Pétrographie et minéralogie des halos d'altération autour du gisement de Cigar Lake et leurs relations avec les minéralisations

1993 ◽  
Vol 30 (4) ◽  
pp. 674-688 ◽  
Author(s):  
A. Pacquet ◽  
F. Weber

Around the Cigar Lake orebody, the present zoneography of alteration halos reflects several alteration episodes, some of which are anterior to and others coeval with the mineralizing events and have a regional extension. The basement retromorphism is characterized by crystallization of muscovite with a low iron and magnesium content and of trioctahedral ferromagnesian chlorites. The later regolith alteration, more obvious at the top of the basement, is marked by iron-bearing 1T kaolinite, by hematite, and by local crandallite–florencite and diaspore. In the Athabasca sandstones far from any mineralization, the diagenetic quartzification was followed by crystallization of aluminous 2M hydromuscovite, dickite, and crandallite–goyazite.In the main pod, the uraninite mineralization was dated 1341 ± 12 Ma. In the sandstones, it is surrounded by ferromagnesian chlorites with a variable sudoitic character. This proximal alteration halo grades into a more distal envelope, visible in the sandstone and in the basement, that is composed of magnesian sudoite and 3T hydromuscovite. During this mineralizing event, dravite crystallized in the form of urchin-like clusters in the basement and xenotime overgrowths, around altered zircon, and apatite formed in the sandstones.Around the main pod and in some perched orebodies, an alteration zone of vanadium-bearing ferrikaolinite and iron-bearing 3T hydromuscovite, crosscut by a later siderite, surrounds the pitchblende dated 323 ± 4 Ma. Coffinite and an aluminous hydromuscovite crystallized during a later fracture event. The aluminous hydromuscovite also appears, with a silica–carbon–uranium complex, in perched mineralizations. Kaolinization and iron-sulfide oxidation into iron hydroxides occurred in perched orebodies that were more exposed to meteoric alteration.

2003 ◽  
Vol 32 (3) ◽  
pp. 773-780 ◽  
Author(s):  
L. R. Hossner ◽  
J. J. Doolittle

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Huan Yang ◽  
Lanqian Gong ◽  
Hongming Wang ◽  
Chungli Dong ◽  
Junlei Wang ◽  
...  

Abstract Nickel–iron composites are efficient in catalyzing oxygen evolution. Here, we develop a microorganism corrosion approach to construct nickel–iron hydroxides. The anaerobic sulfate-reducing bacteria, using sulfate as the electron acceptor, play a significant role in the formation of iron sulfide decorated nickel–iron hydroxides, which exhibit excellent electrocatalytic performance for oxygen evolution. Experimental and theoretical investigations suggest that the synergistic effect between oxyhydroxides and sulfide species accounts for the high activity. This microorganism corrosion strategy not only provides efficient candidate electrocatalysts but also bridges traditional corrosion engineering and emerging electrochemical energy technologies.


1988 ◽  
Vol 11 (3) ◽  
pp. 289-295 ◽  
Author(s):  
Patrick J. Sullivan ◽  
Jennifer L. Yelton ◽  
K. J. Reddy

Pyrite ◽  
2015 ◽  
Author(s):  
David Rickard

The two basic processes concerning pyrite in the environment are the formation of pyrite, which usually involves reduction of sulfate to sulfide, and the destruction of pyrite, which usually involves oxidation of sulfide to sulfate. On an ideal planet these two processes might be exactly balanced. But pyrite is buried in sediments sometimes for hundreds of millions of years, and the sulfur in this buried pyrite is removed from the system, so the balance is disturbed. The lack of balance between sulfide oxidation and sulfate reduction powers a global dynamic cycle for sulfur. This would be complex enough if this were the whole story. However, as we have seen, both the reduction and oxidation arms of the global cycle are essentially biological—specifically microbiological—processes. This means that there is an intrinsic link between the sulfur cycle and life on Earth. In this chapter, we examine the central role that pyrite plays, and has played, in determining the surface environment of the planet. In doing so we reveal how pyrite, the humble iron sulfide mineral, is a key component of maintaining and developing life on Earth. In Chapter 4 we concluded that Mother Nature must be particularly fond of pyrite framboids: a thousand billion of these microscopic raspberry-like spheres are formed in sediments every second. If we translate this into sulfur production, some 60 million tons of sulfur is buried as pyrite in sediments each year. But this is only a fraction of the total amount of sulfide produced every year by sulfate-reducing bacteria. In 1982 the Danish geomicrobiologist Bo Barker Jørgensen discovered that as much as 90% of the sulfide produced by sulfate-reducing bacteria was rapidly reoxidized by sulfur-oxidizing microorganisms. Sulfate-reducing microorganisms actually produce about 300 million tons of sulfur each year, but about 240 million tons is reoxidized. The magnitude of the sulfide production by sulfate-reducing bacte­ria can be appreciated by comparison with the sulfur produced by volcanoes. As discussed in Chapter 5, it was previously supposed that all sulfur, and thus pyrite, had a volcanic origin. In fact volcanoes produce just 10 million tons of sulfur each year.


1979 ◽  
Vol 16 (3) ◽  
pp. 575-584 ◽  
Author(s):  
Joseph J. Donovan ◽  
Ginette Lajoie

It has been proposed that iron hydroxides act as cementing agents in Champlain Sea clays, causing brittle behaviour and high sensitivities. Study of interbedded turbiditic sandy and clayey strata of the Champlain Sea disputes this contention. Ground waters flowing through these sandy interbeds have high pH and are sodium bicarbonate dominant and strongly reduced, with a calculated Eh of −276 to −343 mV, using the sulfate–sulfide redox couple. During movement from recharge to discharge, sulfate is reduced by bacterial decomposition of organic matter in the clays, producing high sulfide and bicarbonate activities. In terms of Eh and pH, these waters fall within the stability fields of Fe2+ and FeS2.No pyrite was detected in the sediments, but in borehole samples and very fresh exposures of both clay and sand lithologies a very finely-disseminated black mineral phase, interpreted as iron monosulfides, was observed which is highly unstable in an aerobic environment, oxidizing rapidly to red-brown ferric hydroxide. The presence of these monosulfides, along with the aqueous geochemical data, indicate strongly reducing conditions in the clay strata, in which iron hydroxides are not a stable phase. Ferric hydroxides can therefore not be called upon as cementing agents; past studies which identified these ferric compounds as such cementing agents based their conclusions on samples out of equilibrium with their natural environment and are not directly relevant to the behaviour of the clay under natural conditions. The effects of these iron monosulfides and associated organic material on clay behaviour have not yet been studied.


2014 ◽  
Vol 20 (4) ◽  
pp. 419-435 ◽  
Author(s):  
Sarka Vaclavkova ◽  
Christian Juncher Jørgensen ◽  
Ole Stig Jacobsen ◽  
Jens Aamand ◽  
Bo Elberling

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