Inferences of lithospheric evolution in Italy from Pb isotopic compositions in northern Apennine cherts

1985 ◽  
Vol 22 (9) ◽  
pp. 1370-1373 ◽  
Author(s):  
R. Vollmer

Pb isotope data by Barrett on Upper Jurassic cherts and associated ophiolites in the northern Apennines form a mixing trend with only two end members. Oblique secondary trends in the data are most likely an effect of radiogenic growth since the Jurassic and not due to multiple end members as proposed by Thorpe in his criticism of Barrett. Implications of these data for the evolution of the lithosphere in this region have not been previously discussed: (1) the distinct Pb isotopic signature of the chert end member is shared by the Pb in the Cenozoic Tuscan anatectic magmas, which suggests the same crustal provenance for both leads, and (2) the Jurassic sea-floor basalts constrain the age of anomalous metasomatized mantle now underlying most of Italy to less than 140 Ma.

Minerals ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 25
Author(s):  
Shuang-Shuang Chen ◽  
Tong Hou ◽  
Jia-Qi Liu ◽  
Zhao-Chong Zhang

Shikoku Basin is unique as being located within a trench-ridge-trench triple junction. Here, we report mineral compositions, major, trace-element, and Sr-Nd-Pb isotopic compositions of bulk-rocks from Sites C0012 (>18.9 Ma) and 1173 (13–15 Ma) of the Shikoku Basin. Samples from Sites C0012 and 1173 are tholeiitic in composition and display relative depletion in light rare earth elements (REEs) and enrichment in heavy REEs, generally similar to normal mid-ocean ridge basalts (N-MORB). Specifically, Site C0012 samples display more pronounced positive anomalies in Rb, Ba, K, Pb and Sr, and negative anomalies in Th, U, Nb, and Ta, as well as negative Nb relative to La and Th. Site 1173 basalts have relatively uniform Sr-Nd-Pb isotopic compositions, close to the end member of depleted mantle, while Site C0012 samples show slightly enriched Sr-Nd-Pb isotopic signature, indicating a possible involvement of enriched mantle 1 (EM1) and EM2 sources, which could be attributed to the metasomatism of the fluids released from the dehydrated subduction slab, but with the little involvement of subducted slab-derived sedimentary component. Additionally, the Shikoku Basin record the formation of the back-arc basin was a mantle conversion process from an island arc to a typical MORB. The formation of the Shikoku Basin is different from that of the adjacent Japan Sea and Parece Vela Basin, mainly in terms of the metasomatized subduction-related components, the nature of mantle source, and partial melting processes.


2018 ◽  
Vol 156 (5) ◽  
pp. 833-848 ◽  
Author(s):  
R. M. MOUMBLOW ◽  
G. A. ARCURI ◽  
A. P. DICKIN ◽  
C. F. GOWER

AbstractThe Makkovik Province of eastern Labrador represents part of an accretionary orogen active during an early stage in the development of the Palaeoproterozoic southern Laurentian continental margin. New Nd isotope data for the eastern Makkovik Province suggest that accreted juvenile Makkovik crust was generated in the Cape Harrison domain during a single crust-forming event at c. 2.0 Ga. Pb isotope data support this model, and show a strong similarity to radiogenic crustal signatures in the juvenile Palaeoproterozoic crust of the Ketilidian mobile belt of southern Greenland. As previously proposed, an arc accretion event at c. 1.9 Ga triggered subduction-zone reversal and the development of an ensialic arc on the composite margin. After the subduction flip, a temporary release of compressive stress at c. 1.87 Ga led to the development of a retro-arc foreland basin on the downloaded Archean continental edge, forming the Aillik Group. Unlike previous models, a second arc is not envisaged. Instead, a compressive regime at c. 1.82 Ga is attributed to continued ensialic arc plutonism on the existing margin. The tectonic model for the Makkovikian orogeny proposed here is similar to that for the Ketilidian orogeny. Major- and trace-element analyses suggest that much of the magmatism in the Makkovik orogen results from post-accretionary ensialic arc activity, and that few vestiges remain of the original accreted volcanic arc. This pattern of arc accretion and intense post-accretion reworking is common to many accretionary orogens, such as the South American Andes and North American Cordillera.


Author(s):  
Neil A Fernandes ◽  
Gema R. Olivo ◽  
Daniel Layton-Matthews ◽  
Alexandre Voinot ◽  
Donald Chipley ◽  
...  

ABSTRACT Different types of sediment-hosted whole-rock Pb isotope (206Pb/204Pb, 207Pb/204Pb, 208Pb/204Pb) compositions were determined from phyllites, carbonaceous phyllites (>1% TOC), and meta-litharenites belonging to the Serra do Garrote Formation, which is part of the Proterozoic Vazante Group, Brazil. Results were integrated with lithogeochemistry in order to identify the Pb isotopic signature of Zn enrichment (up to 0.24 wt.% Zn) associated with meta-siliciclastic-hosted sulfide mineralization that formed prior to the Brasiliano Orogeny (850 to 550 Ma) in order to (1) understand the nature of siliciclastic sediment sources, (2) identify possible metal sources in pre-orogenic meta-siliciclastic-hosted Zn mineralization, and (3) evaluate the genetic links between the Zn enrichment in the relatively reduced phyllite package, and different styles of syn-orogenic Zn ± Pb mineralization (hypogene Zn-silicate and Zn-Pb sulfide) in overlying dolomitic carbonates throughout the Vazante-Paracatu Zn District, Brazil. The whole-rock 206Pb/204Pb and 207Pb/204Pb isotope ratios of meta-siliciclastic rocks plot as positively sloping, sub-parallel arrays with radiogenic, upper continental crust compositions, which could represent a detrital contribution from at least two upper continental crust sources. However, the 206Pb/204Pb versus 207Pb/204Pb isotope system does not distinguish between Zn-enriched samples and un-mineralized samples. In the whole-rock 206Pb/204Pb–208Pb/204Pb plot, Zn-enriched samples form a flat trend of lower 208Pb/204Pb values (38.3 to 39.5) compared to the Zn-poor ones that follow common upper crustal trends. Zinc-enriched samples have low whole-rock Th/U values (<4) and higher whole-rock U concentrations compared to unmineralized samples. These support the hypothesis that U (± Pb) was added by pre-orogenic metalliferous fluids, which were in turn derived from underlying Paleoproterozoic and Archean basement rocks. Due to U addition, the original whole-rock thorogenic and uranogenic Pb isotope systems were decoupled in mineralized samples. Pre-orogenic metalliferous fluids have similar present-day first-order characteristics, including: (1) relatively high U/Pb and (2) low Th/U values, when compared to galena in the major carbonate-hosted Zn ± Pb deposits (Vazante, Morro Agudo, Ambrosia, Fagundes) in the Vazante Group. These results support the hypothesis that Zn-rich layers and veins in mineralized carbonaceous phyllites could be linked to the same origins as carbonate-hosted mineral deposits throughout the Vazante Basin, but further data are warranted. We suggest that the tectonic evolution of the Vazante Basin saw multiple phases of Zn-rich mineralization over protracted time periods from around 1200 to 550 Ma.


1996 ◽  
Vol 133 (5) ◽  
pp. 611-617 ◽  
Author(s):  
R. Haggerty ◽  
B. M. Rohl ◽  
P. D. Budd ◽  
N. H. Gale

AbstractPb-isotope data on ore galenas from the West Shropshire orefield show a significant spread of 20pb/204pb values, with minor variation in 207Pb/204Pb and 208Pb/204Pb ratios. These indicate that lead was derived from multiple sources, some of them uranium-enriched and incompletely mixed prior to ore deposition. Four possible mineralizing agents are considered: circulating sea-water, metamorphic waters, basinal brines and convecting formation waters. Pb-isotope data exclude a circulating sea-water origin for the mineralization, and best support a convecting formation water mineralizing agent. A model involving a single fluid tapping multiple lead sources is proposed to explain the observed Pb-isotope variation.


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