A Silurian U–Pb age for the Cape St. Mary's sills, Avalon Peninsula, Newfoundland, Canada: implications for Silurian orogenesis in the Avalon Zone

1993 ◽  
Vol 30 (8) ◽  
pp. 1607-1612 ◽  
Author(s):  
John D. Greenough ◽  
Sandra L. Kamo ◽  
Thomas E. Krogh

Mafic sills from Cape St. Mary's on the Avalon Peninsula of Newfoundland give an U–Pb baddeleyite age of 441 ± 2 Ma. This age corresponds with the earliest ages recorded for the climactic Silurian orogenic event that dominantly affected rocks of the Central Mobile Belt in Newfoundland. The age is consistent with but in no way necessitates that the Avalon and Gander zones were juxtaposed during the Silurian. Because sills tend to form in poorly lithified and undeformed sedimentary rocks, it is unlikely that Cambrian sediments hosting the sills were affected by Ordovician orogenic events that strongly affected central Newfoundland. Negative Nb and Ti anomalies on mid-ocean-ridge basalt normalized diagrams show that the sill geochemistry is consistent with formation in a transpressional tectonic environment. Mafic magmas clearly associated with the Silurian event share these chemical and tectonic affinities. Thus both the age and geochemical data are consistent with but do not require a link between the Gander and Avalon zones during the Silurian. If the two zones were joined prior to the Silurian then the Avalon must have been distal to both the Ordovician and Silurian orogenic activity. Further, considerable post-Silurian movement would have had to occur along the bounding Hermitage–Dover fault to account for contrasts in the intensity of metamorphism, plutonism, and deformation between the Gander and Avalon zones.

Geofluids ◽  
2018 ◽  
Vol 2018 ◽  
pp. 1-20 ◽  
Author(s):  
Samuel Pierre ◽  
Alexander P. Gysi ◽  
Thomas Monecke

Seawater-basalt interaction taking place at mid-ocean ridges was studied using numerical modeling to determine the compositional evolution of hydrothermal fluids and associated alteration mineralogy forming within newly emplaced crustal material. Geochemical modeling was carried out in a closed seawater-basalt system at discrete temperature intervals between 2 and 400°C at 500 bars, varying fluid/rock ratios, and secondary mineral assemblages representative of basalt alteration in natural systems. In addition to temperature, the fluid/rock ratio has a fundamental control on the resulting system chemistry. At rock-buffered conditions (low fluid/rock ratios), the mineral-solution equilibrium was characterized by high cation to proton activity ratios foraCa2+/(aH+)2andaNa+/aH+and very low dissolved Mg concentrations due to the precipitation of smectites and chlorite. A complex secondary mineral alteration assemblage dominated by Ca- and Na-bearing minerals including zeolites, calcite, epidote, prehnite, clinozoisite, and albite was predicted to form. The resulting fluid composition was alkaline and reduced relative to ambient seawater, with Eh values ranging between −0.2 and −0.6 V. In contrast, seawater-buffered conditions (high fluid/rock ratios) resulted in lower cation to proton activity ratios foraCa2+/(aH+)2andaNa+/aH+and higher dissolved Mg concentrations comparable to the value of this element in ambient seawater. A more simple mineral assemblage was predicted to form at these conditions with the predominance of Al-Si- and Mg-bearing minerals including kaolinite, quartz, and talc in addition to large amounts of anhydrite. The resulting fluid composition was mildly acidic and oxidized relative to seawater with Eh values ranging between −0.2 and 0 V. These modeling results were compared to a compilation of submarine hydrothermal vent fluid compositions from mid-ocean ridge settings and analogous basalt-dominated environments. The agreement obtained between the simulations and the compiled fluid data indicates that mid-ocean ridge hydrothermal processes can be closely reproduced by mineral-solution equilibria for a broad range of temperatures and fluid/rock ratios.


2009 ◽  
Vol 180 (2-4) ◽  
pp. 171-188 ◽  
Author(s):  
David A. Clague ◽  
Jennifer B. Paduan ◽  
Alice S. Davis

Nature ◽  
1990 ◽  
Vol 343 (6257) ◽  
pp. 450-452 ◽  
Author(s):  
David E. Fisher ◽  
Michael R. Perfit

Nature ◽  
2002 ◽  
Vol 418 (6893) ◽  
pp. 68-72 ◽  
Author(s):  
Vincent J. M. Salters ◽  
Henry J. B. Dick

1988 ◽  
Vol 96 (2) ◽  
pp. 237-244 ◽  
Author(s):  
Robert J. Rosenbauer ◽  
James L. Bischoff ◽  
Robert A. Zierenberg

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