Stable isotope record of the Eifelian–Givetian boundary Kačák–otomari Event (Middle Devonian) from Hungry Hollow, Ontario, Canada

2008 ◽  
Vol 45 (3) ◽  
pp. 353-366 ◽  
Author(s):  
Peter J. van Hengstum ◽  
Darren R. Gröcke

The Kačák Event in the Middle Devonian (Eifelian–Givetian (E–G) boundary) is a period of apparent global anoxia coincident with widespread deposition of black shale in hemipelagic, pelagic, and some neritic facies. Conodont biostratigraphy in the North American Appalachian Basin has proven to be problematic in precisely demarcating the E–G boundary. In this study, we show that the E–G boundary may be defined more accurately through isotope stratigraphy (δ13C) in conjunction with a conodont faunal change across this boundary, identified as the Kačák– otomari Event. The Canadian Hamilton Group outcropping in Hungry Hollow, Ontario, is a 22 m sedimentary succession spanning the Middle Devonian. Conodont biostratigraphy for this section makes it difficult to define the E–G boundary, but the otomari Event can be detected. High-resolution isotopic analysis of bulk sedimentary carbonate and organic matter for this succession records a significant negative δ13C excursion (δ13Ccarb = up to 2‰; δ13Corg = ∼3.0‰) that is synchronous with total organic carbon (TOC) values up to 12.5%. We identify this negative δ13C excursion as a result of marine anoxia associated with the Kačák–otomari Event and suggest that the excursion is a global event driven by a source of isotopically light carbon, followed by a productivity event, similar to Mesozoic oceanic anoxic events. Such similarities between Devonian and Mesozoic oceanic anoxic events may become more evident with increased high-resolution isotopic and geochemical investigations of Devonian successions.

2011 ◽  
Vol 62 (5) ◽  
pp. 413-433 ◽  
Author(s):  
István Főzy ◽  
Nico Janssen ◽  
Gregory Price

High-resolution ammonite, belemnite and stable isotope record from the most complete Upper Jurassic section of the Bakony Mts (Transdanubian Range, Hungary)This research focuses on the cephalopod fauna and biostratigraphy of the latest Jurassic succession of the Lókút Hill (Bakony Mts, Transdanubia, Hungary). Fossils were collected bed-by-bed from Ammonitico Rosso facies and from the subsequent Biancone type rock. The poorly preserved cephalopods from the lowermost part of the profile, immediately above the radiolarite, may represent a part of the Oxfordian stage. The rich Kimmeridgian ammonite fauna is published for the first time while the formerly illustrated Tithonian fauna is revised. All the successive Kimmeridgian and Early Tithonian Mediterranean ammonite zones can be traced. The highest documented ammonite zone is the Late Tithonian Microcanthum Zone. The beds above yielded no cephalopods. Particular attention was paid to the belemnite fauna of over 120 specimens collected under strict ammonite control. Among the belemnite faunas an Early Tithonian, an early middle Tithonian, a late middle Tithonian, and a latest Tithonian assemblage can be distinguished. Thereby, an association is distinguished in the middle Late Kimmeridgian and one that characterizes the Oxfordian-Kimmeridgian boundary beds. The main difference from previously published belemnite data appears to be that the Hungarian assemblages are impoverished with respect to contemporary faunas from Italy and Spain (Mediterranean Province). An isotopic analysis of the belemnites show that the carbon-isotope data are consistent with carbon-isotope stratigraphies of the Western Tethys and show a decrease in values towards the Jurassic-Cretaceous boundary.


2003 ◽  
Vol 40 (1) ◽  
pp. 99-113 ◽  
Author(s):  
Leanne J Pyle ◽  
Michael J Orchard ◽  
Christopher R Barnes ◽  
Michelle L Landry

A new Lower to Middle Devonian basinal unit of the Road River Group, herein formally named the Deserters Formation, contains argillaceous, crinoidal limestone and black shale deposited in a linear sub-basin of the Ospika Embayment, southern Kechika Trough. The abrupt lateral facies changes in the region, facies thickness, and occurrence of volcanics indicate a period of extensional tectonism. A total of 53 (4–5 kg each) samples from the Deserters Formation yielded 7766 conodont elements assigned to 14 genera representing 33 species. The formation ranges from the Lochkovian (eleanorae Zone, or lower part of the delta Zone of the Cordilleran Region) to Eifelian (australis Zone). The temporal constraints established by conodont biostratigraphy allow correlation to the Grizzly Bear Formation, a regionally restricted Lower to Middle Devonian unit in the Selwyn Basin to the north.


2016 ◽  
Author(s):  
Oliver Friedrich ◽  
Sietske J. Batenburg ◽  
Kazuyoshi Moriya ◽  
Silke Voigt ◽  
Cécile Cournède ◽  
...  

Abstract. Earth’s climate during the Maastrichtian (latest Cretaceous) was punctuated by brief warming and cooling episodes, accompanied by perturbations of the global carbon cycle. Superimposed on a long-term cooling trend, the middle Maastrichtian is characterized by deep-sea warming and relatively high values of stable carbon-isotope ratios, followed by strong climatic variability towards the end of the Cretaceous. A lack of knowledge on the timing of climatic change inhibits our understanding of underlying causal mechanisms. We present an integrated stratigraphy from Site U1403, providing an expanded deep ocean record from the North Atlantic (IODP Expedition 342, Newfoundland Margin). Distinct sedimentary cyclicity suggests that orbital forcing played a major role on depositional processes, which is confirmed by statistical analyses of high resolution elemental data obtained by X-ray fluorescence (XRF) scanning. Astronomical calibration reveals that the investigated interval encompasses seven 405-kyr cycles (Ma4051 to Ma4057) and spans 2.8 Myr directly preceding the Cretaceous/Paleocene (K/Pg) boundary. A high-resolution carbon-isotope record from bulk carbonates allows to identify global trends in the late Maastrichtian carbon cycle. Low-amplitude variations (up to 0.4 ‰), typical for open ocean settings, are compared to the hemipelagic Zumaia section (N-Spain), with a well-established independent cyclostratigraphic framework. Whereas the pre-K/Pg oscillations and the negative values of the Mid-Maastrichtian Event (MME) can be readily discerned in both records, patterns diverge around 67.5 Ma, with Site U1403 more reliably reflecting global climate change. Our new carbon isotope record and the established cyclostratigraphy from Site U1403 may serve as a future reference for detailed studies of late Maastrichtian events in the North Atlantic.


2010 ◽  
Vol 23 (17) ◽  
pp. 4608-4618 ◽  
Author(s):  
Norel Rimbu ◽  
Gerrit Lohmann

Abstract The variability of an annual resolution deuterium time series from central Greenland is investigated in connection with the variability in the frequency of daily atmospheric circulation patterns in the North Atlantic region. Statistical analysis reveals that a large part of the decadal variability of the deuterium isotope record is related to decadal variability in the frequency of several identified daily circulation patterns. The study shows that these circulation patterns induce variations in the deuterium record by altering where isotopic fractionation occurs, mainly during the passage of the associated air masses over continental areas. The study identifies three significant periodic components in the deuterium isotope record at ∼12, ∼20, and ∼30 yr. It also shows that the ∼20-yr signal in the deuterium isotope record is related to the variability in the frequency of a winter circulation type. An analysis of six oxygen isotope records from central Greenland reveals decadal variations similar to the deuterium isotope record. The authors argue that high-resolution stable isotope records from Greenland ice cores can be used to obtain information about the frequency of certain daily circulation patterns during past periods.


1970 ◽  
Vol 36 ◽  
pp. 271-273
Author(s):  
B. B. Jones ◽  
B. C. Boland ◽  
R. Wilson ◽  
S. T. F. Engstrom

A high-resolution solar spectrum in the range 2000–2200 Å was obtained in a recent flight of a sunpointing Skylark rocket. This was launched at 04.21 hr UT on April 22, 1969 from Woomera and reached an apogee of 178 km. An optical alignment system operating on the main vehicle pointing system gave a net stabilisation of ±3 arc sec in the position of the solar image relative to the spectrograph slit. The slit, of length 1.0 mm, was set in the north-east quadrant parallel to and 5 arc min from the north/south axis, its lower edge being 1 arc min from the equator. The roll control of ±2.5° was provided entirely by the standard Elliott Bros. type of vehicle stabilisation.


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