In situ gasification of coal, a natural example: history, petrology, and mechanics of combustion

1982 ◽  
Vol 19 (3) ◽  
pp. 514-523 ◽  
Author(s):  
R. M. Bustin ◽  
W. H. Mathews
Keyword(s):  
Roof Rock ◽  
Vitrinite Reflectance ◽  
Ground Surface ◽  
Coal Ash ◽  
Sharp Decrease ◽  
Upper Jurassic ◽  
Thick Coal Seam ◽  
Roof Rocks ◽  
Roof Support

A 6 m thick coal seam of the Upper Jurassic and Lower Cretaceous Mist Mountain Formation in the southeastern Canadian Cordillera has been burning since 1936. The upper 3 m of coal is being consumed to an estimated depth of 20 m. Temperatures in excess of 1100 °C are locally reached, resulting in the melting of overlying sandstones and shales. The melted and vitrified rocks contain a new suite of minerals, including diopside, anorthite, cristobalite, and tridymite. Underlying the burnt coal ash is a zone of coke averaging about 10 cm thick, which is in turn underlain by unaltered coal.Within the area of combustion three zones can be distinguished: an advance zone, where open cracks are developed at the ground surface; a zone of active combustion, where volatiles driven off the coal burn en route to the surface and at the mouth of vents; and an abandoned zone marked by vents, some of which act as air intakes. Approximately 1000 t/year of coal is consumed, giving an energy release of about 1 MW. The heat generated is carried both forward and upward by convecting gas, thereby coking the coal and baking the roof rock. Little heat is carried downward, as evident from a sharp decrease in vitrinite reflectance below the zone of combustion.The baked roof rocks are brittle and extensively fractured, providing little roof support. The completely fused and scoriaceous rock and welded associated breccias, on the other hand, have greater coherence. This welding hinders roof collapse and thereby assists the passage of gases.

Co-solidification of bauxite residue and coal ash into indurated monolith via ambient geopolymerisation for in situ environmental application

2022 ◽  
Vol 422 ◽  
pp. 126925
Author(s):  
Tuan A.H. Nguyen ◽  
Xingyun Guo ◽  
Fang You ◽  
Narottam Saha ◽  
Songlin Wu ◽  
...  
Keyword(s):  
Bauxite Residue ◽  
Coal Ash ◽  
Environmental Application

scholarly journals Estimating Surface Soil Heat Flux in Permafrost Regions Using Remote Sensing-Based Models on the Northern Qinghai-Tibetan Plateau under Clear-Sky Conditions

2019 ◽  
Vol 11 (4) ◽  
pp. 416 ◽  
Author(s):  
Cheng Yang ◽  
Tonghua Wu ◽  
Jiemin Wang ◽  
Jimin Yao ◽  
Ren Li ◽  
...  
Keyword(s):  
Remote Sensing ◽  
Land Surface ◽  
Surface Soil ◽  
Ground Surface ◽  
Soil Heat Flux ◽  
Parameterization Scheme ◽  
Clear Sky ◽  
Sky Conditions ◽  
Permafrost Regions

The ground surface soil heat flux (G0) quantifies the energy transfer between the atmosphere and the ground through the land surface. However; it is difficult to obtain the spatial distribution of G0 in permafrost regions because of the limitation of in situ observation and complication of ground surface conditions. This study aims at developing an improved G0 parameterization scheme applicable to permafrost regions of the Qinghai-Tibet Plateau under clear-sky conditions. We validated several existing remote sensing-based models to estimate G0 by analyzing in situ measurement data. Based on the validation of previous models on G0; we added the solar time angle to the G0 parameterization scheme; which considered the phase difference problem. The maximum values of RMSE and MAE between “measured G0” and simulated G0 using the improved parameterization scheme and in situ data were calculated to be 6.102 W/m2 and 5.382 W/m2; respectively. When the error of the remotely sensed land surface temperature is less than 1 K and the surface albedo measured is less than 0.02; the accuracy of estimates based on remote sensing data for G0 will be less than 5%. MODIS data (surface reflectance; land surface temperature; and emissivity) were used to calculate G0 in a 10 x 10 km region around Tanggula site; which is located in the continuous permafrost region with long-term records of meteorological and permafrost parameters. The results obtained by the improved scheme and MODIS data were consistent with the observation. This study enhances our understanding of the impacts of climate change on the ground thermal regime of permafrost and the land surface processes between atmosphere and ground surface in cold regions.

scholarly journals Deriving surface soil moisture from reflected GNSS signal observations from a grassland site in southwestern France

2017 ◽  
Author(s):  
Sibo Zhang ◽  
Jean-Christophe Calvet ◽  
José Darrozes ◽  
Nicolas Roussel ◽  
Frédéric Frappart ◽  
...  
Keyword(s):  
Soil Moisture ◽  
Land Surface ◽  
Land Surface Model ◽  
Ground Surface ◽  
Satellite System ◽  
Surface Model ◽  
Global Navigation Satellite ◽  
Grassland Site

Abstract. This work aims to assess the estimation of surface volumetric soil moisture (VSM) using the Global Navigation Satellite System Interferometric Reflectometry (GNSS-IR) technique. Year-round observations were acquired from a grassland site in southwestern France using an antenna consecutively placed at two contrasting heights above the ground surface (3.3 or 29.4 m). The VSM retrievals are compared with two independent reference datasets: in situ observations of soil moisture, and numerical simulations of soil moisture and vegetation biomass from the ISBA (Interactions between Soil, Biosphere and Atmosphere) land surface model. Scaled VSM estimates can be retrieved throughout the year removing vegetation effects by the separation of growth and senescence periods and by the filtering of the GNSS-IR observations that are most affected by vegetation. Antenna height has no significant impact on the quality of VSM estimates. Comparisons between the VSM GNSS-IR retrievals and the in situ VSM observations at a depth of 5 cm show a good agreement (R2 = 0.86 and RMSE = 0.04 m3 m−3). It is shown that the signal is sensitive to the grass litter water content and that this effect triggers differences between VSM retrievals and in situ VSM observations at depths of 1 cm and 5 cm, especially during light rainfall events.

scholarly journals Diurnal, Seasonal and Annual Variation of Microwave Radio Refractivity Gradient over Akure, South West Nigeria

2019 ◽  
pp. 1-11
Author(s):  
Adekunle Titus Adediji ◽  
Joseph Babatunde Dada ◽  
Moses Oludare Ajewole
Keyword(s):  
Rainy Season ◽  
Annual Variation ◽  
Ground Surface ◽  
Local Effect ◽  
Dry Season ◽  
Radio Link ◽  
Wet Season ◽  
Annual Variations ◽  
Microwave Radio

In this study, four years in-situ measurements of atmospheric parameters (pressure, temperature and relative humidity) were carried out. The measurement was by placing an automatic weather station at five different heights: ground surface, 50, 100, 150 and 200 m respectively on a 220 m Nigeria Television Authority TV tower in Akure, South Western Nigeria. The four years Data collected (January 2007 to December 2009 and January to December 2011) were used to compute radio refractivity and its gradient. The local effect of a location/ region cannot but looked into when designing effective radio link, hence the diurnal, seasonal and annual variations of the radio refractivity gradient were studied. Results showed that refractivity gradient steadily increases inthe hour of 8:30 and 9:30 to 18:00 during dry season throughout the years investigated, and decreases two hours in the rainy season than the dry season. The record shows that at 50 m altitude, the maximum and minimum values are 158 N-unit/km around 14:30 and - 286 N-unit/km around 13:30 to 14:00 hrs, LT during the dry and rainy season respectively. Seasonally, refractivity gradient is steeper with greater variability in the dry season months than in the wet season months.

scholarly journals Ground thermal and geomechanical conditions in a permafrost-affected high-latitude rockslide site (Polvartinden, Northern Norway)

2016 ◽  
Author(s):  
Regula Frauenfelder ◽  
Ketil Isaksen ◽  
Jeannette Nötzli ◽  
Matthew J. Lato
Keyword(s):  
Temperature Regime ◽  
Laser Scanning ◽  
Ground Surface ◽  
Failure Zone ◽  
Climate Data ◽  
Conduction Model ◽  
Near Surface ◽  
Northern Norway ◽  
Surface Temperatures

Abstract. In June 2008, a rockslide detached in the northeast facing slope of Polvartinden, a high-alpine mountain in Signaldalen, Northern Norway. Here, we report on the observed and modelled past and present near-surface temperature regime close to the failure zone, as well as on a subsequent simulation of the subsurface temperature regime, and on initial geomechanical mapping based on laser scanning. The volume of the rockslide was estimated to be approximately 500 000 m3. The depth to the actual failure surface was found to range from 40 m at the back of the failure zone to 0 m at its toe. Visible in-situ ice was observed in the failure zone just after the rockslide. Between September 2009 and August 2013 ground surface temperatures were measured with miniature temperature data loggers at fourteen different localities close to the original failure zone along the northern ridge of Polvartinden, and in the valley floor. The results from these measurements and from a basic three-dimensional heat conduction model suggest that the lower altitudinal limit of permafrost at present is at 600–650 m a.s.l., which corresponds to the upper limit of the failure zone. A coupling of our in-situ data with regional climate data since 1958 suggests a general gradual warming and that a period with highest mean near surface temperatures on record ended four months before the Signaldalen rockslide detached. A comparison with a transient permafrost model run at 10 m depth, representative for areas where snow accumulates, strengthen this findings, which are also in congruence with measurements in nearby permafrost boreholes. It is likely that permafrost in and near the failure zone is presently subject to degradation. This degradation, in combination with the extreme warm year antecedent to the rock failure, is seen to have played an important role in the detaching of the Signaldalen rockslide.

Evaluation of a Collagen-Reactive Monomer with Advanced Bonding Durability

2020 ◽  
Vol 99 (7) ◽  
pp. 813-819
Author(s):  
F. Yu ◽  
M.L. Luo ◽  
R.C. Xu ◽  
L. Huang ◽  
W. Zhou ◽  
...  
Keyword(s):  
Sharp Decrease ◽  
Bonding Interface ◽  
Collagenolytic Activity ◽  
High Quality ◽  
Reactive Monomer ◽  
Atomic Force ◽  
One Step ◽  
Bonding Durability ◽  
Hybrid Layers

This study evaluated the use of a new collagen-reactive monomer (CRM), isocyanate-terminated urethane methacrylate precursor, which has covalent affinity to dental collagen, in the formation of dentin-resin bonds and compared it with 2 other dental adhesives. Dentin specimens were bonded with either the CRM-based adhesive (CBA), One-Step (OS; Bisco, Inc.), or a negative adhesive (NA) control and subjected to 24-h storage in water, thermocycling to simulate 1-y clinical function, or a matrix metalloproteinase–mediated aging process. We tested the microtensile bond strength (µTBS), characterized the bonding interface with an atomic force microscope, conducted micro-Raman analysis, and performed leakage tests and in situ zymography. CBA and OS exhibited comparable bonding strength after 24 h ( P > 0.05); however, there was a sharp decrease in µTBS after aging for all except CBA ( P < 0.001). Raman spectra results indicated increased collagen crosslinking and chemical reaction between the adhesive and collagen in the CBA group. CBA achieved high-quality hybridization with collagen, improving mechanical properties and integrity, and decreased the enzyme-mediated degradation of the bonding interface by inhibiting collagenolytic activity. With the promising bonding durability of coapplied CBA, CRM may be the first dental adhesive to provide strong and long-lasting resin-dental collagen bonding without the additional conditioning step. The use of CBA results in high-quality hybrid layers that protect the resin-dentin interface from harmful biological and chemical activities commonly occurring in the oral environment.

Respiratory activity, molar growth yields, and ATP content in an Arthrobacter sp. ammonium-limited chemostat culture

1983 ◽  
Vol 29 (9) ◽  
pp. 1136-1140 ◽  
Author(s):  
I. Cacciari ◽  
D. Lippi ◽  
S. Ippoliti ◽  
W. Pietrosanti
Keyword(s):  
Respiratory Activity ◽  
Chemostat Culture ◽  
Morphological Changes ◽  
Sharp Decrease ◽  
Growth Yields ◽  
Atp Content ◽  
Lower Growth ◽  
Wide Range ◽  
Metabolic Activities

Arthrobacter fluorescens was grown in chemostat culture under ammonium-limited conditions and respiratory activity; molar growth yields and ATP content were determined over a wide range of dilution rates. Within a range of dilution rates between 0.10 h−1 and 0.20 h−1, morphological transition occurred, the ratio of cocci to rods appearing inversely related to growth rate. Molar growth yields for both glucose and ammonium decreased with increasing dilution rates because of the higher intracellular polysaccharide content at the lower growth rates. Different metabolic activities were shown in cocci, in rods, and during morphogenesis. A sharp decrease in in situ and potential oxygen quotient (Q(O2)) and in ATP content was observed in the range of dilution rates in which morphological changes occurred.

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