Massive sulfide deposits of the Noranda area, Quebec. II. The Aldermac mine

1991 ◽  
Vol 28 (9) ◽  
pp. 1301-1327 ◽  
Author(s):  
T. J. Barrett ◽  
S. Cattalani ◽  
F. Chartrand ◽  
P. Jones

The original Aldermac mine near Noranda contained several Cu–Zn massive sulfide lenses hosted by felsic to mafic volcanic rocks of the late Archean Blake River Group. The original Nos. 3–6 orebodies, which consisted of massive pyrite, with lesser magnetite, pyrrhotite, chalcopyrite, and sphalerite, contained 1.87 Mt of Cu–Zn ore that averaged 1.47% Cu (Zn was not recovered). The orebodies occurred within felsic breccias and tuffs up to 100 m thick that are stratigraphically overlain by an extensive dome of mainly massive rhyolite and rhyodacite (up to 250 m thick and at least 550 m across). Most of the volcanic rocks that laterally flank and overlie the felsic dome are dacitic to andesitic flows, breccia, and tuff, with minor rhyolites, and associated subvolcanic sills of quartz-feldspar porphyry and gabbro.The new massive sulfide deposit, discovered in 1988, lies 150–200 m east of the mined-out orebodies, at a similar stratigraphic level within altered felsic breccia and tuff. The sulfides are mainly in the No. 8 lens, which contains 1.0 Mt at an average grade of 1.54% Cu, 4.12% Zn, 31.2 g/t Ag, and 0.48 g/t Au. Pyrite forms porphyroblastic megacrysts in a groundmass of pyrrhotite, sphalerite, magnetite, and chalcopyrite. A funnel-shaped, chloritized stockwork zone underlies the No. 8 lens and contains Cu-stringer mineralization. The No. 8 lens appears to be zoned, with overall decreasing Cu:Zn ratios from the core to the fringes of the lens. Massive sulfides in this lens have high Ag, Cd, and Hg contents relative to other massive sulfide deposits near Noranda.Ti versus Zr trends for least-altered Aldermac volcanic rocks indicate a more or less continuous magmatic fractionation trend ranging from high-Ti andesite to andesite, dacite, rhyodacite, and two distinct rhyolites (A and B). Most volcanic rocks were derived from a common parental magma that was transitional between tholeiitic and calc-alkaline compositions, as indicated by Ti–Y–Zr–Nb data and rare-earth-element distributions.Ti versus Zr trends in altered volcanic rocks indicate that silicification (mass gain) has affected some of the andesitic to rhyodacitic rocks, whereas chloritization (mass loss) has affected many of the rhyolitic rocks. Intermediate to mafic volcanic rocks above and lateral to the felsic dome are commonly silicified, possibly the result of hydrothermally remobilized silica derived from underlying felsic volcanic rocks.The orebodies appear to have formed at an eruptive hiatus between mafic → felsic and felsic → mafic cycles, during explosive activity and accumulation of felsic breccia and tuff. Ore was deposited mainly within a felsic fragmental sequence (rhyolite A), but before emplacement of the dome of rhyolite B. In compositionally diverse volcanic terrains, the contact between successive mafic–felsic and felsic–mafic cycles may be a good exploration target, in particular specific geochemical contacts within the felsic stratigraphy.

1992 ◽  
Vol 29 (7) ◽  
pp. 1349-1374 ◽  
Author(s):  
T. J. Barrett ◽  
S. Cattalani ◽  
L. Hoy ◽  
J. Riopel ◽  
P.-J. Lafleur

The Mobrun polymetallic deposit near Rouyn–Noranda comprises two complexes of massive sulfide lenses within mainly felsic volcanic rocks of the Archean Blake River Group. The Main lens contained 3.37 Mt of massive sulfides, with 1989 reserves of 0.95 Mt at 0.81% Cu, 2.44% Zn, 30.3 g/t Ag, and 2.2 g/t Au. The 1100 complex, located ~250 m to the southeast of the Main complex, contains estimated 1989 reserves of 10.4 Mt at 0.76% Cu, 5.43% Zn, 37.4 g/t Ag, and 1.35 g/t Au.Host volcanic rocks of the Main complex are mostly massive, brecciated, and tuffaceous rhyolites. The rhyolites are commonly strongly sheared parallel to lithological contacts, which are locally displaced by high-angle faults. Immobile-element plots such as Y–Zr and Nb–Zr show a separation of rhyolite data into two distinct alteration trends that generally correspond to massive and in situ brecciated rhyolite of the footwall, and tuffaceous rhyolite of the hanging wall. The hanging wall has tholeiitic Zr/Y ratios (3–5), whereas the footwall has mildly calc-alkaline Zr/Y ratios (7–9). Several immobile-element trends indicate that there was a subtle but clear change in rhyolite composition near the time of ore deposition. Identification of chemically distinct footwall and hanging wall rhyolites allows these units to be recognized and traced along strike, even where alteration is strong. Sericitization and silicification extend at least 100 m from the orebody, with local chloritic zones in the upper footwall. Calculated mass changes indicate that the footwall generally has lost silica mass relative to the hanging wall. Alteration zones associated with mineralization have mass gains in FeO + MgO and K2O gains, but mass loss in silica.The 1100 complex, located stratigraphically below the Main complex, is hosted by rhyolite, with one main andesite interval in the footwall. The footwall contains three chemically distinct rhyolite types, all tholeiitic. Hanging-wall rhyolites are, however, mildly calc-alkaline, and thus are chemically comparable to, and correlated with, the footwall of the Main complex. Rhyolites within ~100 m stratigraphically of the Main and 1100 complexes commonly have positively shifted δ18O whole-rock values of 11–13‰. These high values are interpreted as the result of an initial, widespread phase of low-temperature hydrothermal alteration that increased δ18O values by 3–5‰ relative to unaltered rhyolites. Some footwall rhyolites, however, are relatively depleted in 18O, strongly depleted in Ca–Na and depleted in Eu2+. Rhyolites with these chemical features have been overprinted by higher temperature alteration, presumably in localized feeder zones. All four rhyolite types near the 1100 complex are chemically recognizable despite contrasting alteration.The orebodies are interpreted as synvolcanic, based on their occurrence along distinctive volcanic contacts, and the presence of primary sulfide textures where deformation is minor. The chemostratigraphic framework defined for the host rhyolite sequence can be used to trace critical volcanic contacts through lithologically monotonous, strongly altered, and faulted stratigraphy.


1991 ◽  
Vol 28 (11) ◽  
pp. 1699-1730 ◽  
Author(s):  
T. J. Barrett ◽  
W. H. MacLean ◽  
S. Cattalani ◽  
L. Hoy ◽  
G. Riverin

The Ansil massive sulfide deposit occurs at the contact of the underlying Northwest Rhyolite and the overlying Rusty Ridge Andesite, in the lower part of the Central Mine sequence of the Blake River Group. The orebody, which is roughly ellipsoidal in outline and up to 200 m × 150 m across, contained reserves of 1.58 Mt of massive sulfide grading 7.2% Cu, 0.9% Zn, 1.6 g/t Au, and 26.5 g/t Ag. Production began in 1989. Least-altered host rocks are low-K basaltic andesites and low-K rhyolites. These rocks have Zr/Y ratios of ~5 and LaN/YbN ratios of ~2.3, typical of tholeiitic volcanic rocks, although their major-element chemistry is transitional between tholeiitic and calc-alkaline volcanic rocks.The Ansil deposit, which dips ~50° east, is a single orebody comprising two main massive sulfide lenses (up to ~35 m thick) connected laterally via a thinner blanket of massive sulfides, with thin discontinuous but conformable massive magnetite units at the base and top of the orebody. Sulfide ore consists of massive to banded pyrrhotite–chalcopyrite. In the downplunge lens, up to 10 m of massive magnetite are capped by up to 10 m of massive sulfide. Finely banded cherty tuff, with sphalerite–pyrite–chalcopyrite, forms a discontinuous fringe to the deposit.The two main lenses of massive sulfide have the highest contents of Cu, Ag, and Au and are thought to have formed in areas of major hydrothermal input. Altered feeder zones contain either chlorite + chalcopyrite + pyrrhotite ± magnetite, or chlorite + magnetite ± sulfides. Footwall mineralization forms semiconformable zones ~5–10 m thick that directly underlie the orebody and high-angle pipelike zones that extend at least 50 m into the footwall. Ti–Zr–Al plots indicate that almost all altered footwall rocks were derived from a homogeneous rhyolite precursor. Hanging-wall andesites were also altered. Despite some severe alteration, all initial volcanic rock compositions can be readily identified, and thus mass changes can be calculated. Silica has been both significantly added or removed from the footwall, whereas K has been added except in feeder pipes. Oxygen-isotope compositions up to at least 50 m into the hanging wall and footwall are typically depleted in δ18O by 2–6‰. These rocks have gained Fe + Mg and lost Si. Altered samples in general range from light-rare-earth-element (REE) depleted to light-REE enriched, although some samples exhibit little REE modification despite strong alkali depletion. Mineralized volcanic rocks immediately below the orebody are enriched in Eu (as are some Cu-rich sulfides in the orebody).Contact and petrographic relations generally suggest that the main zone of massive magnetite formed by replacement of cp–po-rich sulfides, although local relations are ambiguous. Magnetite formation may reflect waning hydrothermal activity, during which fluids mixed with seawater and became cooler and more oxidized. Cu-rich feeder pipes that cut magnetite-rich footwall indicate a renewal of Cu-sulfide mineralization after magnetite deposition. Chloritic zones with disseminated sulfides occur up to a few hundred metres above the orebody, attesting to continuing hydrothermal activity.


2016 ◽  
Vol 53 (2) ◽  
pp. 176-188 ◽  
Author(s):  
Michael D. Hendrickson

The Oaks Belt (OB) is a Neoarchean volcanic complex located in northwestern Minnesota, USA. It is part of the Wabigoon granite–greenstone terrane that hosts the world-class Rainy River gold deposit in nearby Ontario, Canada. Rocks in the OB form a north-dipping homocline in the fault-bounded pressure shadow of a sigma-shaped volcano-plutonic wedge that spans east–west for 220 km across the Minnesota, USA – Ontario, Canada border. Exploration drilling in the area delineated pyrrhotite–pyrite massive sulfide deposits, iron formation, chert, and semi-massive sphalerite mineralized zones. High-resolution aeromagnetic data indicate a large (∼60 km2) composite subvolcanic intrusion underlies these iron-rich strata in the OB. The position of this inferred intrusion elucidates the low base metal content of known massive sulfide deposits, as they were too far away (6–10 km) from a heat source to have been favorable sites for base metal deposition. The relative abundance of Au and Zn in the OB, alongside correlation coefficients between metals in massive sulfide deposits, iron formation, and chert, indicates the rocks were affected by a low-temperature hydrothermal system under relatively shallow water conditions (<1000 m). Negative correlation between Na2O and CaO in basalt, and their mutual moderate positive correlation with immobile corundum (Al2O3), implies alteration in the upper part of the volcanic pile did not result in substantial element mobility in most samples. Geochemical data from mafic and felsic volcanic rocks plot mainly in the calc-alkaline field. Thus, the OB is most prospective for hosting Au-rich VMS deposits and future exploration should focus on paleo-thermal corridors and favorable stratigraphic horizons near the newly inferred composite subvolcanic intrusion.


LITOSFERA ◽  
2021 ◽  
Vol 21 (6) ◽  
pp. 775-804
Author(s):  
A. М. Kosarev ◽  
V. N. Puchkov ◽  
Igor B. Seravkin ◽  
Gulnara T. Shafigullina

Research subject. Volcanism, rock geochemistry, geodynamics, and massive sulfide formation in the Magnitogorsk megazone (MMZ) of the Southern Urals in the Middle Paleozoic.Materials and Methods. Across the largest part of the massive sulfide deposits under investigation, the authors conducted route studies, including geological surveys of individual ore fields and quarries of deposits, core samples of deep wells and transparent sections. Representative analyses of petrogenic and microelements were performed using wet chemistry and ICP-MS in analytical centers in Russia and Europe. Along with the authors’ data, analytical materials published by Russian and foreign researchers were used. Geodynamic reconstructions were carried out taking into account regional data on gravics, thermal field, magnetometry, and seismic stu dies, including «Urseis-95».Results. The geodynamic reconstructions established that the main elements of the paleostructure of the Southern Urals in the Devonian were the subduction zone of the eastern dip and asthenospheric diapirs that penetrated into the «slab-window», which determined the type of volcanic belts, the composition and volume of volcanic rocks of pyrite-bearing complexes, and ore matter of pyrite deposits. The following geodynamic zones in the MMZ were identified: 1 – polychronous accretion prism; 2 – frontal and developed island arcs (D1e2–D2ef1); 3 – zone of back-arc spreading (D1e2); 4 – rear island arc (D2ef1).Conclusions. All investigated zones and ore areas are characterized by an autonomous development of volcanism, a special deep structure and a different composition, as well as by a different volume of massive sulfide deposits that vary in the Cu and Zn ratios and Pb, Ba, Au amounts. In the MMZ volcanic complexes, three groups of plume source basalts are distinguished. The results can be used in predictive-estimation and search operations for massive sulfide mineralization.


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