The Surficial Sediments of Lake Huron

1973 ◽  
Vol 10 (2) ◽  
pp. 226-271 ◽  
Author(s):  
R. L. Thomas ◽  
A. L. Kemp ◽  
C. F. M. Lewis

On the basis of extensive sampling and echo sounding, three major lithological units are recognized in the main basin of Lake Huron: (1) glacial till and bedrock; (2) glaciolacustrine clay; and (3) postglacial mud. Sand is a lesser unit in the Huron surficial sediments. Owing to the wide range in bathymetric complexity, postglacial muds occur in basins of three distinct types:Type A. Regular basins in which mud forms a continuous cover.Type B. Irregular basins with undulating bottom topography. Glaciolacustrine clays outcrop in the crests and mud fill occurs in the hollows. Mud cover is greater than 50%.Type C. As for type B but with mud cover less than 50%.The sediment distribution pattern is essentially simple with a natural superposition of sediment units reflecting the glacial and postglacial history of the lake. A bedrock escarpment from Point Clark to Thunder Bay divides Lake Huron into two distinct morphological regions. To the south of the escarpment, the lake has a gentle topography. A second low amplitude escarpment, trending northeast from Ipperwash, divides the southern region of the lake into two large depositional basins. To the north of the major escarpment, the lake is much deeper and has a complex bottom topography. The northern region is separated into two large basins of discontinuous sediment deposition by a rise of glacial sediments trending north from Thunder Bay. The inshore region of Lake Huron and the two escarpments are composed of glacial till and bedrock. The till is overstepped in the deeper water by glaciolacustrine clays which are themselves overstepped by postglacial muds. Postglacial mud accumulation is continuous in the southern basins due to the gentle relief of the lake bottom. In the northern region of the lake, mud accumulation is discontinuous due to the undulating nature of the lake bottom. Mud fills the hollows leaving glaciolacustrine clay exposed at the top of the undulations in this region.The surficial sediments contain variable amounts of quartz, clay minerals, organic carbon, and carbonates. Quartz content is greatest in the coarser inshore sediments while clay minerals and organic carbon are greatest in the liner offshore sediments. Carbonate is low throughout the lake, except along the eastern edge. Blite is the dominant clay mineral with lesser amounts of chlorite and kaolinite.Amphipods, oligochaetes, and chironomids are the major benthic organisms in the Huron sediments. Amphipods are most numerous at a water depth of 70 m, oligochaetes at 140 m, and chironomids in the shallowest depths.The textural characteristics of the sediments, defined by moment measures, can be interpreted as resulting from variable mixing of a clay and a sand end member population.Both end member populations are leptokurtic and asymmetrically skewed due to the introduction of a silt size mode predominantly in the form of a carbonate. The sand end member population is positively skewed and occurs in the inshore zone comprising the coastal nearshore region and the shallow mid-lake regions. The clay end member is negatively skewed and occurs in the depositional basins. Between these two extremes there is a gradual prograding from sand to clay related to a progressive mixing of the two populations. This mixing is believed to be a direct function of declining energy with increasing water depth.Sediment composition reflects both the source materials and the textural properties. The sediments of the southern basin are derived predominantly from glacial tills whereas the composition of the sediments of the northern basin has been substantially modified by dilution with reworked glaciolacustrine clays.

2015 ◽  
Vol 23 (4) ◽  
pp. 461-479 ◽  
Author(s):  
Robie W. Macdonald ◽  
Zou Zou A. Kuzyk ◽  
Sophia C. Johannessen

The sediments of the pan-Arctic shelves contribute an important component to the Arctic Ocean ecosystem by providing a habitat for biota (benthos), a repository for organic and inorganic non-conservative substances entering or produced within the ocean, a reactor and source of transformed substances back to the water column, and a mechanism of burial. Sediments interact with ice, ocean, and the surrounding land over a wide range of space and time scales. We discuss the vulnerability of shelf sediment to changes in (i) organic carbon sources, (ii) pathways of sediment and organic carbon supply, and (iii) physical and biogeochemical alteration (diagenesis). Sedimentary environments of the shelves and basins are likely to exhibit a wide variance in their response to global change because of their wide variation in sediment sources, processes, and metabolic conditions. In particular, the Chukchi and Barents shelves are dominated by inflowing waters from oceans to the south, whereas the interior shelves are more closely tied to terrigenous sources due to river inflow and coastal erosion.


2013 ◽  
Vol 13 (10) ◽  
pp. 28225-28278 ◽  
Author(s):  
D. R. Gentner ◽  
T. B. Ford ◽  
A. Guha ◽  
K. Boulanger ◽  
J. Brioude ◽  
...  

Abstract. Petroleum and dairy operations are prominent sources of gas-phase organic compounds in California's San Joaquin Valley. Ground site measurements in Bakersfield and aircraft measurements of reactive gas-phase organic compounds were made in this region as part of the CalNex (California Research at the Nexus of Air Quality and Climate Change) project to determine the sources contributing to regional gas-phase organic carbon emissions. Using a combination of near-source and downwind data, we assess the composition and magnitude of emissions from these prominent sources that are relatively understudied compared to motor vehicles We also developed a statistical modeling method with the FLEXPART-WRF transport and meteorological model using ground-based data to assess the spatial distribution of emissions in the San Joaquin Valley. We present evidence for large sources of paraffinic hydrocarbons from petroleum extraction/processing operations and oxygenated compounds from dairy (and other cattle) operations. In addition to the small straight-chain alkanes typically associated with petroleum operations, we observed a wide range of branched and cyclic alkanes that have limited previous in situ measurements or characterization in emissions from petroleum operations. Observed dairy emissions were dominated by ethanol, methanol, and acetic acid, and methane. Dairy operations were responsible for the vast majority of methane emissions in the San Joaquin Valley; observations of methane were well-correlated with non-vehicular ethanol, and multiple assessments of the spatial distribution of emissions in the San Joaquin Valley highlight the dominance of dairy operations for methane emissions. The good agreement of the observed petroleum operations source profile with the measured composition of non-methane hydrocarbons in unrefined natural gas associated with crude oil suggests a fugitive emissions pathway during petroleum extraction, storage, or processing with negligible coincident methane emissions Aircraft observations of emission hotspots from operations at oil wells and dairies are consistent with the statistical source footprint determined via transport modeling and ground-based data. At Bakersfield, petroleum and dairy operations each comprised 22–23% of anthropogenic non-methane organic carbon and were each responsible for ~12% of potential precursors to ozone, but their direct impacts as potential SOA precursors were estimated to be minor. A comparison with the California Air Resources Board emission inventory supports the current relative emission rates of reactive organic gases from these sources in the region.


2020 ◽  
Vol 12 (2) ◽  
pp. 1267-1285 ◽  
Author(s):  
Viena Puigcorbé ◽  
Pere Masqué ◽  
Frédéric A. C. Le Moigne

Abstract. The ocean's biological carbon pump (BCP) plays a major role in the global carbon cycle. A fraction of the photosynthetically fixed organic carbon produced in surface waters is exported below the sunlit layer as settling particles (e.g., marine snow). Since the seminal works on the BCP, global estimates of the global strength of the BCP have improved but large uncertainties remain (from 5 to 20 Gt C yr−1 exported below the euphotic zone or mixed-layer depth). The 234Th technique is widely used to measure the downward export of particulate organic carbon (POC). This technique has the advantage of allowing a downward flux to be determined by integrating the deficit of 234Th in the upper water column and coupling it to the POC∕234Th ratio in sinking particles. However, the factors controlling the regional, temporal, and depth variations of POC∕234Th ratios are poorly understood. We present a database of 9318 measurements of the POC∕234Th ratio in the ocean, from the surface down to >5500 m, sampled on three size fractions (∼>0.7 µm, ∼1–50 µm, ∼>50 µm), collected with in situ pumps and bottles, and also from bulk particles collected with sediment traps. The dataset is archived in the data repository PANGAEA® under https://doi.org/10.1594/PANGAEA.911424 (Puigcorbé, 2019). The samples presented in this dataset were collected between 1989 and 2018, and the data have been obtained from published papers and open datasets available online. Unpublished data have also been included. Multiple measurements can be found in most of the open ocean provinces. However, there is an uneven distribution of the data, with some areas highly sampled (e.g., China Sea, Bermuda Atlantic Time Series station) compared to some others that are not well represented, such as the southeastern Atlantic, the south Pacific, and the south Indian oceans. Some coastal areas, although in a much smaller number, are also included in this global compilation. Globally, based on different depth horizons and climate zones, the median POC∕234Th ratios have a wide range, from 0.6 to 18 µmol dpm−1.


2004 ◽  
Vol 5 (1) ◽  
pp. 43
Author(s):  
K.G. PEHLIVANOGLOU ◽  
G. TRONTSIOS ◽  
A. TSIRAMBIDES

The Thermaikos Gulf constitutes the NW part of the North Aegean Sea and is limited eastward from the Chalkidiki Peninsula and westward from the Pieria Prefecture. Its plateau covers an area of 3,500 km2. The mechanisms responsible for the grain size distribution into the Gulf, the clay mineralogy and the chemistry of some bottom sediments from the outer Thermaikos Gulf, are examined. Source mixing during transportation, flocculation, differential settling processes and organic matter appear to be the main mechanisms for the distribution of clay minerals in shallow waters. All grain size fractions studied present a wide range of values confirming the extreme variations of the discharged load and the variability in marine processes. Plagioclases predominate over K-feldspars, while quartz is the most abundant mineral present. In addition, micas, chlorites, amphiboles and pyroxenes exist as primary and/or accessory minerals in all samples. Among clay minerals, illite predominates over smectite and smectite over chlorite (+ kaolinite). The ordered interstratified phase of I/S, with 30-35% S layers, is present in the 2-0.25µm fraction. The randomly interstratified phase of I/S, with 50% S layers, is present in the <0.25& micro; m fraction. On average the clay mineral content of the studied samples is: 48% I, 23% S, 17% Ch (+K) and 12% others for the 2-0.25µm fraction and 50% I, 30% S and 20% Ch (+K) for the <0.25 µm fraction. All these minerals are the weathering products of the rocks from the drainage basins of the rivers flowing into the Gulf, as well as of the Neogene and Quaternary unconsolidated sediments of the surrounding coasts. The terrigenous input, the water mass circulation and, to a lesser extent, the quality of the discharged material and the differential settling of grains, control the grain size distribution within the outer Thermaikos Gulf. The chemical composition of the analysed samples is generally in agreement with their mineral composition and signifies their terrigenous origin presenting discretely clastic character.


1986 ◽  
Vol 23 (9) ◽  
pp. 1442-1449 ◽  
Author(s):  
Daniel J. Conley ◽  
Claire L. Schelske ◽  
Brian G. Dempsey ◽  
Charles D. Campbell ◽  
Teresa L. Newberry

The spatial distribution of biogenic silica (BSi) in the surficial sediments of Lake Michigan is described from Shipek grab samples collected in 1975 and gravity cores obtained in 1983. Significantly smaller surficial BSi concentrations in the 1975 samples were attributed primarily to the inability of a Shipek grab to collect intact surficial sediment samples. Lower concentrations o.f BSi were found in nondepositional and transitional areas of sediment accumulation than in depositional basins. Therefore, BSi accumulation is restricted primarily to the 40% of the lake bottom where sediments are presently accumulating. High concentrations found in Green Bay surficial sediments are related to high productivity in the bay coupled with inputs of new silica from the Fox River. In the open lake, BSi concentrations of surficial sediments in depositional basins appeared to vary inversely with sedimentation rate in that lower BSi concentrations were found in areas with higher sedimentation rates.


1981 ◽  
Vol 38 (1) ◽  
pp. 68-76 ◽  
Author(s):  
Clifford N. Dahm

Removal of dissolved organic carbon (DOC) from water resulting from adsorption and microbial uptake was examined to determine the importance of biotic and abiotic pathways. Physical–chemical adsorption to components of the stream sediment or water and biotic assimilation associated with the microbial population was determined in recirculating chambers utilizing leachate from alder (Alnus rubra). Adsorptive mechanisms were further separated into interactions involving (1) specific clay minerals, (2) amorphous solid phases of hydrous aluminum and iron oxides, and (3) fine particulate organic matter. Physical–chemical adsorptive mechanisms for alder leachate removal exhibited rapid kinetic equilibration between the DOC and solid phases, but only a specific fraction of the DOC, likely containing certain chemical functional groups, was adsorbed. The amorphous aluminum and iron oxides possessed a much higher potential capacity than the clay minerals or fine particulate organics for DOC adsorption. Microbial uptake of DOC from the alder leachate was kinetically slower than adsorptive uptake. However, microbial activity was overall much more effective in the removal and degradation of the total DOC pool leached from alder leaves. Over a 48-h period, 97% of added 14C labeled leachate was removed from solution by adsorption (~ 20%) and microbial utilization (~ 77%). The rate of microbial uptake was 45 μg C/g sediment C∙h−1 or 14 mg C∙m−2∙h−1.


Clay Minerals ◽  
2002 ◽  
Vol 37 (4) ◽  
pp. 699-707 ◽  
Author(s):  
A. Mirabella ◽  
M. Egli ◽  
S. Carnicelli ◽  
G. Sartori

AbstractThe formation of clay minerals was investigated in Spodosols developed in the subalpine belt, with similar exposure, climate and age, but deriving from different parent materials. All the soils were classified as Haplic Podzols and showed the characteristic eluviation and illuviation features of Fe, Al and organic carbon. However, varying parent material lithology led to different clay mineral assemblages in the soil. Smectite could be found in the E horizons of soils developed from granodiorite and tonalite materials. Its formation was strongly dependent on the presence of chlorite in the parent material. If nearly no other 2:1 mineral components, such as chlorite, are present in the lower soil horizons, then a residual micaceous mineral becomes the dominant clay mineral. The latter derives from a mica-vermiculite interstratified mineral.


Soil Research ◽  
1997 ◽  
Vol 35 (6) ◽  
pp. 1301 ◽  
Author(s):  
P. W. Moody ◽  
S. A. Yo ◽  
R. L. Aitken

Total organic carbon (TC) in 32 acidic surface (0–10 cm) soils was divided into 3 fractions (C1, C2, and C3) based on oxidisability by different strengths of KMnO4 (33 mM and 167 mM). With the methodology used, ease of oxidation decreased in the order C1>C2>C3. Several fundamental soil chemical properties were also determined, i.e. ECEC, CEC at pH 6·5 (CEC6·5), slope of the charge curve (ΔCEC), pH buffer capacity, (pHBC), P sorption capacity using a single addition index (PSI150), and content of organically complexed Al. All soils had pH (1:5 water) <6·5, and comprised a wide range of soil types and clay contents. Multiple step-up regression indicated that C fractions were significantly (P < 0·05) correlated with ECEC, ΔCEC, CEC6·5, and pHBC. These results reinforce the critical importance of soil organic matter to the fundamental soil chemical properties of predominantly variable charge soils. The intercorrelations between the various oxidisable C fractions made it difficult to elucidate if degree of oxidisability had any bearing on the reactivity of the organic matter. ECEC was primarily correlated with C1, whereas all C fractions had highly significant (P < 0·01) effects on ΔCEC and pHBC. The fraction which was most difficult to oxidise, C3, made a significant (P < 0·01) contribution to CEC6·5 when combined with clay and ECEC in a multiple regression equation. Generally, one or other of the C fractions was better correlated with the fundamental soil chemical properties than TC. This simple empirical fractionation of soil organic C may therefore be a useful tool for assessing the effects of soil management on these properties.


2020 ◽  
Vol 17 (3) ◽  
pp. 581-595
Author(s):  
Keri L. Bowering ◽  
Kate A. Edwards ◽  
Karen Prestegaard ◽  
Xinbiao Zhu ◽  
Susan E. Ziegler

Abstract. Boreal forests are subject to a wide range of temporally and spatially variable environmental conditions driven by season, climate, and disturbances such as forest harvesting and climate change. We captured dissolved organic carbon (DOC) from surface organic (O) horizons in a boreal forest hillslope using passive pan lysimeters in order to identify controls and hot moments of DOC mobilization from this key C source. We specifically addressed (1) how DOC fluxes from O horizons vary on a weekly to seasonal basis in forest and paired harvested plots and (2) how soil temperature, soil moisture, and water input relate to DOC flux trends in these plots over time. The total annual DOC flux from O horizons contain contributions from both vertical and lateral flow and was 30 % greater in the harvested plots than in the forest plots (54 g C m−2 vs. 38 g C m−2, respectively; p=0.008). This was despite smaller aboveground C inputs and smaller soil organic carbon stocks in the harvested plots but analogous to larger annual O horizon water fluxes measured in the harvested plots. Water input, measured as rain, throughfall, and/or snowmelt depending on season and plot type, was positively correlated to variations in O horizon water fluxes and DOC fluxes within the study year. Soil temperature was positively correlated to temporal variations of DOC concentration ([DOC]) of soil water and negatively correlated with water fluxes, but no relationship existed between soil temperature and DOC fluxes at the weekly to monthly scale. The relationship between water input to soil and DOC fluxes was seasonally dependent in both plot types. In summer, a water limitation on DOC flux existed where weekly periods of no flux alternated with periods of large fluxes at high DOC concentrations. This suggests that DOC fluxes were water-limited and that increased water fluxes over this period result in proportional increases in DOC fluxes. In contrast, a flushing of DOC from O horizons (observed as decreasing DOC concentrations) occurred during increasing water input and decreasing soil temperature in autumn, prior to snowpack development. Soils of both plot types remained snow-covered all winter, which protected soils from frost and limited percolation. The largest water input and soil water fluxes occurred during spring snowmelt but did not result in the largest fluxes of DOC, suggesting a production limitation on DOC fluxes over both the wet autumn and snowmelt periods. While future increases in annual precipitation could lead to increased DOC fluxes, the magnitude of this response will be dependent on the type and intra-annual distribution of this increased precipitation.


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