basalts ◽  
Enriched Mantle

AbstractLate Triassic submarine alkali basalts and hawaiites were collected from two superimposed tectonic slices belonging to the Kara Dere – Sayrun unit of the Middle Antalya nappes, southwestern Turkey. New determinations on conodont faunas allow to date this sequence to the Lower Carnian (Julian). The volcanic rocks show rather homogeneous compositions, with high TiO2 and relatively low MgO and Ni contents which suggest olivine fractionation. Their primitive mantle-normalised multi-elements plots show Nb and Ta enrichments relative to La, Pb negative anomalies and heavy rare earth element and Y depletions typical of intraplate ocean island basalts. These characteristics are consistent with the major and trace element compositions of their primary clinopyroxene phenocrysts, which do not show any feature ascribable to crustal contamination. The studied lavas display a restricted range of εNd (+4.6 to +5.2) which falls within the range of ocean island basalts. Their initial (143Nd/144Nd)i ratios are too low to be explained by a simple mixing line between depleted MORB mantle (DMM) and HIMU components. Their Pb and Nd isotopic compositions plot along a mixing line between HIMU component and an enriched mantle, the composition of which could be the result of the addition of about 5 to 8% of an EM2 component (recycled marine sediments) to DMM. The lack of evidence for any continental crustal component in their genesis could be consistent with their emplacement in an intra-oceanic setting.

Lithospheric mantle, asthenosphere, slab and crustal contribution to petrogenesis of Eocene to Miocene volcanic rocks from the west Alborz Magmatic Assemblage, SE Ahar, Iran

2020 ◽  
pp. 1-32
Author(s):  
Ahmad Ahmadvand ◽  
Mohammad Reza Ghorbani ◽  
Mir Ali Asghar Mokhtari ◽  
Yi Chen ◽  
William Amidon ◽  
...  
Keyword(s):  
Lithospheric Mantle ◽  
Mantle Wedge ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
The West ◽  
Nw Iran ◽  
Enriched Mantle ◽  
Basement Rocks ◽  
Cenozoic Volcanism ◽  
Back Arc

Abstract Significant uncertainty remains regarding the exact timing and nature of subduction events during the closure of the Tethyan seas in what is now NW Iran. This study thus presents new geochemical compositions and U–Pb ages for a suite of volcanic rocks emplaced during Cenozoic volcanism in the west Alborz Magmatic Assemblage, which is commonly regarded as the back-arc of the Neotethyan magmatism in Central Iran. The subalkali basalts and andesites are dated to 57 ± 1.2 Ma, and are likely derived from a supra-subduction mantle wedge. Later, trachytic A-type rocks erupted from ~42 to 25 Ma during an anorogenic (extensional) stage triggered by slab retreat and associated asthenospheric mantle influx. A-type melts were at least partly concurrent with lithospheric mantle magmatism implied by eruption of subalkali basalts–andesites around 26–24 Ma. Next, Amp-Bt trachybasaltic volcanism with high-Nb basaltic affinity at ~19 Ma likely records slab deepening and slab partial melting, which reacted with the mantle wedge to produce the source material for the high-Nb basalts. Sr–Nd isotopic ratios for SE Ahar mafic as well as A-type rocks imply rather enriched mantle source(s). Some crustal contamination is implied by the presence of inherited zircons dominated by those derived from Neoproterozoic–Cambrian basement rocks and Carboniferous magmatism. Rhyolitic rocks with adakitic affinity probably mark the final volcanism in the study area. The adakitic rocks show crustal signatures such as high K and Th, probably formed as a consequence of higher temperature gradients, at crustal levels, imposed by both slab and mantle partial melts.

scholarly journals Origin of the High-K Tertiary magmatism in Northern Greece: Implications for mantle geochemistry and geotectonic setting.

2013 ◽  
Vol 47 (1) ◽  
pp. 416
Author(s):  
K. Pipera ◽  
A. Koroneos ◽  
T. Soldatos ◽  
G. Poli ◽  
G. Christofides
Keyword(s):  
Mantle Source ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Calc Alkaline ◽  
Northern Greece ◽  
Mafic Rocks ◽  
High K ◽  
Depleted Mantle ◽  
Subducted Oceanic Crust ◽  
Compositional Variations

Tertiary plutonic and volcanic rocks cropping out in the Rhodope Massif (N. Greece) are studied using existing and new geochemical and isotopic data. Most of these rocks belong to the post-collisional magmatism formed as part of the prolonged extensional tectonics of the Rhodope region in Late Cretaceous– Paleogene time. This magmatism is considered to be of mantle origin; however, the character of the mantle source is controversial. Rock bulk chemistry and compositional variations show magmas with calc-alkaline to high-K calc-alkaline and shoshonitic features associated with magmatism at convergent margins. Initial 87Sr/86Sr, 143Nd/144Nd ratios, Pb isotopes and REE composition of the mafic rocks indicate mainly an enriched mantle source, even if some rocks indicate a depleted mantle source. Low- and High-K mafic members of these rocks coexist indicating a strongly heterogeneous mantle source. The High-K character of some of the mafic rocks is primarily strongly related to mantle enrichment by subduction-related components, rather than crustal contamination. The geochemical characteristics of the studied rocks (e.g Ba/Th,Th/Yb,Ba/La, U/Th, Ce/Pb) indicate that primarily sediments and/or sediment melts, rather than fluid released by the subducted oceanic crust controlled the source enrichment under the Rhodope Massif.

A Late Miocene magmatic flare-up in West Sulawesi triggered by Banda slab rollback

2020 ◽  
Vol 132 (11-12) ◽  
pp. 2517-2528
Author(s):  
Xiaoran Zhang ◽  
Chia-Yu Tien ◽  
Sun-Lin Chung ◽  
Adi Maulana ◽  
Musri Mawaleda ◽  
...  
Keyword(s):  
Late Miocene ◽  
Source Region ◽  
River Sediments ◽  
Volcanic Rocks ◽  
Detrital Zircons ◽  
Magma Source ◽  
Magmatic Rocks ◽  
High K ◽  
Slab Rollback ◽  
T Values

Abstract Cenozoic magmatism occurs throughout West Sulawesi, Indonesia, yet its detailed evolution remains enigmatic due mainly to the scarcity of precise dating. Here, we report new whole-rock geochemical and zircon U-Pb-Hf isotopic data of plutonic/volcanic rocks and river sediments from West Sulawesi to constrain the petrogenesis and magmatic tempo. The magmatic rocks are intermediate to felsic (SiO2 = 58.1–68.0 wt%), high-K calc-alkaline to shoshonitic (K2O = 2.2–6.0 wt%), metaluminous to weakly peraluminous, and I-type in composition. Trace element concentrations and ratios (e.g., Nb/U = 1.7–4.3 and Ti/Zr < 28), along with negative zircon εHf(t) values (–17.0 to –0.4) and old crustal model ages (TDMC = 2.1–1.1 Ga), indicate a dominant magma source region from the underlying continental crystalline basement. U-Pb dating on zircons from ten magmatic rocks yielded weighted mean 206Pb/238U ages of 7.2–6.1 Ma, best representing the crystallization ages of host magmas, further consistent with the prominent age peaks (7.3–6.3 Ma) defined by detrital zircons from four sedimentary samples. Our new data, combined with available results, allow the identification of a noticeable climax of magmatism (flare-up) at ca. 7–6 Ma, forming a continuous magmatic belt throughout West Sulawesi. Given the absence of contemporaneous subduction and the coincidence of incipient opening of the South Banda Basin during ca. 7.15–6.5 Ma, the Late Miocene magmatic flare-up in West Sulawesi and coeval regional extension in eastern Indonesia are attributed to a resumed episode of Banda slab rollback.

Superhydrous Arc Magmas in the Alpine Context

Elements ◽  
2021 ◽  
Vol 17 (1) ◽  
pp. 35-40 ◽  
Author(s):  
Othmar Müntener ◽  
Peter Ulmer ◽  
Jonathan D. Blundy
Keyword(s):  
Mantle Wedge ◽  
Volcanic Rocks ◽  
Geochemical Data ◽  
The West ◽  
Arc Magmas ◽  
Magmatic Rocks ◽  
Fluid Saturation ◽  
The Alps ◽  
Low K ◽  
Primary Magmas

Magmatic rocks in the Alps are scarce. What little arc magmatism there was pre-dates the Eurasia–Adria collision at 43–34 Ma but ends at 30–29 Ma. Conversely, geochemical data for magmatic rocks from the Alps resemble that of subduction-related magmatic arcs. A characteristic of Alpine magmatism is the occurrence of relatively deep (80–100 km) super-hydrous (>8 wt% H2O) low-K primary magmas in the east and shoshonitic K-rich magmas in the west. These features are likely related to the absence of vigorous mantle wedge convection. Superhydrous primary magmas undergo extensive crystallization and fluid saturation at depth, producing high ratios of plutonic to volcanic rocks. We speculate that superhydrous primary arc magmas are a consequence of slow convergence and the initial architecture of subducting crust.

Alteration of volcanic rocks and genesis of kaolin deposits in the Şile Region, northern İstanbul, Turkey. Part II: differential mobility of elements

Clay Minerals ◽  
2003 ◽  
Vol 38 (4) ◽  
pp. 529-550 ◽  
Author(s):  
O. I. Ece ◽  
Z.-E Nakagawa
Keyword(s):  
Upper Cretaceous ◽  
Source Region ◽  
Volcanic Rocks ◽  
Crustal Contamination ◽  
Aegean Sea ◽  
Calc Alkaline ◽  
Tectonic Zone ◽  
Nw Turkey ◽  
Parent Rocks ◽  
Kaolin Deposit

AbstractIn the area of S° ile, NW Turkey, Upper Cretaceous calc-alkaline volcanic rocks with compositions ranging from andesite to rhyolite have been recognized. The most widespread rocks of the suite are andesites, which can be grouped into altered and fresh. The oldest altered andesites are the parent rocks for the kaolin deposits of the study area. The Upper Cretaceous volcanic suite consists of spilite, basalt, andesite, trachyandesite, trachyandesitic and hyaloandesitic dacite, rhyolite lavas, tuffs and agglomerates. The highly altered andesites are composed of plagioclase, pyroxene, hornblende, biotite, augite and very fine opaque minerals. During the Turonian, an E –W trending extensional magmatic arc was developed in the Istanbul Tectonic Zone of the oceanic Western Black Sea basin and intermediate volcanic rocks were emplaced, mostly calc-alkaline andesites, suggesting multi-stage magmatism. The significant features of the andesites are: (1) enrichment of LILE (Rb, Ba, K) over HFSE (Zr, Nb, Hf, Ti, Th, U, Y) and LREE (La –Sm), resulting in high Ba/Nb, Th/Nb, Ba/La, K/Ti and Th/La ratios; (2) depletion of LREE over HFSE, MREE and HREE, generating high La/Nb, Ce/Ti, La/Sm and La/Y values; and (3) depletion of Nb, Sr and Ti; all of which are typical of island arc magmatism, with possible back arc signature. The Th-Hf-Ta diagram for tectonomagmatic classification shows that the S° ile calc-alkaline rocks are similar to volcanic rocks from the Mariana Arc, the Aeolian Arc of Salina, Italy, the Skaros island in the Aegean Sea and Sardinia's ignimbrites. Moreover, relatively low La/Th and Ce/Pb ratios suggest that the source region of volcanism was enriched in LILE with respect to REE, indicating crustal contamination during melting.Highly weathered andesitic rocks, rich in smectite, were transported gradually and deposited in a lacustrine basin, a coal-forming dysaerobic environment, in which they were subject to post-depositional alteration, or in situkaolinization, to form a kaolin deposit in the presence of humic and fulvic acids. The mobility of major and trace elements and REEs during the progressive kaolinization of andesitic materials has been investigated to reveal the geochemical characteristics of Upper Cretaceous volcanic parent rocks and to explain mineralogical processes in a kaolin deposit as a daughter rock ‘end-product’ . Alteration is characterized by the loss of Si, Fe, Ca, Na and K, and by the gain of Al, Ti, Zr and LOI. Moreover, Ho, Er and Yb are immobile, and Hf, Zr and Nb are mobile. Th and U are slightly enriched in clay horizons with respect to the andesitic rocks. In addition, Cr, Ga, Nb and Ta enrichments indicate variable sources of terrigenous sediments and differential mobilities of elements in lake waters rich in organic acids. The anatase concentration increases in the <2 mm size fractions as subspherical particles and these precipitate at acidic conditions (pH ≈ 5) during early diagenesis.

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