Metallogenesis of the Abitibi greenstone belt of Canada: a contribution from the analysis of trace lead in sulfide minerals

1989 ◽  
Vol 26 (12) ◽  
pp. 2529-2540 ◽  
Author(s):  
Etienne Deloule ◽  
Clément Gariépy ◽  
Bernard Dupré

Pb-isotopic compositions are reported for 12 ore localities within the late Archean Abitibi greenstone belt. The studied samples carry massive or disseminated sulfides hosted in a variety of materials, including mafic–ultramafic igneous rocks, felsic lavas, porphyries, and sedimentary iron formations. Repeated leaching experiments on these sulfides frequently revealed the presence of a radiogenic Pb component, which is attributed to in situ decay of U and Th. The leaching experiments make it possible, in some cases, to separate the radiogenic Pb from the initial Pb included in the minerals. Six Pb–Pb isochrons formed by the analyses on leachates and residues show little evidence of secondary perturbations and yield ages that are, within error, similar to those determined for the supracrustal assemblage. This implies that the ores were concentrated synchronously with the main phases of magmatic activity, close to 2.7 Ga.The initial isotopic compositions of the sulfide specimens point to the existence of two different sources of metals: (i) juvenile, mantle-derived igneous rocks and (ii) older recycled supracrustal series. Ore formation frequently involves mixing of metals from these two sources in variable proportions. The initial isotopic composition of these two reservoirs is best evaluated by examining the composition of sulfides associated with komatiitic lava flows and with sedimentary iron formations, respectively.

2021 ◽  
Author(s):  
D. Yergeau ◽  
P. Mercier-Langevin ◽  
B. Dubé ◽  
M. Malo ◽  
A. Savoie

Abstract The Westwood deposit (4.5 Moz Au) is hosted in the 2699–2695 Ma Bousquet Formation volcanic and intrusive rocks, in the eastern part of the Blake River Group, southern Abitibi greenstone belt. The Bousquet Formation is divided in two geochemically distinct members: a mafic to intermediate, tholeiitic to transitional lower member and an intermediate to felsic, transitional to calc-alkaline upper member. The Bousquet Formation is cut by the synvolcanic (2699–2696 Ma) polyphase Mooshla Intrusive Complex, which is cogenetic with the Bousquet Formation. The deposit contains three strongly deformed (D2 flattening and stretching), steeply S-dipping mineralized corridors that are stacked from north to south: Zone 2 Extension, North Corridor, and Westwood Corridor. The North and Westwood corridors are composed of Au-rich polymetallic sulfide veins and stratabound to stratiform disseminated to massive sulfide ore zones that are spatially and genetically associated with the calcalkaline, intermediate to felsic volcanic rocks of the upper Bousquet Formation. The formation of the disseminated to semimassive ore zones is interpreted as strongly controlled by the replacement of porous volcaniclastic rocks at the contact with more impermeable massive cap rocks that helped confine the upflow of mineralizing fluids. The massive sulfide lenses are spatially associated with dacitic to rhyolitic domes and are interpreted as being formed, at least in part, on the paleoseafloor. The epizonal, sulfide-quartz vein-type ore zones of the Zone 2 Extension are associated with the injection of subvolcanic, calc-alkaline felsic sills and dikes within the lower Bousquet Formation. These subvolcanic intrusive rocks, previously interpreted as lava flows, are cogenetic and coeval with the intermediate to felsic lava flows and domes of the upper Bousquet Formation. The change from fractional crystallization to assimilation- and fractional crystallization-dominated processes and transitional to calc-alkaline magmatism is interpreted to be responsible for the development of the auriferous ore-forming system. The Westwood deposit is similar to some Phanerozoic Au ± base metal-rich magmatic-hydrothermal systems, both in terms of local volcano-plutonic architecture and inferred petrogenetic context. The complex volcanic evolution of the host sequence at Westwood, combined with its proximity to a polyphase synvolcanic intrusive complex, led to the development of one of the few known large Archean subaqueous Au-rich magmatic-hydrothermal systems.


1979 ◽  
Vol 16 (3) ◽  
pp. 440-458 ◽  
Author(s):  
R. Kerrich ◽  
B. J. Fryer

The Porcupine District, Abitibi Greenstone Belt, is one of the most extensive areas of Archaean auriferous mineralisation. At least two stages of lode-gold emplacement are recognised: the first stage involves gold-bearing carbonate–chert chemical sediments within the lower mafic volcanic sequence; the second stage is represented by auriferous hydrothermal quartz veins which postdate deformation of the greenstone assemblage and transect diverse host rocks.Rare-earth element (REE) concentrations in the stratiform carbonates are typical of the distinctive patterns recorded for Archaean chemical sediments. Chert in these rocks has a δ18O value averaging 17.1‰, implying exchange from heavier 18/16 ratios during diagenesis and metamorphism. Metabasic volcanic rocks and quartz–feldspar porphyry stocks with background gold abundances have mean whole-rock δ18O values of 9.1‰ and 10.7‰ respectively. This enrichment in 18O relative to primary igneous rocks is attributed to oxygen isotope exchange with seawater at low temperatures during fluid transport through the oceanic crust.Quartz in all of the five hydrothermal vein systems present has a δ18O of 14‰ to 15‰, and quartz-muscovite fractionations are 3.4‰ to 3.8‰. Ambient temperatures of mineralisation are estimated to have been 400 °C to 450 °C, from oxygen isotope thermometers, fluid inclusion filling temperatures, and metamorphic mineral assemblages. The calculated δ18O of the mineralising solutions is~10‰, implying fluids of metamorphic origin. REE patterns in hydrothermal quartz veins suggest that they have been derived from high-temperature solutions in equilibrium with source rocks having relatively flat (chondrite normalised) REE distributions, such as tholeiitic and komatiitic volcanics. Adjacent to hydrothermal veins, quartz in igneous rocks approaches isotopic equilibrium with vein quartz, at 15‰, and whole-rock δ18O values for metabasalts shift to ~11‰, implying extensive water-rock interaction. Strong depletions in heavy REE of metabasic schists adjacent to veins provides further evidence for pervasive hydrothermal alteration. The Eu enrichment of all lode gold deposits analysed at Dome Mine is consistent with the reduced state of the solutions involved in their deposition, as recorded by the predominance of Fe2+. The gold-bearing veins are believed to have formed by focussed flow of fluids outgassed at the greenschist–amphibolite transition. Source volumes for Au in the Porcupine District exceed 600 km3, the carrier fluid volume for mineralisation was 60–90 km3, the Au solute concentration in the low nanogram mL−1 range, and transport distances were of the order of 10 km. Such veins may be the precursors of precious-metal-bearing chemical sediments if fluids debouche into the hydrosphere.


2019 ◽  
Vol 9 (1) ◽  
Author(s):  
Mara Murri ◽  
Maria C. Domeneghetti ◽  
Anna M. Fioretti ◽  
Fabrizio Nestola ◽  
Francesco Vetere ◽  
...  

AbstractTerrestrial analogues are often investigated to get insights into the geological processes occurring on other planetary bodies. Due to its thickness and petrological similarities, the pyroxenitic layer of the 120m-thick magmatic pile Theo’s Flow (Archean Abitibi greenstone belt Ontario, Canada), has always been regarded as the terrestrial analogue for Martian nakhlites. However, its origin and cooling history and, as a consequence those of nakhlites, have always been a matter of vigorous debate. Did this lava flow originate from a single magmatic event similar to those supposed to occur on Mars or do the different units derive from multiple eruptions? We demonstrate, by a combination of geothermometric constraints on augite single crystals and numerical simulations, that Theo’s Flow has been formed by multiple magma emplacements that occurred at different times. This discovery supports the idea that the enormous lava flows with similar compositions observed on Mars could be the result of a process where low viscosity lavas are emplaced during multiple eruptions. This has profound implications for understanding the multiscale mechanisms of lava flow emplacement on Earth and other planetary bodies.


2011 ◽  
Vol 48 (4) ◽  
pp. 757-777 ◽  
Author(s):  
P.-S. Ross ◽  
V. McNicoll ◽  
J. Goutier ◽  
P. Mercier-Langevin ◽  
B. Dubé

In the Archean Blake River Group, mafic to intermediate fragmental units have controversially been proposed to have formed during the collapse of a giant submarine caldera. This paper describes and interprets these rocks, summarizing their physical characteristics, inferred origins, age relationships, and geochemical signatures. The widespread Stadacona member, south of Rouyn-Noranda, consists of several hundred metres of bedded volcaniclastic rocks interpreted to have been mostly deposited from aqueous density currents fed directly by explosive eruptions. The magmas involved in these eruptions were plagioclase-phyric, tholeiitic to transitional basalts. The similarly widespread D’Alembert tuff, in the northern part of the Blake River Group, shares many physical characteristics with the Stadacona member and is thought to have a similar origin. However, the D’Alembert tuff is approximately six million years younger than the Stadacona member. It is composed mostly of transitional to calc-alkaline andesites and basaltic andesites with very distinct trace element profiles. Volcaniclastic rocks from other areas, such as Tannahill Township in Ontario and the Monsabrais area in Quebec, are interpreted to represent mostly in situ to remobilized hyaloclastite, with no explosive eruptions involved in their genesis. Our observations and interpretations are not compatible with models in which the volcaniclastic units are emplaced during a catastrophic event in relation with the collapse of a giant caldera. Instead, the fragmental rocks were produced by various mechanisms at many distinct times during the evolution of the Blake River Group.


2017 ◽  
Vol 120 (3) ◽  
pp. 303-322
Author(s):  
D. Pienaar ◽  
B.M. Guy ◽  
C. Pienaar ◽  
K.S. Viljoen

Abstract Mineralogical and textural variability of ores from different sources commonly leads to processing inefficiencies, particularly when a processing plant is designed to treat ore from a single source (i.e. ore of a relatively uniform composition). The bulk of the Witwatersrand ore in the Klerksdorp goldfield, processed at the AngloGold Ashanti Great Noligwa treatment plant, is derived from the Vaal Reef (>90%), with a comparatively small contribution obtained from the Crystalkop Reef (or C-Reef). Despite the uneven contribution, it is of critical importance to ensure that the processing parameters are optimized for the treatment of both the Vaal and C-Reefs. This paper serves to document the results of a geometallurgical study of the C-Reef at the Great Noligwa gold mine in the Klerksdorp goldfield of South Africa, with the primary aim of assessing the suitability of the processing parameters that are in use at the Great Noligwa plant. The paper also draws comparisons between the C-Reef and the Vaal Reef A-facies (Vaal Reef) and attempts to explain minor differences in the recovery of gold and uranium from these two sources. Three samples of the C-Reef were collected in-situ from the underground operations at Great Noligwa mine for mineralogical analyses and metallurgical tests. Laboratory-scale leach tests for gold (cyanide) and uranium (sulphuric acid) were carried out using dissolution conditions similar to that in use at the Great Noligwa plant, followed by further diagnostic leaching in the case of gold. The gold in the ore was found to be readily leachable with recoveries ranging from 95% to 97% (as opposed to 89% to 93% for the Vaal Reef). Additional recoveries were achieved in the presence of excess cyanide (96% to 98%). The recovery of uranium varied between 72% and 76% (as opposed to 30% to 64% for the Vaal Reef), which is substantially higher than predicted, given the amount of brannerite in the ore, which is generally regarded as refractory. Thus, the higher uranium recoveries from the C-Reef imply that a proportion of the uranium was recovered by the partial dissolution of brannerite. As the Vaal Reef contain high amounts of chlorite (3% to 8%), which is an important acid consumer, it is considered likely that this could have reduced the effectiveness of the H2SO4 leach in the case of the ore of the Vaal Reef. Since the gold and uranium recoveries from the C-Reef were higher than the recoveries from the Vaal Reef, the results demonstrate that the processing parameters used for treatment of the Vaal Reef are equally suited to the treatment of the C-Reef. Moreover, small processing modifications, such as increased milling and leach retention times, may well increase the recovery of gold (particularly when e.g. coarse gold, or unexposed gold, is present).


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