Pinwarian (1.50 Ga) volcanism and hydrothermal activity at the eastern margin of the Wakeham Group, Grenville Province, Quebec

2005 ◽  
Vol 42 (10) ◽  
pp. 1749-1782 ◽  
Author(s):  
Louise Corriveau ◽  
Anne-Laure Bonnet
Keyword(s):  
Granulite Facies ◽  
Hydrothermal Activity ◽  
Grenville Province ◽  
Magmatic Arc ◽  
Argillic Alteration ◽  
Supracrustal Belt ◽  
Hydrothermal Alteration Zones ◽  
Continental Magmatic Arc ◽  
Arc Volcano ◽  
Volcanic Belts

Volcanic belts developed along the southeastern continental margin of Laurentia between 1.70 and 1.30 Ga and subsequently metamorphosed at high grade are today largely concealed among gneiss complexes of the Grenville Province. At the eastern end of the Wakeham Group and in the La Romaine Supracrustal Belt to the east, four 1.50 Ga volcanic centres were found among gneissic synvolcanic intrusions typical of the 1.52–1.46 Ga Pinwarian continental magmatic arc. Upper amphibolite- to granulite-facies rhyolitic to dacitic lavas and coarse lapillistone overlie or are intimately associated with arenites typical of the Wakeham Group. Garnetite, ironstone, carbonate rock, calc-silicate rock, and sillimanite-bearing nodules, veins, and gneiss, locally preserving lapilli, are also present. The distribution, paragenesis, and modes of most of these latter units differ from those of normal metasediments but are diagnostic of metamorphosed exhalites and hydrothermal alteration zones. In the La Romaine Supracrustal Belt, they are associated with pyroclastic horizons and a mineralized composite amphibolite unit. Volcanic textures include flow banding, wispy lapilli moulding fragmented lapilli and rounded lapilli with quartz-feldspar mosaics (filled vesicles), and in situ shattering of lapilli. These textures and the presence of advanced argillic alteration point to vesicular volcanism and hydrothermal activity in a subaerial to shallow submarine environment. Rare mafic lapilli attest to coeval mafic magmatism. The pervasive calc-alkaline signature of the eruptive and intrusive felsic to mafic rocks and their distribution are compatible with the development of 1.50 Ga intra-arc volcano-sedimentary belts stemming from the Wakeham Group basin and extending eastward within the Pinwarian continental magmatic arc.

Chemical imprint of highly metamorphosed volcanic-hosted hydrothermal alterations in the La Romaine Supracrustal Belt, eastern Grenville Province, Quebec

2005 ◽  
Vol 42 (10) ◽  
pp. 1783-1814 ◽  
Author(s):  
Anne-Laure Bonnet ◽  
Louise Corriveau ◽  
Marc R La Flèche
Keyword(s):  
Granulite Facies ◽  
Chemical Changes ◽  
Grenville Province ◽  
Mafic Lava ◽  
Shallow Marine ◽  
Alteration Zones ◽  
Magmatic Arc ◽  
Supracrustal Belt ◽  
Heavy Rare Earth Elements ◽  
Continental Magmatic Arc

The La Romaine Supracrustal Belt and the southeastern end of the Wakeham Group in the eastern Grenville Province, Canada, host a series of Pinwarian, 1.50 Ga felsic-dominated volcanic centres metamorphosed at amphibolite to granulite facies during the Grenville orogeny. The centres are interpreted as being related to the emergence of rhyolitic domes in shallow-marine intra-arc basins within the active Pinwarian continental magmatic arc. High-grade metamorphosed hydrothermal alteration zones are intimately associated with pyroclastic deposits composing these volcanic centres and an overlying composite amphibolite unit. They comprise layers of rhyolitic metatuff bearing networks of aluminous nodules and veins, migmatized garnet–biotite–sillimanite gneiss with well-preserved volcanic fragments, and mottled quartz–cordierite gneiss with textures similar to those of vuggy silica facies. Alteration zones of ironstone, carbonate and calc-silicate rocks, garnetite, diopsidite, epidosite, and sulphide mineralization collectively cut across the internal contacts of a composite amphibolite unit inferred to be a mafic lava and sill complex. Lithogeochemical analysis of inferred metamorphosed altered rocks and precursors highlights chemical changes typical of metamorphosed sericitic zones, advanced argillic and silicic zones, and discharge zones characterized by calcic alterations and copper mineralizations. Such zones involve the interaction of hot, very acidic to neutral fluids. Medium to heavy rare-earth elements (REE) and Zr behave as mobile elements in the hydrothermal system as a result of the presence of F-rich fluids. The chemical changes recorded by the various alteration zones share similarities with those observed in high-sulphidation, volcanic-hosted massive sulphide deposits occurring in proximal, shallow-marine, volcanic sequences.

Crustal-scale flexural slip folding during late tectonic amplification of an orogenic boundary perturbation in the Paleoproterozoic Torngat Orogen, northeastern Canada

1997 ◽  
Vol 34 (12) ◽  
pp. 1545-1565 ◽  
Author(s):  
M. J. Van Kranendonk ◽  
R. J. Wardle
Keyword(s):  
Shear Zone ◽  
Plate Boundary ◽  
Granulite Facies ◽  
Boundary Perturbation ◽  
Magmatic Arc ◽  
Tectonic Events ◽  
Deep Crust ◽  
High Grade Metamorphism ◽  
Continental Magmatic Arc ◽  
Northern Segment

Large variations in metamorphic grade over short distances, disparate orientations and diverse kinematics of contemporaneous structures, and a previously unexplained, 90° counterclockwise bend in the orogenic boundary of the amphibolite- to granulite-facies northern segment of the Paleoproterozoic Torngat Orogen are shown to be the result of multiple tectonic events acting upon an orogenic boundary perturbation. The perturbation was initiated when a promontory on the Nain Province margin, composed of a 1910–1885 Ma continental magmatic arc (Burwell domain), indented the Rae Province hinterland during the onset of collisional orogeny at ca. 1870 Ma (Dn+1). Sinistral transpression at ca. 1845–1822 Ma (Dn+2) caused formation of the orogen-parallel Abloviak shear zone and oblique burial of the Nain Province margin beneath a tilted section of the hot, buoyant magmatic arc. Reactivation of the orogen at ca. 1798–1770 Ma (Dn+3) involved crustal-scale flexural slip folding of the perturbation and simultaneous exhumation of the Burwell domain and the previously buried Nain crust across the Komaktorvik shear zone, which represents a sheared, tightened fold train localized along the western limit of thinned Nain crust affected by preorogenic rifting, but which does not represent a fundamental plate boundary. The along-strike heterogeneities in the Torngat Orogen document the influence of geometrical and competency heterogeneities in the colliding margins on subsequent deformation and the fact that heterogeneities in the deep crust persist through high-grade metamorphism.

Hydrothermally altered volcanic rocks metamorphosed at granulite-facies conditions: an example from the Grenville Province

2017 ◽  
Vol 54 (6) ◽  
pp. 622-638 ◽  
Author(s):  
Marisa Hindemith ◽  
Aphrodite Indares ◽  
Stephen Piercey
Keyword(s):  
Hydrothermal Alteration ◽  
Volcanic Rocks ◽  
Granulite Facies ◽  
Metamorphic Overprint ◽  
Grenville Province ◽  
Rock Types ◽  
Argillic Alteration ◽  
New Findings ◽  
Mineral Assemblages ◽  
Liberation Analysis

A 1.2 Ga association of aluminous gneisses, garnetites, and white felsic gneisses of andesitic composition in the southern Manicouagan area (central Grenville Province) provides evidence consistent with protolith formation and hydrothermal alteration in a submarine volcanic environment. In addition to field relations, potential relics of quartz phenocrysts in the aluminous gneisses, revealed by SEM–MLA (scanning electron microscope with a mineral liberation analysis software) imaging, are consistent with a volcanic precursor. Moreover, in these rocks, aluminous nodules and seams of sillimanite are considered to represent metamorphosed hydrothermal mineral assemblages and to reflect former pathways of hydrothermal fluid. These features are preserved despite the Grenvillian granulite-facies metamorphic overprint and evidence of partial melting. In addition, the garnetites are inferred to represent hydrothermally altered products of the white gneisses, based on the gradational contacts between the two rock types. The compositional ranges of minerals are generally similar to those of granulite-facies metapelites, but moderately elevated contents of Mn in garnet from the garnetites, and Zn in spinel from the aluminous gneisses, are consistent with hydrothermal addition of these elements to the protolith. The most prominent alteration trends are an increase in Fe–Mg–Mn from the white gneisses to the aluminous gneisses and the garnetites, and a trend of increasing alumina index in some white gneisses, suggesting mild argillic alteration. The new findings highlight the preservation of early hydrothermal alteration in high-grade metamorphic belts in the Grenville Province, and these altered rocks are potential targets for exploration.

Jurassic Arc: Reconstructing the Lost World of eastern Gondwana

Geology ◽  
2021 ◽  
Author(s):  
Elliot K. Foley ◽  
R.A. Henderson ◽  
E.M. Roberts ◽  
A.I.S. Kemp ◽  
C.N. Todd ◽  
...  
Keyword(s):  
Detrital Zircon ◽  
Tectonic Setting ◽  
Magmatic Arc ◽  
Continental Arc ◽  
Key Factor ◽  
Igneous Activity ◽  
Competing Models ◽  
Juvenile Crust ◽  
Sedimentary Fill ◽  
Continental Magmatic Arc

The tectonic setting of the Australian sector of the eastern Gondwanan margin during the Jurassic and Cretaceous is enigmatic. Whether this involved convergent tectonism and a long-lived continental magmatic arc or rift-related extension unrelated to subduction is debated. The paucity of Australian Jurassic–Cretaceous igneous outcrops makes resolving these competing models difficult. We used the detrital zircon record of the Jurassic–Cretaceous Great Australian Superbasin (GAS) as a proxy for igneous activity. We attribute the persistent magmatism recorded in GAS sedimentary fill throughout the Mesozoic to ca. 95 Ma to continuation of the established Paleozoic continental arc system. The detrital zircon record signals short (~10 m.y.) pulses of elevated Jurassic and Cretaceous magmatic activity and strongly positive εHf values, indicating juvenile crust or mantle-derived magmatism. Margin reconstruction indicates sustained continental growth at rates of at least ~55 km3 km–1 m.y.–1, mainly to the tract now represented by submerged northern Zealandia, due to the retreat of this arc system. We posit that arc retreat was a key factor in rapid crust generation and preservation, and that continental sedimentary systems globally may host cryptic records of juvenile crustal addition that must be considered in estimating crustal growth rates along convergent plate margins.

New age constraints on magmatism and metamorphism in the Morin terrane (Grenville Province, Quebec)

2022 ◽  
Author(s):  
William H Peck ◽  
Matthew P Quinan
Keyword(s):  
Shear Zone ◽  
Granulite Facies ◽  
Western Boundary ◽  
Grenville Province ◽  
Granulite Facies Metamorphism ◽  
Metamorphic History ◽  
Crustal Block ◽  
Two Samples ◽  
Western Side ◽  
Age Constraints

The Morin terrane is an allochthonous crustal block in the southwestern Grenville Province with a relatively poorly-constrained metamorphic history. In this part of the Grenville Province, some terranes were part of the ductile middle crust during the 1.09–1.02 Ga collision of Laurentia with the Amazon craton (the Ottawan phase of the Grenvillian orogeny), while other terranes were part of the orogen’s superstructure. New U-Pb geochronology suggests that the Morin terrane experienced granulite-facies metamorphism during the accretionary Shawinigan orogeny (1.19–1.14 Ga) and again during the Ottawan. Seven zircon samples from the 1.15 Ga Morin anorthosite suite were dated to confirm earlier age determinations, and Ottawan metamorphic rims (1.08–1.07 Ga) were observed in two samples. U-Pb dating of titanite in nine marble samples surrounding the Morin anorthosite suite yielded mixed ages spanning between the Shawinigan and Ottawan metamorphisms (n=7), and predominantly Ottawan ages (n=2). Our results show that Ottawan zircon growth and resetting of titanite ages is spatially heterogeneous in the Morin terrane. Ages with a predominantly Ottawan signature are recognized in the Morin shear zone, which deforms the eastern lobe of the anorthosite, in an overprinted skarn zone on the western side of the massif, and in the Labelle shear zone that marks its western boundary. In the rest of the Morin terrane titanite with Shawinigan ages appear to have been only partially reset during the Ottawan. Further work is needed to better understand the relationship between the character of Ottawan metamorphism and resetting in different parts of the Morin terrane.

Chapter 23: Alteration, Mineralization, and Age Relationships at the Kışladağ Porphyry Gold Deposit, Turkey

2020 ◽  
pp. 467-495
Author(s):  
T. Baker ◽  
S. Mckinley ◽  
S. Juras ◽  
Y. Oztas ◽  
J. Hunt ◽  
...  
Keyword(s):  
Volcanic Rocks ◽  
White Mica ◽  
Western Anatolia ◽  
Low Grade ◽  
Porphyry Deposits ◽  
Magmatic Arc ◽  
Argillic Alteration ◽  
Metamorphic Basement ◽  
Slab Tear ◽  
Roll Back

Abstract The Miocene Kışladağ deposit (~17 Moz), located in western Anatolia, Turkey, is one of the few global examples of Au-only porphyry deposits. It occurs within the West Tethyan magmatic belt that can be divided into Cretaceous, Cu-dominant, subduction-related magmatic arc systems and the more widespread Au-rich Cenozoic magmatic belts. In western Anatolia, Miocene magmatism was postcollisional and was focused in extension-related volcanosedimentary basins that formed in response to slab roll back and a major north-south slab tear. Kışladağ formed within multiple monzonite porphyry stocks and dikes at the contact between Menderes massif metamorphic basement and volcanic rocks of the Beydağı stratovolcano in the Uşak-Güre basin. The mineralized magmatic-hydrothermal system formed rapidly (<400 kyr) between ~14.75 and 14.36 Ma in a shallow (<1 km) volcanic environment. Volcanism continued to at least 14.26 ± 0.09 Ma based on new age data from a latite lava flow at nearby Emiril Tepe. Intrusions 1 and 2 were the earliest (14.73 ± 0.05 and 14.76 ± 0.01 Ma, respectively) and best mineralized phases (average median grades of 0.64 and 0.51 g/t Au, respectively), whereas younger intrusions host progressively less Au (Intrusion 2A: 14.60 ± 0.06 Ma and 0.41 g/t Au; Intrusion 2 NW: 14.45 ± 0.08 Ma and 0.41 g/t Au; Intrusion 3: 14.39 ± 0.06 and 14.36 ± 0.13 Ma and 0.19 g/t Au). A new molybdenite age of 14.60 ± 0.07 Ma is within uncertainty of the previously published molybdenite age (14.49 ± 0.06 Ma), and supports field observations that the bulk of the mineralization formed prior to the emplacement of Intrusion 3. Intrusions 1 and 2 are altered to potassic (biotite-K-feldspar-quartz ± magnetite) and younger but deeper sodic-calcic (feldspar-amphibole-magnetite ± quartz ± carbonate) assemblages, both typically pervasive with disseminated to veinlet-hosted pyrite ± chalcopyrite ± molybdenite and localized quartz-feldspar stockwork veinlets and sodic-calcic breccias. Tourmaline-white mica-quartz-pyrite alteration surrounds the potassic core both within the intrusions and outboard in the volcanic rocks. Tourmaline was most strongly developed on the inner margins of the tourmaline-white mica zone, particularly along the Intrusion 1 volcanic contact where it formed breccias and veins, including Maricunga-style veinlets. Field relationships show that the early magmatic-hydrothermal events were cut by Intrusion 2A, which was then overprinted by Au-bearing argillic (kaolinite-pyrite ± quartz) alteration, followed by Intrusion 3 and late-stage, low-grade to barren argillic and advanced argillic alteration (quartz-pyrite ± alunite ± dickite ± pyrophyllite). Gold deportment changes with each successive hydrothermal event. The early potassic and sodic-calcic alteration controls much of the original Au distribution, with the Au dominantly deposited with feldspar and lesser quartz and pyrite. Tourmaline-white mica and argillic alteration events overprinted and altered the early Au-bearing feldspathic alteration and introduced additional Au that was dominantly associated with pyrite. Analogous Au-only deposits such as Maricunga, Chile, La Colosa, Colombia, and Biely Vrch, Slovakia, are characterized by similar alteration styles and Au deportment. The deportment of Au in these Au-only porphyry deposits differs markedly from that in Au-rich porphyry Cu deposits where Au is typically associated with Cu sulfides.

New insights into the geologic evolution of the Grenvillian Trenton Prong inlier, Central Appalachian Piedmont, USA

2020 ◽  
Vol 57 (7) ◽  
pp. 840-854
Author(s):  
Richard A. Volkert
Keyword(s):  
Tectonic Setting ◽  
Hanging Wall ◽  
Sediment Source ◽  
Slow Cooling ◽  
Grenville Province ◽  
Magmatic Arc ◽  
Metamorphic History ◽  
Arc Setting ◽  
Appalachian Piedmont ◽  
Back Arc

New geochemical and 40Ar/39Ar hornblende and biotite data from the Grenvillian Trenton Prong inlier provide the first constraints for the identification of lithotectonic units, their tectonic setting, and their metamorphic to post-metamorphic history. Gneissic tonalite, diorite, and gabbro compose the Colonial Lake Suite magmatic arc that developed along eastern Laurentia prior to 1.2 Ga. Spatially associated low- and high-TiO2 amphibolites were formed from island-arc basalt proximal to the arc front and mid-ocean ridge basalt-like basalt in a back-arc setting, respectively. Supracrustal paragneisses include meta-arkose derived from a continental sediment source of Laurentian affinity and metagraywacke and metapelite from an arc-like sediment source deposited in a back-arc basin, inboard of the Colonial Lake arc. The Assunpink Creek Granite was emplaced post-tectonically as small bodies of peraluminous syenogranite produced through partial melting of a subduction-modified felsic crustal source. Prograde mineral assemblages reached granulite- to amphibolite-facies metamorphic conditions during the Ottawan phase of the Grenvillian Orogeny. Hornblende 40Ar/39Ar ages of 935–923 Ma and a biotite age of 868 Ma record slow cooling in the northern part of the inlier following the metamorphic peak. Elsewhere in the inlier, biotite 40Ar/39Ar ages of 440 Ma and 377–341 Ma record partial to complete thermal resetting or new growth during the Taconian and Acadian orogens. The results of this study are consistent with the Trenton Prong being the down-dropped continuation of the Grenvillian New Jersey Highlands on the hanging wall of a major detachment fault. The Trenton Prong therefore correlates to other central and northern Appalachian Grenvillian inliers and to parts of the Grenville Province proper.

scholarly journals Petrogenesis and U-Pb and Sm-Nd geochronology of the Taquaral granite: record of an orosirian continental magmatic arc in the region of Corumba - MS

2015 ◽  
Vol 45 (3) ◽  
pp. 431-451 ◽  
Author(s):  
Letícia Alexandre Redes ◽  
Maria Zélia Aguiar de Sousa ◽  
Amarildo Salina Ruiz ◽  
Jean-Michel Lafon
Keyword(s):  
Geochemical Data ◽  
Alkaline Magmatism ◽  
Alluvial Deposits ◽  
Mato Grosso ◽  
Microgranular Enclave ◽  
Magmatic Arc ◽  
Rock Types ◽  
High K ◽  
Continental Magmatic Arc ◽  
Shrimp Zircon

The Taquaral Granite is located on southern Amazon Craton in the region of Corumbá, westernmost part of the Brazilian state of Mato Grosso do Sul (MS), near Brazil-Bolivia frontier. This intrusion of batholitic dimensions is partially covered by sedimentary rocks of the Urucum, Tamengo Bocaina and Pantanal formations and Alluvial Deposits. The rock types are classified as quartz-monzodiorites, granodiorites, quartz-monzonites, monzo and syenogranites. There are two groups of enclaves genetically and compositionally different: one corresponds to mafic xenoliths and the second is identified as felsic microgranular enclave. Two deformation phases are observed: one ductile (F1) and the other brittle (F2). Geochemical data indicate intermediate to acidic composition for these rocks and a medium to high-K, metaluminous to peraluminous calk-alkaline magmatism, suggesting also their emplacement into magmatic arc settings. SHRIMP zircon U-Pb geochronological data of these granites reveals a crystallization age of 1861 ± 5.3 Ma. Whole rock Sm-Nd analyses provided εNd(1,86 Ga) values of -1.48 and -1.28 and TDM model ages of 2.32 and 2.25 Ga, likely indicating a Ryacian crustal source. Here we conclude that Taquaral Granite represents a magmatic episode generated at the end of the Orosirian, as a part of the Amoguija Magmatic Arc.

scholarly journals Geochemical Significance of Clay Minerals and Elements in Paleogene Sandstones in the Center of the Northern Margin of the Qaidam Basin, China

Minerals ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 505 ◽  
Author(s):  
Guoqiang Sun ◽  
Meng Wang ◽  
Jiajia Guo ◽  
Yetong Wang ◽  
Yongheng Yang
Keyword(s):  
Clay Minerals ◽  
Chemical Weathering ◽  
Qaidam Basin ◽  
Sedimentary Environment ◽  
Climatic Conditions ◽  
Northern Margin ◽  
Magmatic Arc ◽  
Average Value ◽  
Geochemical Significance ◽  
Continental Magmatic Arc

The average thickness of Paleogene sandstones reaches about 3000–4000 m at the northern margin of the Qaidam Basin. However, the provenance and sedimentary environment of these sandstones are uncertain; thus, more comprehensive research is needed. Integrated research is conducted on the provenance and weathering process based on petrographic characteristics, clay minerals, and geochemical compositions of sandstones in the center of the northern Qaidam Basin. The results of lithofacies analysis show that the Paleogene sandstones were mainly derived from an active continental magmatic arc, subduction accretion, or a fold-thrust belt. The average illite content in the Paleogene clay minerals is more than 50%, followed by chlorite and smectite, which reflect climatic and environmental characteristics that were arid to semi-arid, whereas the characteristics of carbon–oxygen isotopes reveal a mainly freshwater sedimentary environment. The corrected chemical index of alteration (CIAcorr) is between 56.3 and 75.7, with an average value of 66.5. These results indicate that the provenance of the Paleogene sandstones in the center of the northern Qaidam Basin mainly formed under cold and dry climatic conditions and experienced limited chemical weathering with a small amount that underwent intermediate chemical weathering under warm and humid conditions.

scholarly journals Ore Formation During Jurassic Subduction of the Tethys Along the Eurasian Margin: Constraints from the Kapan District, Lesser Caucasus, Southern Armenia

2019 ◽  
Vol 114 (7) ◽  
pp. 1251-1284 ◽  
Author(s):  
Johannes Mederer ◽  
Robert Moritz ◽  
Massimo Chiaradia ◽  
Richard Spikings ◽  
Jorge E. Spangenberg ◽  
...  
Keyword(s):  
Middle Jurassic ◽  
Late Jurassic ◽  
Ore Deposits ◽  
Sulfide Deposit ◽  
Short Time Interval ◽  
Ore Formation ◽  
Magmatic Arc ◽  
Argillic Alteration ◽  
Lesser Caucasus ◽  
Host Rocks

Abstract The Kapan mining district in the southernmost Lesser Caucasus is one of the few locations along the central Tethyan metallogenic belt where ore-forming processes were associated with magmatic arc growth during Jurassic Tethys subduction along the Eurasian margin. Three ore deposits of the Kapan district were investigated in this study: Centralni West, Centralni East, and Shahumyan. The ore deposits are hosted by Middle Jurassic andesitic to dacitic volcanic and volcaniclastic rocks of tholeiitic to transitional affinities below a late Oxfordian unconformity, which is covered by calc-alkaline to transitional Late Jurassic-Early Cretaceous volcanic rocks interlayered with sedimentary rocks. The mineralization consists of veins, subsidiary stockwork, and partial matrix replacement of breccia host rocks, with chalcopyrite, pyrite, tennantite-tetrahedrite, sphalerite, and galena as the main ore minerals. Centralni West is a dominantly Cu deposit, and its host rocks are altered to chlorite, carbonate, epidote, and sericite. At Centralni East, Au is associated with Cu, and the Shahumyan deposit is enriched in Pb and Zn as well as precious metals. Both deposits contain high-sulfidation mineral assemblages with enargite and luzonite. Dickite, sericite, and diaspore prevail in altered host rocks in the Centralni East deposit. At the Shahumyan deposit, phyllic to argillic alteration with sericite, quartz, pyrite, and dickite is dominant with polymetallic veins, and advanced argillic alteration with quartz-alunite ± kaolinite and dickite is locally developed. The lead isotope composition of sulfides and alunite (206Pb/204Pb = 18.17–18.32, 207Pb/204Pb = 15.57–15.61, 208Pb/204Pb = 38.17–38.41) indicates a common metal source for the three deposits and suggests that metals were derived from magmatic fluids that were exsolved upon crystallization of Middle Jurassic intrusive rocks or leached from Middle Jurassic country rocks. The δ18O values of hydrothermal quartz (8.3–16.4‰) and the δ34S values of sulfides (2.0–6.5‰) reveal a dominantly magmatic source at all three deposits. Combined oxygen, carbon, and strontium isotope compositions of hydrothermal calcite (δ18O = 7.7–15.4‰, δ13C = −3.4−+0.7‰, 87Sr/86Sr = 0.70537–0.70586) support mixing of magmatic-derived fluids with seawater during the last stages of ore formation at Shahumyan and Centralni West. 40Ar/39Ar dating of hydrothermal muscovite at Centralni West and of magmatic-hydrothermal alunite at Shahumyan yield, respectively, a robust plateau age of 161.78 ± 0.79 Ma and a disturbed plateau age of 156.14 ± 0.79 Ma. Re-Os dating of pyrite from the Centralni East deposit yields an isochron age of 144.7 ± 4.2 Ma and a weighted average age of the model dates of 146.2 ± 3.4 Ma, which are younger than the age of the immediate host rocks. Two different models are offered, depending on the reliability attributed to the disturbed 40Ar/39Ar alunite age and the young Re-Os age. The preferred interpretation is that the Centralni West Cu deposit is a volcanogenic massive sulfide deposit and the Shahumyan and Centralni East deposits are parts of porphyryepithermal systems, with the three deposits being broadly coeval or formed within a short time interval in a nascent magmatic arc setting, before the late Oxfordian. Alternatively, but less likely, the three deposits could represent different mineralization styles successively emplaced during evolution and growth of a magmatic arc during a longer time frame between the Middle and Late Jurassic.

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