Geochemistry of Precambrian basaltic rocks from the Central African Republic (Equatorial Africa)

1985 ◽  
Vol 22 (5) ◽  
pp. 653-662 ◽  
Author(s):  
J. Dostal ◽  
C. Dupuy ◽  
J. L. Poidevin
Keyword(s):  
Upper Mantle ◽  
Central African Republic ◽  
Incompatible Element ◽  
Dolerite Dyke ◽  
Basaltic Rocks ◽  
Incompatible Elements ◽  
Equatorial Africa ◽  
Metavolcanic Rocks ◽  
Greenstone Belts ◽  
Dyke Swarms

The two Archaean greenstone belts (Bandas and Bogoin) in the Central African Republic (Equatorial Africa) are 250 and 150 km long. The metavolcanic rocks in the belts are predominantly komatiitic and tholeiitic basalts. Komatiites include both Al-depleted and Al-undepleted types. The komatiites and light-REE-depleted tholeiites were probably derived from a similar upper mantle source. However, the tholeiitic basalts enriched in light REE from the upper volcanic strata of the Bandas belt were generated from a different source. The dolerites from Proterozoic dyke swarms and sills differ from the basalts mainly in their abundances and ratios of several incompatible elements such as K, Rb, Th, and light REE. They were derived from a distinct, incompatible-element-enriched upper mantle source.The average background gold levels in the Bandas belt and dolerite dyke swarms are comparable to those in equivalent rocks from North America. The exception is the Bogoin greenstone belt, which has anomalously high gold abundances.

Geochemistry of Siluro-Devonian Tobique volcanic belt in northern and central New Brunswick (Canada): tectonic implications

1989 ◽  
Vol 26 (6) ◽  
pp. 1282-1296 ◽  
Author(s):  
J. Dostal ◽  
R. A. Wilson ◽  
J. D. Keppie
Keyword(s):  
New Brunswick ◽  
Mantle Source ◽  
Upper Mantle ◽  
Volcanic Rocks ◽  
Volcanic Belt ◽  
Continental Rift ◽  
Basaltic Rocks ◽  
Incompatible Elements ◽  
Tectonic Implications

Siluro-Devonian volcanic rocks of the northwestern mainland Appalachians are found mainly in the Tobique belt of New Brunswick where they consist predominantly of bimodal mafic–felsic suites erupted in a continental-rift environment. The axis of the Tobique rift trends north-northeast – south-southwest, obliquely to the regional northeast–southwest trend of the Appalachians. These geometric relationships are interpreted as being the result of rifting in a sinistral shear regime produced during emplacement of the Avalon terrene. The basaltic rocks are continental tholeiites and transitional basalts derived from a heterogeneous upper-mantle source that was enriched in incompatible elements relative to the primordial mantle. The mantle source was probably affected by the subduction processes.

scholarly journals Secular oxidation of Archean upper mantle caused by increasing crustal recycling

2021 ◽  
Author(s):  
Lei Gao ◽  
Shuwen Liu ◽  
Peter Cawood ◽  
Jintuan Wang ◽  
Guozheng Sun ◽  
...  
Keyword(s):  
Upper Mantle ◽  
Redox State ◽  
Incompatible Element ◽  
Volcanic Rocks ◽  
Crustal Recycling ◽  
Incompatible Elements ◽  
Mid Ocean Ridge ◽  
Redox Evolution ◽  
Ocean Ridge ◽  
Plate Subduction

Abstract The redox evolution of Archean mantle impacted Earth differentiation, mantle melting and the nature of chemical equilibrium between mantle, ocean and atmosphere of the early Earth. However, how and why it varies with time remain controversial. Archean mantle-derived volcanic rocks, especially basalts are ideal lithologies for reconstructing the mantle redox state. Here we show that the ~3.8-2.5 Ga basalts from fourteen cratons are subdivided geochemically into two groups, B-1, showing incompatible element depleted and modern mid-ocean ridge basalt-like features ((Nb/La)PM ≥ 0.75) and B-2 ((Nb/La)PM < 0.75), characterized by modern island arc basalt-like features. Our updated V-Ti redox proxy indicates the Archean upper mantle was more reducing than today, and that there was a significant redox heterogeneity between ambient and modified mantle presumably related to crustal recycling, perhaps via plate subduction, as shown by B-1 and B-2 magmas, respectively. The oxygen fugacity of modified mantle exhibits a ~1.5-2.0 log units increase over ~3.8-2.5 Ga, whereas the ambient mantle becomes more and more heterogeneous with respect to redox, apart from a significant increase at ~2.7 Ga. These findings are coincident with the increase in the proportions of crustal recycling-related lithologies with associated enrichment of associated incompatible elements (e.g., Th/Nb), indicating that increasing recycling played a crucial role on the secular oxidation of Archean upper mantle.

Geochemistry and origin of Mesoproterozoic metavolcanic rocks from Fisher Massif, Prince Charles Mountains, East Antarctica

1996 ◽  
Vol 8 (1) ◽  
pp. 85-104 ◽  
Author(s):  
E. V. Mikhalsky ◽  
J. W. Sheraton ◽  
A. A. Laiba ◽  
B. V. Beliatsky
Keyword(s):  
Tectonic Setting ◽  
Active Continental Margin ◽  
Volcanic Rocks ◽  
Granulite Facies ◽  
Island Arc ◽  
Crustal Component ◽  
Basaltic Rocks ◽  
Metavolcanic Rocks ◽  
High K ◽  
Low K

Fisher Massif consists of Mesoproterozoic (c. 1300 Ma) lower amphibolite-facies metavolcanic rocks and associated metasediments, intruded by a variety of subvolcanic and plutonic bodies (gabbro to granite). It differs in both composition and metamorphic grade from the rest of the northern Prince Charles Mountains, which were metamorphosed to granulite facies about 1000 m.y. ago. The metavolcanic rocks consist mainly of basalt, but basaltic andesite, andesite, and more felsic rocks (dacite, rhyodacite, and rhyolite) are also common. Most of the basaltic rocks have compositions similar to low-K island arc tholeiites, but some are relatively Nb-rich and more akin to P-MORB. Intermediate to felsic medium to high-K volcanic rocks, which appear to postdate the basaltic succession, have calc-alkaline affinities and probably include a significant crustal component. On the present data, an active continental margin with associated island arc was the most likely tectonic setting for generation of the Fisher Massif volcanic rocks.

Variable unroofing in the western Superior Province - metamorphic evidence and possible origin

2006 ◽  
Vol 43 (7) ◽  
pp. 805-819 ◽  
Author(s):  
Andrew Hynes ◽  
Zixin Song
Keyword(s):  
Superior Province ◽  
Surface Distribution ◽  
Seismic Line ◽  
The North ◽  
Metavolcanic Rocks ◽  
Limited Support ◽  
Greenstone Belts ◽  
Rotation Motion ◽  
East West ◽  
Broad Region

Western Superior Lithoprobe seismic-reflection line 1 exhibits a broad region of northward-dipping reflectors in the Uchi subprovince, which gives way to southward-dipping reflectors farther north in the Berens River sub province. Mafic metavolcanic rocks across the region of northward-dipping reflectors exhibit a decline in metamorphic pressure, from pressures of 6 kbar (1 kbar = 100 MPa) in the south to only 2 kbar 80 km to the north. This indicates that the southern edge of the Uchi subprovince has undergone significantly more unroofing than regions farther north. The differential unroofing is not consistent with a doubly vergent thrusting origin for the northward- and southward-dipping reflector pattern. It could result from a crustal-scale synform, of which the region of northward-dipping reflectors would make up the southern limb. Metamorphic pressures from samples off the seismic line, however, provide only limited support for a regional synform, and suggest that much of the pressure variation may result from deformation associated with motion on late faults that are widespread in the western Superior Province. These faults occur in a WNW-striking set with dextral offsets and an ENE-striking set with sinistral offsets. They could result from north–south compression and east–west extension, provided the faults have rotated towards the east–west direction during deformation. Regional tilting and (or) jostling of crustal blocks is attributed to deformation associated with the fault rotation. Motion on the faults and the associated deformation of intervening fault blocks may be important contributors to the present crustal architecture of the western Superior Province, including the surface distribution and form of the greenstone belts.

Central Superior Province geology: evidence for an allochthonous, ensimatic, southern Abitibi greenstone belt

1990 ◽  
Vol 27 (4) ◽  
pp. 582-589 ◽  
Author(s):  
S. L. Jackson ◽  
R. H. Sutcliffe
Keyword(s):  
Crustal Structure ◽  
Greenstone Belt ◽  
Superior Province ◽  
Low Grade ◽  
Simple Correlation ◽  
Abitibi Greenstone Belt ◽  
Structural Style ◽  
Metavolcanic Rocks ◽  
Crustal Model ◽  
Greenstone Belts

Published U–Pb geochronological, geological, and petrochemical data suggest that there are late Archean ensialic greenstone belts (GB) (Michipicoten GB and possibly the northern Abitibi GB), ensimatic greenstone belts (southern Abitibi GB and Batchawana GB), and possibly a transitional ensimatic–ensialic greenstone belt (Swayze GB) in the central Superior Province. This lateral crustal variability may preclude simple correlation of the Michipicoten GB and its substrata, as exposed in the Kapuskasing Uplift, with that of the southern Abitibi GB. Furthermore, this lateral variability may have determined the locus of the Kapuskasing Uplift. Therefore, although the Kapuskasing Uplift provides a useful general crustal model, alternative models of crustal structure and tectonics for the southern Abitibi GB warrant examination.Thrusting of a juvenile, ensimatic southern Abitibi GB over a terrane containing evolved crust is consistent with (i) the structural style of the southern Abitibi GB; (ii) juvenile southern Abitibi GB metavolcanic rocks intruded by rocks having an isotopically evolved, older component; and (iii) Proterozoic extension that preserved low-grade metavolcanic rocks within the down-dropped Cobalt Embayment, which is bounded by higher grade terranes to the east and west.

Suite subdivision and petrological evolution of granitoids from the Taylor Valley and Ferrar Glacier region, south Victoria Land

1992 ◽  
Vol 4 (1) ◽  
pp. 71-87 ◽  
Author(s):  
Robert W. Smillie
Keyword(s):  
Upper Mantle ◽  
Structural Control ◽  
Geological Mapping ◽  
Dry Valleys ◽  
Crustal Extension ◽  
Calc Alkaline ◽  
Taylor Valley ◽  
Victoria Land ◽  
Early Palaeozoic ◽  
Dyke Swarms

Detailed geological mapping and geochemical analysis of early Palaeozoic granitoid plutons and dykes from the Taylor Valley and Ferrar Glacier region in south Victoria Land reveal two distinct suites. This suite subdivision-approach is a departure from previous lithology-based schemes and can be applied elsewhere in south Victoria Land. The older calc-alkaline Dry Valleys 1 suite is dominated by the compositionally variable Bonney Pluton, a flow-foliated concordant pluton with an inferred length of over 100 km. Plutons of this suite are elongate in a NW-SE direction and appear to have been subjected to major structural control during their emplacement. The younger alkali-calcic Dry Valleys 2 suite comprises discordant plutons and numerous dyke swarms with complex age relationships. Field characteristics of this suite indicate that it was passively emplaced into fractures at higher levels in the crust than the Dry Valleys 1 suite. Whole-rock geochemistry confirms this suite subdivision based on field relationships and indicates that the two suites were derived from different parent magmas by fractional crystallization. The Dry Valleys 1 suite resembles Cordilleran I-type granitoids and is inferred to be derived from partial melting of the upper mantle and/or lower crust above an ancient subduction zone. The Dry Valleys 2 suite resembles Caledonian I-type granitoids and may have resulted from a later episode of crustal extension.

The geochemistry of mafic and ultramafic from the Archaean greenstone belts of Sierra Leone

1983 ◽  
Vol 47 (344) ◽  
pp. 267-280 ◽  
Author(s):  
H. R. Rollinson
Keyword(s):  
Sierra Leone ◽  
Magma Chamber ◽  
Source Region ◽  
Double Diffusion ◽  
Ultramafic Rocks ◽  
Magma Chambers ◽  
Basaltic Rocks ◽  
Ocean Ridges ◽  
Different Depths ◽  
Greenstone Belts

AbstractThe Archaean (c. 2800 Ma) ultramafic rocks in eastern Sierra Leone cut basalt lavas and are mostly olivine-rich cumulates either iron-rich (Fo85–86) and derived from a basaltic or picritic parent, or more magnesian (Fo92–93) derived from an ultramafic melt with c. 18–25 wt. % MgO. In central Sierra Leone the ultramafic rocks are lavas predating tholeiitic basalts.The basalts show a wide variation in Zr/Y, suggesting that garnet was present in the source region of some of these rocks but not others. This implies that melting took place at different depths in the mantle. The REE evidence for basaltic rocks in the upper part of the Nimini belt succession suggests that they were derived from a mantle source region which had already suffered melt extraction. Ti/Zr ratios in the basaltic rocks are also variable and individual belts define different trends on a Ti vs. Zr plot implying that the basaltic rocks evolved in geographically distinct magma chambers. It is likely that the basaltic rocks evolved from a parental liquid with Ti/Zr = 90 via shallow level crystal fractionation. The source region for these rocks therefore had a lower than chondritic Ti/Zr.There are two possible models for the basaltic and ultramafic magmas in the Sierra Leone greenstone belts. First that the ultramafic and basaltic liquids were derived from mantle diapirs of differing size, but originating in the same region of the mantle. Ultramafic liquids were produced in small diapirs, which store large melt fractions, and basaltic liquids in larger diapirs which segregate larger melt fractions. A second model is based upon the double diffusion process suggested for magma chambers at mid-ocean ridges and involves a transient magma chamber from which basalts, derived from parental ultramafic liquids, are erupted, with ultramafic liquids rising directly to the surface when the magma chamber is frozen. The available data does not discriminate between these two models.

Implication of Mesoproterozoic (∼1.4 Ga) magmatism within Sette-Daban (Southeast Siberia)

2021 ◽  
Author(s):  
Sergey Malyshev ◽  
Andrey Khudoley ◽  
Alexei Ivanov ◽  
Vadim Kamenetsky ◽  
Maya Kamenetsky
Keyword(s):  
Mantle Source ◽  
Regression Line ◽  
Flood Basalt ◽  
Russian Science ◽  
Southeastern Part ◽  
Dolerite Dyke ◽  
The North ◽  
Anabar Shield ◽  
Dyke Swarms ◽  
Lithospheric Mantle Source

&lt;p&gt;Numerous Mesoproterozoic mafic dyke swarms are known in Siberia. The main intrusions are concentrated in the northern part of the platform and in Sette-Daban (southeastern part of Siberia), and single intrusions are known on all the outcrops of the crystalline basement in the southern part. The largest dyke swarms are located on the Anabar shield and Sette-Daban (with ~1500 Ma and 1000-950 Ma, respectively [1,2]). In the period 1400-1300 Ma, single intrusions are known: 1382 &amp;#177; 2 Ma [3] on the Anabar shield, 1385 &amp;#177; 30 Ma [4] on the Udzha uplift, Listvyanka and Goloustnaya dykes in the south of the platform &amp;#8211; &amp;#160;1350 &amp;#177; 6 Ma [5] and 1338 &amp;#177; 3 Ma [6], respectively. Also, there is the north-trending dolerite dyke at Sette-Daban, which cuts the Lower Riphean sediments of the Uchur Group. The age of this dike was estimated as 1339 &amp;#177; 59 Ma employing Sm-Nd isochrone [7]. We report here a new U-Pb age on apatite, Nd isotopy, and geochemistry for this dolerite dyke.&lt;/p&gt;&lt;p&gt;A typical apatite grain used for the U-Pb dating. On the&amp;#160; Tera-Wasserburg diagram, the regression line intercepts in the lower part the concordia line at 1419 &amp;#177; 15 Ma. The chemical composition of this dyke corresponds to subalkaline basalts (SiO&lt;sub&gt;2&lt;/sub&gt; = 45.6, Na&lt;sub&gt;2&lt;/sub&gt;O+K&lt;sub&gt;2&lt;/sub&gt;O = 3.9 wt%). The rocks correspond (Mg# = 61) to the calc-alkaline series (FeO*/MgO = 1.1) with a low content of Ti&amp;#1054;&lt;sub&gt;2&lt;/sub&gt; (1.25 wt %). A clear negative Nb-Ta anomaly on the multielement diagram suggests an IAB affinity. Incompatible element ratios such as Th/Yb, Nb/Th, Nb/Yb, Zr/Nb also suggest that these dolerites are close to arc-related basalts in composition. Eps(Nd) calculated to the initial value at 1400 Ma shows a slightly negative value -0.2, which is considered as mantle source with contribution from the enriched source.&lt;/p&gt;&lt;p&gt;Geochemical and Nd isotopy characteristics show the affinity of the Sette-Daban dyke with low-Ti series of the Phanerozoic flood basalt provinces (e.g. Karoo, Siberian traps, etc. [8,9]) with the suggestion that these dolerites were generated from a metasomatized subcontinental lithospheric mantle source. Assuming geochemical characteristics and new U-Pb age of the dolerite we propose flood basalt province in the southeast Siberia in Mezoproterozoic (~1400 Ma).&lt;/p&gt;&lt;p&gt;The research was supported by the Russian Science Foundation grant (19-77-10048).&lt;/p&gt;&lt;p&gt;&amp;#160;&lt;/p&gt;

Origin of Fe-Ni-Cu (Co) sulfide and Fe-Ti oxide minerals in the c. 1.77 Ga dolerite dyke, Singhbhum Craton (eastern India)

2021 ◽  
pp. SP518-2021-46
Author(s):  
Arnab Dey ◽  
Sisir K. Mondal
Keyword(s):  
Dyke Swarm ◽  
Sulfide Liquid ◽  
Eastern India ◽  
Content Type ◽  
Dolerite Dyke ◽  
Singhbhum Craton ◽  
Ti Oxides ◽  
Supplementary Material ◽  
Oxide Minerals ◽  
Dyke Swarms

AbstractDolerite dyke swarms are widespread within the Singhbhum Craton (eastern India) that emplaced from the Neoarchean to Paleoproterozoic era just after the stabilization of crust before c. 3 Ga. These dyke swarms are oriented in NE - SW to NNE - SSW, NW - SE to WNW - ESE, E - W, and N - S directions. The WNW - ESE trending c. 1.77 Ga Pipilia dyke swarm is sampled from the Satkosia area of the Orissa state. The dyke shows a noticeable disparity in terms of the modal proportion and grain size of pyroxenes, plagioclase, Fe-Ti-oxide minerals and texture across the trend. At places the primary silicates are altered to secondary hydrated mineral assemblages of amphibole, chlorite and sericite. Primary silicates are clinopyroxene (augite: Mg# = 65.7 - 82.6; En37-48Fs11-17Wo36-41), orthopyroxene (clinoenstatite: Mg# = 68.5 − 78; En63-70Fs20-29Wo4-5), plagioclase (An11-39Ab44-82Or1-7) and Fe-Ti oxides are titanomagnetite (FeO = 34.38 − 39.50 wt%, Fe2O3 = 48.26 − 56.21 wt%, TiO2 = 5.05 − 9.60 wt%) and ilmenite (FeO = 40.75 − 43.79 wt%, Fe2O3 = 3.54 − 10.03 wt%, TiO2 = 47.82 − 50.87 wt%). Application of two-pyroxene thermometry yields an equilibration temperature range of 1065oC to 978oC, and coexisting titanomagnetite-ilmenite pairs reveal 731.39oC to 573.37oC at the oxygen fugacity (fO2) condition NNO+0.3 to FMQ-1.03. The dyke contains disseminated sulfides at the interstices of Fe-Ti-oxides, and silicates. Major sulfide minerals are pyrite, chalcopyrite, and vaesite; Pyrite-vaesite assemblages occur in association with secondary silicate minerals. Pyrite grains contain variable concentration of Co = 0.01 − 5.70 wt% and Ni = 0.02 − 1.95 wt%. Coexisting vaesite contains Co = 2.42 − 10.44 wt%, Ni = 26.40 − 47.88 wt%, and Fe = 7.32 − 26.55 wt%. Texture, sulfide-silicate assemblage, and presence of low metal/S sulfides such as the pyrite-vaesite assemblage indicate primary Fe-Ni- sulfides (pyrrhotite-pentlandite) that segregated from immiscible sulfide liquid at high temperature is modified by late magmatic/hydrothermal fluid activities. Numerous sulfide-bearing deposits hosted in ultramafic-mafic intrusions of Paleoproterozoic age have been recorded globally and the occurrence of Fe-Ni-sulfides in the c. 1.77 Ga Pipilia dyke swarm in the Singhbhum Craton enhances the exploration potential of this craton in eastern India.Supplementary material at https://doi.org/10.6084/m9.figshare.c.5643989

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