The Long Rapids Formation: an Upper Devonian black shale in the Moose River Basin, northern Ontario

1990 ◽  
Vol 27 (2) ◽  
pp. 291-305 ◽  
Author(s):  
Ruth K. Bezys ◽  
Michael J. Risk
Keyword(s):  
River Basin ◽  
Black Shale ◽  
Weather Conditions ◽  
Black Shales ◽  
Late Devonian ◽  
Organic Carbon Content ◽  
Carbonate Facies ◽  
Overlying Water ◽  
Northern Ontario ◽  
Moose River

The Long Rapids Formation, a sequence of interbedded black shales, green–grey mudstones, and carbonates in the Moose River Basin of northern Ontario, is Late Devonian in age and has counterpart equivalents in the Michigan, Appalachian, and Illinois basins. The Long Rapids Formation has a maximum known thickness of 85 m and can be divided into three informal members. Based on conodont studies, the formation spans the Frasnian–Famennian age boundary.The Long Rapids Formation is an organic-rich, laminated, marine black-shale sequence interbedded with green–grey mudstones and concretionary carbonate interbeds and nodules. The environment of deposition was principally reducing, allowing for preservation of large amounts of organic matter both originating in the overlying water column and derived from terrestrial sources. The depositional basin was stratified, and anoxic bottom waters and oxic surface waters were separated by a pycnocline. The position of the pycnocline (or the absence of it) dictated the type of sediment facies deposited.The Moose River Basin in the Late Devonian was located on the Laurasian Continent, proximal to the equator, in an area where tropical weather conditions prevailed. Conditions were warm and wet along the Appalachian highlands, and farther inland they were warm and dry as a result of the rain-shadow effect. The black shales in the Long Rapids Formation represent a period of transgression of the large epicontinental Catskill Sea, and the green–grey mudstones and carbonates represent periods of minor eustatic or tectonic perturbations.Dark-coloured, organic-rich shale facies (sometimes with abundant bioturbation) are succeeded by lighter coloured shale or mudstone facies and carbonate facies in a repetitive fashion. The facies sequences appear to represent a three-part sedimentary package, or "rhythm", that is very common in the lower two members of the Long Rapids Formation. Bioturbation and total organic carbon content are less in the green–grey shales or mudstones, as well as in the carbonate facies, than in the darker shale facies.

Geochemistry of two Cretaceous coal-bearing sequences: James Bay lowlands, northern Ontario, and Peace River basin, northeast British Columbia

1987 ◽  
Vol 24 (5) ◽  
pp. 1038-1052 ◽  
Author(s):  
E. Van der Flier-Keller ◽  
W. S. Fyfe
Keyword(s):  
British Columbia ◽  
Trace Elements ◽  
River Basin ◽  
Pearson Correlation ◽  
Northern Ontario ◽  
Local Conditions ◽  
Modes Of Occurrence ◽  
Peace River ◽  
Element Contents ◽  
Moose River

Cretaceous coal-bearing sequences from the Moose River basin in northern Ontario and the Peace River basin in northeast British Columbia were analysed for trace- and major-element contents. Modes of occurrence of the trace elements are proposed on the basis of Pearson correlation coefficients and scanning electron microscopy coupled with energy-dispersive X-ray analysis.The Moose River basin lignite was deposited in an alluvial floodplain environment, and the restricted mineralogy, dominated by quartz and kaolinite, reflects derivation from a highly weathered terrain. The bituminous coal from the Peace River basin was deposited in an alluvial to deltaic environment, with a dominant mineralogy including quartz, illite, kaolinite, mixed-layer clays, carbonates, barite, feldspar, and pyrite.Trace-element contents in both deposits are comparable to the average concentration in United States coals. Modes of occurrence of trace elements in the coals are extremely variable and depend on local conditions both during deposition and subsequently. Association with the organic matter is the most common mode of occurrence of trace elements in the Moose River basin lignites, whereas clay minerals are important trace-element sites in the Peace River basin coal.Factors including coal rank, clay mineralogy, nature of the surrounding rocks, and composition of the groundwaters appear to have important influences on the concentrations of the trace elements and their siting in the coals.

scholarly journals A graptolite-rich Ordovician–Silurian boundary section in the south-central Pyrenees, Spain: stratigraphical and palaeobiogeographical significance

2018 ◽  
Vol 156 (06) ◽  
pp. 1069-1091 ◽  
Author(s):  
PETR ŠTORCH ◽  
JOSEP ROQUÉ BERNAL ◽  
JUAN CARLOS GUTIÉRREZ-MARCO
Keyword(s):  
Black Shale ◽  
Black Shales ◽  
High Rate ◽  
Organic Carbon Content ◽  
The South ◽  
Low Latitude ◽  
South Central ◽  
Two New Species ◽  
Bar Formation ◽  
Central Pyrenees

AbstractAn Ordovician–Silurian boundary section marked by an uninterrupted, relatively high rate of black shale sedimentation and abundant, diverse graptolites is described from the south-central Pyrenees. The structurally simple Estana section comprises the uppermost part of the quartzite-dominated Bar Formation and overlying black shales of late Hirnantian and early Rhuddanian age, which have been dated by graptolites to the upper Metabolograptus persculptus and lower–middle Akidograptus ascensus–Parakidograptus acuminatus biozones. Due to the absence of M. persculptus, a Metabolograptus parvulus Biozone correlative with the upper part of the persculptus Biozone is recognized below the lowest occurrence of akidograptids, which indicate the base of the Silurian System. The graptolite fauna comprise 27 species including Normalograptus minor, N. lubricus, N. rhizinus, Hirsutograptus, Korenograptus bifurcus, K. bicaudatus, K. lanpherei and Nd. shanchongensis, most of which were formerly considered to be endemic to the low-latitude palaeobiogeographical province of China, Siberia and northern North America. Two new species, N. baridaensis and N. ednae, are described. The succession of graptolite assemblages in the Estana section, and occurrence of several cosmopolitan taxa in its parvulus and lower ascensus–acuminatus biozones that are unknown elsewhere in peri-Gondwanan Europe, suggest that strata immediately surrounding the Ordovician–Silurian boundary may be absent, highly condensed or oxic and barren of graptolites in other sections of northwestern peri-Gondwana. Common graptolite synrhabdosomes and abnormal rhabdosomes may indicate some environmental stress in the parvulus Biozone, although the rather uniform black shale lithology, total organic carbon content and δ13Corg values suggest uninterrupted sedimentation under stable, anoxic conditions.

Widespread Late Devonian marine anoxia in eastern North America: a case study of the Kettle Point Formation black shale, southwestern Ontario

2016 ◽  
Vol 53 (8) ◽  
pp. 837-855 ◽  
Author(s):  
Nikole Bingham-Koslowski ◽  
Cameron Tsujita ◽  
Jisuo Jin ◽  
Karem Azmy
Keyword(s):  
North America ◽  
Sea Level ◽  
Black Shale ◽  
Black Shales ◽  
Shallow Waters ◽  
Eastern North America ◽  
Late Devonian ◽  
Red Beds ◽  
Relative Sea Level ◽  
Organic Rich Sediment

The Kettle Point Formation of southwestern Ontario consists of intervals of organic-rich interlaminated black shale interbedded with organic-poor greyish green mudstones and rare red beds, separated by metre-scale sequences of non-interlaminated black shale. The formation shows a largely consistent background value for the black shales around −20‰ δ34S, punctuated by a substantial positive excursion of ∼32‰ (up to +12.87‰) that coincides with a significant interval of greyish green mudstone and red beds. Lithological and geochemical data indicate that the black shales were deposited during periods of anoxia, with thick intervals of non-interlaminated black shales recording the peak of anoxia, whereas the greyish green mudstones record deposition in more oxygenated environments. Relative water depth is interpreted as the key control on the vertical and lateral distribution of the Kettle Point lithofacies. Interbedded black shales and greyish green mudstones were deposited in relatively shallow waters, where minor, short-lived falls in relative sea level promoted dysoxic to oxic conditions and the deposition of organic-poor lithologies. Non-interlaminated black shales are indicative of substantial rises in relative sea level, resulting in widespread anoxia and the deposition of thicker and more laterally extensive packages of organic-rich sediment. The formation of black shales in relatively shallow waters in southwestern Ontario implies that the extensive deposition of organic-rich sediment across eastern North America during the Late Devonian was a product of widespread anoxia related to restricted circulation in intracratonic and foreland basin depositional centers.

Organochlorine Contaminants in Headwater Peatlands, and Selected Estuary Sites of the Moose River

1986 ◽  
Vol 21 (2) ◽  
pp. 251-256 ◽  
Author(s):  
Robert C. McCrea ◽  
Greg M. Wickware
Keyword(s):  
Atmospheric Deposition ◽  
Organochlorine Pesticides ◽  
River Basin ◽  
Vascular Plants ◽  
Typha Latifolia ◽  
Coastal Marshes ◽  
Surficial Sediments ◽  
Organochlorine Contaminants ◽  
Hexachlorocyclohexane Isomers ◽  
Moose River

Abstract Peatland waters of the Moose River basin, as well as surficial sediments and vascular plants of the estuary were sampled in 1982. Elevated levels of PCBs were found at all five peatland sites; concentrations ranged from 28 to 65 ng/L. Of the seventeen organochlorine pesticides investigated, the hexachlorocyclohexane isomers (a-and y-BHC) were the most prominent with total BHC concentrations ranging from 1.5 to 13.7 ng/L. The presence of these contaminants in ombrotrophic bogs indicated that there was atmospheric deposition of organochlorine contaminants in the basin. Analyses of surficial sediments, collected from tidal flats and coastal marshes, showed that PCBs and organochlorine pesticides were not present. Samples of Triglochin maritima L. seed heads and Typha latifolia L. roots were also free of PCBs.

Sorption of pesticides used in banana production on soils of Ecuador

Soil Research ◽  
2002 ◽  
Vol 40 (7) ◽  
pp. 1085 ◽  
Author(s):  
Tanya Cáceres ◽  
Guang-Guo Ying ◽  
Rai Kookana
Keyword(s):  
River Basin ◽  
Ecosystem Health ◽  
Production Systems ◽  
Parent Compound ◽  
Mean Value ◽  
Organic Carbon Content ◽  
Banana Production ◽  
Kd Values ◽  
Production Area ◽  
Impact Of Pesticides

There is concern about the migration and adverse impact of pesticides used in banana production systems in Ecuador on aquaculture and ecosystem health. Therefore, we studied the sorption of chlorothalonil, fenamiphos, and its 2 metabolites (fenamiphos sulfone and fenamiphos sulfoxide), by batch method on 6 surface soils from the Guayas River Basin (1–3�S, 79–81�W), a major banana production area of Ecuador. The sorption of chlorothalonil on the 6 soils was high and varied considerably as shown by the Kd values ranging from 68.50 to 152.60 L/kg. The sorption coefficients normalised with the organic carbon content of soil (Koc) for chlorothalonil ranged from 2330 to 7336 kg/L, with a mean value of 4012 kg/L. These Koc values are higher than those previously reported in the literature. The sorption of fenamiphos and its metabolites to the 6 soils varied among soils in a similar pattern. The Kd values ranged from 5.66 to 14.31�L/kg for fenamiphos, from 2.81 to 8.79 L/kg for fenamiphos sulfone, and from 0.77 to 4.00 L/kg for fenamiphos sulfoxide, respectively. In all of the soils the sorption coefficients of both metabolites of fenamiphos were lower than that for the parent compound. The Koc values ranged from 220 to 515 kg/L (mean value 371 kg/L) for fenamiphos, from 29 to 141 kg/L (mean value of 76 kg/L) for fenamiphos sulfoxide, and from 79 to 334 kg/L (mean value of 191 kg/L) for fenamiphos sulfone. Chlorothalonil had much stronger sorption than fenamiphos and its metabolites on the Ecuadorian soil. Due to lower sorption and therefore greater mobility and longer persistence of the fenamiphos metabolites, these compounds need adequate consideration during residue monitoring and assessment of potential off-site impacts on ecosystem health and aquaculture in the Guayas River Basin.

scholarly journals Erratum to “A Perspective on Stratigraphic, Vertically-Upward “Displacements or Dislocations” of Conodont-Elements: An Example From the Upper Devonian, Pre-Lithified, Black Shales of the Chattanooga Shale Formation In Tennessee, USA” ...

2019 ◽  
Vol 9 (1) ◽  
pp. 14
Author(s):  
Michael Iannicelli
Keyword(s):  
Black Shale ◽  
Environmental Chemistry ◽  
Black Shales ◽  
Photic Zone ◽  
Marine Organic Matter ◽  
Chattanooga Shale ◽  
Shale Formation ◽  
Organic Matter Biomarkers ◽  
Reference Section ◽  
Made In

Even though the author already incorporated the citation of Sinninghe-Damste & Schouten (2006) into the text of the paper, the author regrets having failed to include their full citation within the Reference Section of my above paper which is: Sinninghe-Damste, J. S. & Schouton, S. (2006). Biological markers for anoxia in the photic zone of the water column. In, Volkman, J. K. (ed.), Marine Organic Matter: Biomarkers, Isotopes and DNA, (pp. 127 – 163). The Handbook of Environmental Chemistry, vol. 2N. Springer: Berlin and Heidelberg. https://doi.org/10.1007/698_2_005 The author also needs to paraphrase a statement made in the last three lines of the 2nd paragraph on page 40 where it reads as: “Thus, we may conclude here that paleo-upfreezing of any conodont-element(s) originally buried in the pre-lithified, light-colored shale occurred in order to account for their presence in black shale”. Instead, in lieu of that statement, it should read as “At this point in time of the study, we may tentatively conclude here while completely concluding later in the study, that conodont-elements originally existing in the underlying, pre-lithified, light-colored shale, had to paleo-upfreeze vertically upward into pre-lithified, black shale sediment in order to account for their presence in lithified black shale”.

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