Hydrothermal zircon and baddeleyite in Val-d'Or Archean mesothermal gold deposits: characteristics, compositions, and fluid-inclusion properties, with implications fortiming of primary gold mineralization

1993 ◽  
Vol 30 (12) ◽  
pp. 2334-2351 ◽  
Author(s):  
Robert Kerrich ◽  
Robert King
Keyword(s):  
Fluid Inclusion ◽  
Gold Mineralization ◽  
Wall Rock ◽  
Gold Deposits ◽  
Southern Volcanic Zone ◽  
Primary Fluid ◽  
Inheritance Model ◽  
Homogenization Temperatures ◽  
Host Rocks

Zircon and baddeleyite occur within quartz–tourmaline veins at four gold deposits in the Val-d'Or district of the Archean Abitibi Southern Volcanic Zone. Host rocks have experienced intense metasomatic enrichment of Zr, Hf, Y, and rare earth elements. The zircons contain primary inclusions of quartz, tourmaline, pyrite, albite, K-mica, scheelite, and gold, and gold occurs in primary fluid inclusions in zircons. Magmatic zircons in host rocks do not have this suite of inclusions; consequently a wall-rock inheritance model for the vein zircons is implausible. Compositionally, the zircons feature pronounced interzone and intergrain variations of Hf, Y, Yb, Th, and U, and sporadic anomalous Ce contents of ~ 1100 ppm, distinct from magmatic counterparts. Two principal types of primary fluid inclusion occur in the vein zircons. Type 1 H2O–CO2 inclusions have low salinities, variable quantities of CO2 and homogenization temperatures of 260–380 °C, and type 2 CO2 rich inclusions contain minor H2O and CH4. The vein zircons coprecipitated at 260–380 °C and ~ 2 kbar (1 kbar = 100 MPa) with coexisting minerals of undisputed hydrothermal origin, such as vein quartz and gold. In the Superior Province, mesothermal gold deposits are related in space and time to translithospheric structures that mark the diachronous accretion of allochthonous subprovinces from north to south between ~ 2710 and 2680 Ma. Consequently, vein zircon ages of ~ 2680 Ma record the primary mineralizing event, whereas aberrantly young ages for rutile, titanite, scheelite, and micas in the same vein systems, that scatter over 2630–2579 Ma, reveal the age of secondary remobilization events.

scholarly journals Ore-Fluid Evolution of the Sizhuang Orogenic Gold Deposit, Jiaodong Peninsula, China

Minerals ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 190 ◽  
Author(s):  
Yu-Ji Wei ◽  
Li-Qiang Yang ◽  
Jian-Qiu Feng ◽  
Hao Wang ◽  
Guang-Yao Lv ◽  
...  
Keyword(s):  
Fluid Inclusion ◽  
Gold Deposit ◽  
Late Stage ◽  
Gold Mineralization ◽  
Early Stage ◽  
Main Stage ◽  
Jiaodong Peninsula ◽  
Wide Range ◽  
Homogenization Temperatures

The Sizhuang gold deposit with a proven gold resource of >120 t, located in northwest Jiaodong Peninsula in China, lies in the southern part of the Jiaojia gold belt. Gold mineralization can be divided into altered rock type, auriferous quartz vein type, and sulfide-quartz veinlet in K-feldspar altered granite. According to mineral paragenesis and mineral crosscutting relationships, three stages of metal mineralization can be identified: early stage, main stage, and late stage. Gold mainly occurs in the main stage. The petrography and microthermometry of fluid inclusion shows three types of inclusions (type 1 H2O–CO2 inclusions, type 2 aqueous inclusions, and type 3 CO2 inclusions). Early stage quartz-hosted inclusions have a trapped temperatures range 303–390 °C. The gold-rich main stage contains a fluid-inclusion cluster with both type 1 and 2 inclusions (trapped between 279 and 298 °C), and a wide range of homogenization temperatures of CO2 occurs to the vapor phase (17.6 to 30.5 °C). The late stage calcite only contains type 1 inclusions with homogenization temperatures between 195 and 289 °C. With evidences from the H–O isotope data and the study of water–rock interaction, the metamorphic water of the Jiaodong Group is considered to be the dominating source for the ore-forming fluid. The ore-fluid belonged to a CO2–H2O–NaCl system with medium-low temperature (160–360 °C), medium-low salinity (3.00–11.83 wt% NaCl eq.), and low density (1.51–1.02 g/cm3). Fluid immiscibility caused by pressure fluctuation is the key mechanism in inducing gold mineralization in the Sizhuang gold deposit.

U-Pb Dating on Hydrothermal Rutile and Monazite from the Badu Gold Deposit Supports an Early Cretaceous Age for Carlin-Type Gold Mineralization in the Youjiang Basin, Southwestern China

2021 ◽  
Author(s):  
Wei Gao ◽  
Ruizhong Hu ◽  
Albert H. Hofstra ◽  
Qiuli Li ◽  
Jingjing Zhu ◽  
...  
Keyword(s):  
Gold Deposit ◽  
Early Cretaceous ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Detrital Zircons ◽  
Youjiang Basin ◽  
Host Rocks ◽  
Gold Bearing ◽  
Carlin Type Gold Deposits

Abstract The Youjiang basin on the southwestern margin of the Yangtze block in southwestern China is the world’s second largest Carlin-type gold province after Nevada, USA. The lack of precise age determinations on gold deposits in this province has hindered understanding of their genesis and relation to the geodynamic setting. Although most Carlin-type gold deposits in the basin are hosted in calcareous sedimentary rocks, ~70% of the ore in the Badu Carlin-type gold deposit is hosted by altered and sulfidized dolerite. Although in most respects Badu is similar to other Carlin-type gold deposits in the province, alteration of the unusual dolerite host produced hydrothermal rutile and monazite that can be dated. Field observations show that gold mineralization is spatially associated with, but temporally later than, dolerite. In situ secondary ion mass spectrometry (SIMS) U-Pb dating on magmatic zircon from the least altered dolerite yielded a robust emplacement age of 212.2 ± 1.9 Ma (2σ, mean square of weighted deviates [MSWD] = 0.55), providing a maximum age constraint on gold mineralization. The U-Th/He ages of detrital zircons from hydrothermally mineralized sedimentary host rocks at Badu and four other Carlin-type gold deposits yielded consistent weighted mean ages of 146 to 130 Ma that record cooling from a temperature over 180° to 200°C and place a lower limit on the age of gold mineralization in the basin. Hydrothermal rutile and monazite that are coeval with gold mineralization have been identified in the mineralized dolerite. Rutile is closely associated with hydrothermal ankerite, sericite, and gold-bearing pyrite. It has high concentrations of W, Fe, V, Cr, and Nb, as well as growth zones that are variably enriched in W, Fe, Nb, and U. Monazite contains primary two-phase fluid inclusions and is intergrown with gold-bearing pyrite and hydrothermal minerals. In situ SIMS U-Pb dating of rutile yielded a Tera-Wasserburg lower intercept age of 141.7 ± 5.8 Ma (2σ, MSWD = 1.04) that is within error of the in situ SIMS Th-Pb age of 143.5 ± 1.4 Ma (2σ, MSWD = 1.5) on monazite. These ages are ~70 m.y. younger than magmatic zircons in the host dolerite and are similar to the aforementioned U-Th/He cooling ages on detrital zircons from hydrothermally mineralized sedimentary host rocks. We, therefore, conclude that the Badu Carlin-type gold deposit formed at ca. 144 Ma. The agreement of the rutile and monazite ages with the U-Th-He cooling ages of Badu and four other Carlin-type gold deposits in the Youjiang basin suggests that ca. 144 Ma is representative of a regional Early Cretaceous Carlin-type hydrothermal event formed during back-arc extension.

scholarly journals Fluid inclusion study of shear zone hosted lode gold type deposits: El Bagre mining district, Antioquia-Colombia

2020 ◽  
Vol 24 (3) ◽  
pp. 245-257
Author(s):  
Edwin Naranjo Sierra ◽  
Mauricio Alvaran Echeverri
Keyword(s):  
Fluid Inclusion ◽  
Shear Zone ◽  
Gold Deposits ◽  
Fluid Inclusion Study ◽  
Mining District ◽  
Type I ◽  
Lode Gold ◽  
Calcite Veins ◽  
Inclusion Study ◽  
Homogenization Temperatures

The shear zone hosted lode gold type deposits are located at the northeast part of Antioquia department of Colombia. The characteristics of ore-forming fluids were discussed using fluid inclusion petrography and microthermometry analysis. Two stages, namely quartz-pyrite pre-mineralization stage (1) and reactivation-sulfides-tellurides mineralization stage (2) were included in this study. Two types of fluid inclusions were observed: primary aqueous-carbonic inclusions (type I) are characterized by the presence of clathrate, with salinities between 1.5 and 8.3 %wt NaCl equiv. and homogenization temperatures (to liquid) occurs between 238.1° and 297.1°C. Secondary aqueous inclusions (type II) were trapped in reactivated quartz (type IIa) and cross-cutting calcite veins (type IIb), salinity estimates display a mixing trend from a relatively saline with 9.21 %wt NaCl member (type IIa) to a low salinity one with 3.82 %wt NaCl (type IIb), homogenizations to a liquid phase occur between 150.8° and 184.6°C for type IIa inclusions and 130.3° to 190.4°C for type IIb. Based on these results, the shear zone hosted lode gold type deposits from El Bagre mining district, share similar characteristics with orogenic gold deposits.

40Ar/39Ar age constraints on the thermal history of the Archean Abitibi greenstone belt and the Pontiac Subprovince: implications for terrane collision, differential uplift, and overprinting of gold deposits

1992 ◽  
Vol 29 (7) ◽  
pp. 1389-1411 ◽  
Author(s):  
R. Feng ◽  
R. Kerrich ◽  
S. McBride ◽  
E. Farrar
Keyword(s):  
High Temperature ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Coarse Grained ◽  
Metamorphic Rocks ◽  
Low Grade ◽  
Thermal Activity ◽  
Thermal Event ◽  
Southern Volcanic Zone ◽  
Differential Uplift

40Ar/39Ar mineral age spectra of granitic and metamorphic rocks, in conjunction with existing conventional zircon geochronology, indicate that at least two major late Archean thermal events affected tectonic blocks of the Abitibi Southern Volcanic Zone (SVZ) and the juxtaposed Pontiac Subprovince. The earlier thermal activity (2690–2670 Ma) was accompanied by the intrusion of voluminous syntectonic plutons and caused low-pressure, greenschist-facies metamorphism in the SVZ and intermediate-pressure metamorphism in the Pontiac Subprovince. The second thermal event (2660–2630 Ma) was coeval with the emplacement of syncollisional, S-type garnet–muscovite granites in the Pontiac Subprovince and the higher grade Lacorne block of the Abitibi SVZ, and reset the K–Ar systems in preexisting rocks.Magmatic amphibole from the syntectonic Round Lake batholith (~2695 Ma U–Pb zircon age) of the Abitibi SVZ has a slightly disturbed Ar release spectrum with an upper plateau age of 2669 ± 6 Ma, signifying that the low-grade Round Lake block cooled through 500 °C at a slow rate. Amphiboles in syntectonic batholiths from the higher grade Lacorne block and the Pontiac Subprovince have substantially disturbed Ar release spectra, with high-temperature steps giving apparent ages of 2681 ± 4 to 2679 ± 4 Ma; these overlap zircon ages of 2690–2670 Ma, indicating relatively rapid cooling through the amphibole blocking temperature.Metamorphic rocks (amphibolites) from the Lacorne block and the Pontiac Subprovince contain amphiboles with substantially disturbed 40Ar/39Ar release spectra and higher temperature step ages of 2677 ± 6 to 2670 ± 5 Ma, representing the minimum formation age. Fine-grained muscovite and biotite (180–250 μm) from mica schists also have disturbed Ar release patterns, but much younger apparent ages at high-temperature release steps (2581–2523 Ma for muscovite, 2562–2455 Ma for biotite) than the amphiboles.Coarse-grained muscovites from pegmatites associated with syncollision, S-type garnet–muscovite granites (2644 ± 13 Ma) in the Lacorne block and Pontiac Subprpvince show undisturbed or slightly disturbed Ar release spectra and magmatic δ18Oquartz–muscovite = 1.8–3.5‰, with total integrated ages of 2615 ± 10 to 2594 ± 7 Ma (Lacorne) and 2572 ± 6 Ma (Pontiac), respectively, indicating different uplift rates for the two terranes. Amphiboles (~2680 Ma) from metamorphic rocks in the Lacorne block and Pontiac Subprovince and from the Round Lake batholith are disturbed, whereas coarse-grained muscovites from the pegmatites (2644 ± 13 Ma) are relatively undisturbed. This indicates that the disturbance of the amphiboles may have been caused by a thermal event that preceded or was coeval with the emplacement of the garnet–muscovite granite suite, rather than being a grain-size effect.These results are consistent with a model whereby early subduction of oceanic lithosphere beneath the Abitibi SVZ (2740–2680 Ma), and separately under the Pontiac Subprovince, was responsible for syntectonic batholiths and the first thermal event. Collision with the Abitibi SVZ and local underthrusting of the Pontiac Subprovince at about 2670–2630 Ma caused the second major thermal event and partial melting of the underthrust Pontiac-type metasediments to form the garnet–muscovite granites. Later differential uplift exposed the entire Pontiac Subprovince and the Lacorne block as a tectonic window of underthrust Pontiac in the Abitibi SVZ. Resetting of several isotopic systems, including apparent younger ages of gold mineralization, is probably related to this late collisional, tectonothermal overprinting event. Fluid and (or) thermal events at ≥275 °C influenced the Kirkland Lake – Cadillac fault down to 2513 ± 10 Ma, as indicated by a plateau age of postkinematic biotite in the fault. The fault was intermittently reactivated over a period of 440 Ma, from ~2690 Ma to ≤2250 Ma.

sPhysicochemical conditions of fluid–wall rock interaction at amphibolite-facies conditions in two Archean hydrothermal gold deposits in the Mt. York District, Pilbara Craton, Western Australia

1995 ◽  
Vol 32 (7) ◽  
pp. 993-1016 ◽  
Author(s):  
P. Neumayr ◽  
J.R. Ridley ◽  
D.I. Groves
Keyword(s):  
Western Australia ◽  
Gold Mineralization ◽  
Wall Rock ◽  
Gold Deposits ◽  
Iron Formation ◽  
Banded Iron Formation ◽  
Rock Interaction ◽  
Wall Rock Alteration ◽  
Geochemical Analyses ◽  
Pilbara Craton

Synamphibolite facies Archean gold mineralization in the Mt. York District, Pilbara Craton, Western Australia, is hosted in metamorphosed banded iron formation (Main Hill–Breccia Hill prospect), amphibolites, and ultramafic schists (Zakanaka prospect). Mineralization at Main Hill occurs in quartz breccias with sulfide matrices and in altered wall rock adjacent to quartz–biotite–amphibole ± clinopyroxene veins. Alteration associated with quartz veins is zoned, with biotite—pyrrhotite vein selvedges and a distal calcic-amphibole, arsenopyrite–lôllingite zone. Hydrothermal biotite and actinolite have highest Mg/(Mg + Fe) ratios where associated with abundant sulfarsenides in the distal alteratin zone. Whole-rock geochemical analyses and calculated metasomatic reactions indicate the addition of K, Al, S, As, Au, Ag, and Ni during hydrothermal alteration. Mineralization at Zakanaka is characterized by a broad wall rock alteration halo of biotite–amphibole, and zoned quartz–calc silicate veins proximal to ore. Wall rock adjacent to the veins contains pyrrhotite, pyrite, and gold. The alteration is explained by K-metasomatism distal to mineralization and K and Ca metasomatism proximal to mineralization. Balanced metasomatic reactions and mass-balance calculations indicate addition of K and depletion of Na, Ca, Mg, and Fe in distal alteration zones and addition of K, Ca, Mg, Fe, and Ti in proximal zones. Gold precipitation at both prospects occurred through loss of S, and possibly As, from the ore fluid during sulfidation reactions with Fe-rich amphiboles and biotites to form Mg-enriched equivalents and sulfarsenides. Changes in the oxidation state of the ore fluid may have enhanced gold precipitation, though pH changes are unlikely to have been important. The controls on mineralization are thus similar to those at many lower temperature, mesothermal deposits. The lack of consistently increasing Mg ratios of calc-silicate phases with increasing intensity of alteration and sulfidation at Main Hill may be the result of coupled substitutions in amphiboles and biotites during infiltration of a fluid with high-S, but low-As, activities.

Stable-isotope, fluid-inclusion, and mineralogical studies relating to the genesis of amethyst, Thunder Bay Amethyst Mine, Ontario

1993 ◽  
Vol 30 (9) ◽  
pp. 1955-1969 ◽  
Author(s):  
J. R. McArthur ◽  
E. A. Jennings ◽  
S. A. Kissin ◽  
R. L. Sherlock
Keyword(s):  
Fluid Inclusion ◽  
Meteoric Water ◽  
Stable Condition ◽  
Hydrothermal Solution ◽  
Wall Rock ◽  
Near Surface ◽  
Vein System ◽  
Thunder Bay ◽  
Quartz Monzonite ◽  
Homogenization Temperatures

The Thunder Bay Amethyst Mine exploits a vein system in which the main zoned sequence consists of chalcedony, colorless quartz, and three to four stages of amethyst. The main sequence surrounds fragments of a brecciated earlier sequence containing chalcedony, colorless quartz, and prasiolite, which appears to be thermally bleached amethyst. The vein system occupies a fault in Archean granodiorite and is associated with a narrow zone of chloritic and hematite alteration overprinted by weak argillic alteration. Fragments of Proterozoic (1339 Ma) Sibley Group rocks occur in the vein system, indicating the former presence of a shallow cover during deposition of quartz and limiting the maximum age of the deposit. These downfallen fragments and the abundance of vugs indicate near-surface formation of the deposit.Main-stage fluid-inclusion homogenization temperatures are in the range from 91.2 to 40.9 °C (mean 68.4 °C) in amethyst, whereas in colorless quartz homogenization temperatures range from 146.5 to 114.7 °C (mean 132.1 °C). Eutectic temperatures fall in three ranges with means of −50.9, −48.7, and −43.9 °C, which are related to paragenetic position and indicate an NaCl–CaCl2–H2O system, with possible additional components in later inclusions. Salinities in amethyst-hosted inclusions decrease in the growth direction from 22.9 to 15.3 equiv.wt% NaCl.Trace sulfide and other mineral inclusions indicate a trend of decreasing Eh and pH from an initially rather oxidized (sulfate stable) to a reduced (sulfide stable) condition during deposition. Sulfur isotopic composition in pyrite and chalcopyrite ranges from δ34S = −0.4 to −1.4‰ and is similar to values obtained from lead–zinc–barite in other vein deposits surrounding the Sibley depositional basin. Oxygen isotopes in quartz range from δ18O = +12.7 to +17.1‰, corresponding to δ18O(H2O) = −2.1 to −12.8‰ using fluid-inclusion temperatures. Fresh quartz monzonite wall rock (δ18O = +11.82‰) and altered quartz monzonite (δ18O = +11.01‰) do not seem to have undergone significant isotopic exchange with the hydrothermal solution, and the trend of isotopic change does not account for the trend of δ18O(H2O) determined in quartz. Rather, mixing of local meteoric water with a basinal brine appears to explain the observed trend.The amethyst deposits are believed to have been formed by basinal brines expelled from Sibley Group sediments. The brines dissolved silica by alteration processes accompanying their passage through granitic basement rocks in basin marginal faults. Amethyst was deposited on mixing with meteoric water. The temperature interval for amethyst formation appears to be restricted to less than ~90 °C. Temperatures causing thermal bleaching of amethyst are as low as 145 °C, and possibly 115 °C, as indicated by these results. This low range of temperature is not in agreement with bench-type experiments indicating bleaching at hundreds of degrees Celsius.

scholarly journals Epithermal Mineralization in the Busang Southeast Zone, Indonesia: New Insight into the Au Prospect at the Center of the Bre-X Fraud

Minerals ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 698
Author(s):  
Evan Slater ◽  
Jacob Hanley ◽  
Thomas Mulja ◽  
Marcos Zentilli ◽  
Corwin Trottier
Keyword(s):  
Fluid Inclusion ◽  
Aqueous Fluid ◽  
Gold Deposits ◽  
Professor Emeritus ◽  
Mixing Processes ◽  
Hydrothermal Mineralization ◽  
Core Samples ◽  
Epithermal Mineralization ◽  
Lode Gold Deposits ◽  
Host Rocks

The Busang mineral prospect in Kalimantan, Indonesia, was reported to host a large Au resource until 1997 when it was revealed that drill core samples had been deliberately and systematically contaminated (“salted”) with extraneous Au to falsify resource estimates. One month before the fraud was uncovered, Dr. G. Milligan, then professor emeritus of geology, visited the site to collect a suite of core samples for academic study that was deemed representative of the host rocks, alteration, and mineralization of the Busang Southeast Zone. These samples were re-examined here by optical microscopy, electron microprobe (EMPA), whole-rock geochemistry, and fluid inclusion microthermometry to characterize the subsurface geology and hydrothermal mineralization, and to assess reasons why the system is of uneconomic character. The host rocks were variably altered calc-alkaline porphyritic subvolcanic diorites, typical of the lithological units along the mineralized trend in the Kalimantan Gold Belt. Early hydrothermal mineralization with quartz-sulfide (pyrite, chalcopyrite, Cu-sulfosalts) stockwork veinlets associated with pervasive phyllic and propylitic alteration was overprinted by crudely banded quartz-carbonate-sulfide/sulfosalt (pyrite, sphalerite, chalcopyrite, galena, tennantite-tetrahedrite, bournonite-seligmannite) veins. The stockwork veins were associated with up to 140 ppb bulk rock Au, some of which was hosted by Cu-sulfosalts. Microthermometry on quartz-hosted aqueous fluid inclusion assemblages (FIA; n = 13) and single inclusions (non-FIA; n = 20) in quartz-carbonate-sulfide/sulfosalt veins yielded an overall range in homogenization temperatures (Th) between 179 °C and 366 °C and bulk salinities between 1.1 wt.% to 8.6 wt.% NaCl equivalent, with much smaller data ranges for individual FIA (e.g., FIA 3; 239.1 °C to 240.5 °C and 0.5 wt.% to 1.4 wt.% NaCl equivalent). Primary FIA along growth zones in quartz were identified, providing constraints on fluid characteristics at the time of quartz growth. Carbonate-hosted FIA (n = 3) and single inclusions (non-FIA; n = 3) in the same veins yielded Th between 254 °C and 343 °C and bulk salinities of 1.1 wt.% to 11.6 wt.% NaCl equivalent. Likewise, data ranges for individual FIA were much smaller. Many of the geological characteristics of the Busang Southeast Zone were compatible with a telescoped, intermediate-sulfidation epithermal system, having formed from diluted magmatic fluids that precipitated weak base metal mineralization. However, the system was unproductive with respect to Au and Ag, at least within the studied area. Of note, vein textures and fluid inclusion characteristics indicative of boiling or efficient fluid mixing—processes both considered critical for the formation of economic lode gold deposits—were absent in the samples.

Chapter 13: Boddington: An Enigmatic Giant Archean Gold-Copper (Molybdenum-Silver) Deposit in the Southwest Yilgarn Craton, Western Australia

2020 ◽  
pp. 275-288
Author(s):  
Stephen J. Turner ◽  
Graeme Reynolds ◽  
Steffen G. Hagemann
Keyword(s):  
Western Australia ◽  
Melt Inclusion ◽  
Gold Mineralization ◽  
Extended Period ◽  
Granite Gneiss ◽  
Shear Zones ◽  
Gold Deposits ◽  
Yilgarn Craton ◽  
Local Evidence ◽  
Host Rocks

Abstract Boddington is a giant, enigmatic, and atypical Archean Au-Cu deposit hosted in a small, remnant greenstone belt within granite-gneiss and migmatite of the Southwest terrane of the Yilgarn craton, Western Australia. Primary Au and Cu (and Mo) mineralization consists of a network of thin fractures and veins, controlled by shear zones, and dominantly hosted by early dioritic intrusions and their immediate wall rocks, which comprise felsic to intermediate-composition volcanic and volcaniclastic rocks. The pre-~2714 Ma host rocks are typically steeply dipping and strongly deformed, with early ductile and overprinting brittle-ductile fabrics, and have been metamorphosed at mid- to upper greenschist facies. Features consistent with porphyry-style mineralization, classic orogenic shear zones, and intrusion-related Au-Cu-Bi mineralization are all recognized, giving rise to a variety of genetic interpretations. It is clear that Boddington does not fit any classic Archean orogenic gold deposit model, having a general lack of quartz veins and iron carbonate alteration, a Cu (Mo and Bi) association, zoned geochemical anomalism, and evidence of high-temperature, saline ore-forming fluids. Detailed petrographic, geochemical, and melt inclusion studies suggest a late-stage ~2612 Ma, monzogranite intrusion as one of the principal sources of the mineralizing fluids. However, there is also local evidence for older, perhaps protore, porphyry-style Cu (±Au) in the dioritic intrusions and patchy, locally high-grade, orogenic-style gold mineralization associated with enclosing shear zones and brittle-style deformation, which was focused on the relatively competent dioritic intrusions. The relative contributions of metals from these components to the system may not be resolvable. It appears that the Boddington deposit has been a locus for multiple episodes of intrusion, alteration, and mineralization over an extended period of time, as has been demonstrated in a number of other large Canadian and Australian gold deposits, including the Golden Mile near Kalgoorlie.

Chapter 9: Orogenic Gold Deposits of the Kibali District, Neoarchean Moto Belt, Northeastern Democratic Republic of Congo

2020 ◽  
pp. 185-201
Author(s):  
Andrew Allibone ◽  
Carlos Vargas ◽  
Etienne Mwandale ◽  
Justus Kwibisa ◽  
Richard Jongens ◽  
...  
Keyword(s):  
Democratic Republic ◽  
Gold Mineralization ◽  
Democratic Republic Of Congo ◽  
Shear Zones ◽  
Gold Deposits ◽  
Iron Formation ◽  
Banded Iron Formation ◽  
Republic Of Congo ◽  
Lithostratigraphic Units ◽  
Host Rocks

Abstract The Kibali district in the Democratic Republic of Congo hosts the large Karagba-Chaffeur-Durba (KCD) deposit and smaller satellite deposits that together contained 20 million ounces (Moz) of gold when mining recommenced in 2013. An additional 3 Moz of gold was probably mined from the district before 2013. Gold deposits in the Kibali district are located along the KZ trend, a series of folds, contractional shear zones, and altered lithostratigraphic units that coincide with the margin of an earlier 2630 to 2625 Ma intraorogenic basin within the Neoarchean Moto belt. Fluids first responsible for barren carbonate-quartz-sericite alteration, and later for siderite and/or ankerite (±quartz, magnetite, pyrite, and/or chlorite) alteration with associated auriferous pyrite ± rare arsenopyrite veinlets, infiltrated and replaced the siliciclastic, banded iron formation (BIF), and chert host rocks via fold axes, shear zones, and reactive BIF horizons. The complex shape and gentle northeast plunge of the lodes across the Kibali district reflect the shape and plunge of coincident folds that formed during early barren alteration. Many other folded BIF horizons across the wider Moto belt remain barren or only weakly mineralized, suggesting deep extensional structures that may have developed in the vicinity of the KZ trend during basin opening and prior to gold mineralization, were important fluid pathways during later contractional deformation and mineralization.

scholarly journals The Perron Gold Deposit, Archean Abitibi Belt, Canada: Exceptionally High-Grade Mineralization Related to Higher Gold-Carrying Capacity of Hydrocarbon-Rich Fluids

Minerals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1066
Author(s):  
Damien Gaboury ◽  
Dominique Genna ◽  
Jacques Trottier ◽  
Maxime Bouchard ◽  
Jérôme Augustin ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Trace Element ◽  
Gold Deposit ◽  
Gold Mineralization ◽  
Gold Deposits ◽  
Orogenic Gold ◽  
Magmatic Fluid ◽  
High Grade ◽  
Host Rocks ◽  
Mineralizing Fluids

The Perron deposit, an Archean orogenic gold deposit located in the Abitibi belt, hosts a quartz vein-type gold-bearing zone, known as the high-grade zone (HGZ). The HGZ is vertically continuous along >1.2 km, and is exceptionally rich in visible gold throughout its vertical extent, with grades ranging from 30 to 500 ppm. Various hypotheses were tested to account for that, such as: (1) efficient precipitating mechanisms; (2) gold remobilization; (3) particular fluids; (4) specific gold sources for saturating the fluids; and (5) a different mineralizing temperature. Host rocks recorded peak metamorphism at ~600 °C based on an amphibole geothermometer. Visible gold is associated with sphalerite (<5%) which precipitated at 370 °C, based on the sphalerite GGIMFis geothermometer, during late exhumation of verticalized host rocks. Pyrite chemistry analyzed by LA-ICP-MS (Laser Ablation Inductively Coupled Plasma Mass Spectrometry) is comparable to classical orogenic gold deposits of the Abitibi belt, without indication of a possible magmatic fluid and gold contribution. Comparison of pyrite trace element signatures for identifying a potential gold source was inconclusive to demonstrate that primary base-metal rich volcanogenic gold mineralization, dispersed in the host rhyolitic dome, could be the source for the later formation of the HGZ. Rather, nodular pyrites in graphitic shales, sharing similar trace element signatures with pyrite of the HGZ, are considered a potential source. The most striking outcome is the lack of water in the mineralizing fluids, implying that gold was not transported under aqueous complexes, even if fugacity of sulfur (−6) and oxygen (−28), and pH (~7) are providing the best conditions at a temperature of 350 °C for solubilizing gold in water. Fluid inclusions, analyzed by solid-probe mass spectrometry, are rather comparable to fossil gas composed mostly of hydrocarbons (methane and ethane and possibly butane and propane and other unidentified organic compounds), rich in CO2, with N2 and trace of Ar, H2S, and He. It is interpreted that gold and zinc were transported as hydrocarbon-metal complexes or as colloidal gold nanoparticles. The exceptional high content of gold and zinc in the HGZ is thus explained by the higher transporting capacity of these unique mineralizing fluids.

Sign in / Sign up

Export Citation Format

Share Document