Eocene shoshonitic mafic dykes intruding the Monashee Complex, British Columbia: a petrogenetic relationship with the Kamloops Group volcanic sequence?

2005 ◽  
Vol 42 (1) ◽  
pp. 11-24 ◽  
Author(s):  
Matthew G Adams ◽  
David R Lentz ◽  
Cliff SJ Shaw ◽  
Paul F Williams ◽  
Douglas A Archibald ◽  
...  

The newly named Three Valley Suite (TVS) kersantite lamprophyre to shoshonitic mafic dykes of the Monashee Complex are inferred to be hypabyssal feeder dykes to an alkaline to calc-alkaline volcanic suite related to the Kamloops Group. These dykes were emplaced in a subvertical north-trending orientation coincident with inferred Eocene crustal extension (~50.0 Ma), based on the flat 40Ar/39Ar step-heating plateau of contact-metamorphic muscovite on the margin of a TVS dyke. These weakly altered mafic dykes are fine grained with phenocrysts (0.5–2.0 mm) of phlogopite, augite, amphibole, and olivine (pseudomorphed by clays), rare labradorite, and both primary and secondary carbonates set in a fine-grained groundmass of similar mineralogy consistent with their classification as plagioclase-bearing potassic diorite to kersantite lamprophyre. The dykes are weakly silica-undersaturated and alkalic (2.8 wt.% K2O, 7.7 wt.% MgO), with high large ion lithophile element contents (~300 times primitive mantle) and elevated high-field-strength element contents, with a prominent negative Nb (Ta) anomaly, and have radiogenic Nd and Sr isotopic signatures; these geochemical attributes are consistent with a calc-alkaline shoshonitic affinity. Therefore, it is inferred that the subducting oceanic plate influenced subcrustal mantle wedge metasomatism in the region. Decompression partial melting of this metasomatised lithospheric mantle was initiated by coupled rapid unroofing, regional trans pression, slab rollback, and slab window development to the south. The TVS is similar to the mafic volcanic rocks within the nearby Eocene volcanic rocks, suggesting that these dykes represent the feeder system to a volcanic field that is now eroded, i.e., a broad-terrane association.

Geosciences ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 88
Author(s):  
Vasilios Melfos ◽  
Panagiotis Voudouris ◽  
Todor Serafimovski ◽  
Goran Tasev

The Plavica Au-Ag-Cu porphyry and high sulfidation (HS) epithermal deposit is located at the Kratovo–Zlatovo volcanic field in Eastern Former Yugoslavian Republic of Macedonia. In this study, new fluid inclusions data provide additional evidence of the presence of a porphyry style mineralization which is associated with an overlain HS epithermal deposit. The Oligocene–Miocene magmatic rocks have a calc–alkaline to high-K calc–alkaline affinity and consist of sub-volcanic intrusions and volcanic rocks. Previous studies distinguished four alteration types: (a) Sericitic, (b) advanced argillic, (c) silicification, and (d) propylitic alteration. Fluid inclusions showed an early magmatic brine in porphyry style veins with high salinity (33–57 wt% NaCl equiv.), which coexists with a vapor rich fluid with lower salinity (14–20 wt% NaCl equiv.), at temperatures 380–500 °C, under boiling conditions. At shallower depths, the fluid inclusions demonstrate various HS–epithermal deposits which were formed by moderate to low salinity (3–14 wt% NaCl equiv.) hydrothermal fluids at lower temperatures from 200 to 300 °C.


1979 ◽  
Vol 16 (5) ◽  
pp. 1041-1059 ◽  
Author(s):  
C. Alsac ◽  
M. Latulippe

The Archean metavolcanic formations of the Malartic Group in Abitibi, northwestern Quebec (Canada), are several kilometres thick and made up of lavas and pyroclastic rocks, a large part of which are of submarine origin with pillows and hyaloclastites.The mafic phases, with ultramafic material (komatiites), dominate at the base of the unit, the felsitic flows and other derived material, locally associated with copper and zinc sulphides, are located towards the summit of the unit.The regional metamorphism of greenschist and locally amphibolite–almandine facies, has destroyed the magmatic paragenesis; on the other hand, the original textures and structures are generally well preserved.A geochemical study of major elements was carried out on 67 well chosen fine-grained lavas. These were retained for analysis after thin section examination showed them to be nonporphyritic, homogeneous, with a minimum of alteration, and a lack of secondary fillings of amygdales and microfissures. This study led to the following conclusions:(1) The original composition of the volcanic rocks of the Malartic Group is still identifiable in spite of the modification in the content of Na, K, Ca, S, H2O, CO2 and to a lesser degree of Mg and Fe.(2) The variable percentages, generally high in Na and low in K, give to this volcanic group a spilitic characteristic; this may simply be an accentuation of an original tendency for series poor in K.(3) Apart from the ultramafic flows and certain magnesian basalts for which a komatiitic relationship is considered, the Malartic volcanism has magmatic characteristics comparable to those of volcanic island arcs. It begins with dominantly mafic extrusions with a tholeiitic composition poor in K. It continues in the upper Malartic with eruptions in which felsitic phases, locally associated with copper–zinc mineralization, become more abundant; these products seem to belong to two different magmatic series: one tholeiitic, the other calc-alkaline, both poor in K. The phases of these two magmatic series are spatially tightly imbricated.


Author(s):  
Paolo Di Giuseppe ◽  
Samuele Agostini ◽  
Gianfranco Di Vincenzo ◽  
Piero Manetti ◽  
Mehmet Yilmaz Savaşçın ◽  
...  

AbstractAnatolia is characterised by a complex geodynamic evolution, mirrored by a wide spectrum of magmatism. Here, we investigated the timing and the geochemical/isotopic characters of the Miocene to Pliocene volcanism of Sivas–Malatya Region (Central Eastern Anatolia), and its relationships with local and regional tectonics. Na-alkaline basaltic lavas were emplaced during middle Miocene at Sivas (16.7–13.1 Ma), in the North, whilst transition from calc-alkaline to Na-alkaline rocks is observed at Yamadağ and Kepez Dağ volcanic complexes. Calc-alkaline products erupted during early to middle Miocene, and more precisely from 19.5 to 13.6 Ma at Yamadağ and from 16.4 to 13.5 Ma at Kepez Dağ, with final Na-alkaline activity of the Arguvan volcanic field lasting till late Miocene (15.7–10.6 Ma). Volcanism renewed during the Pliocene in the Kangal (5.9–4.0 Ma) volcanic field with the emission of K-alkaline igneous rocks. Mafic calc-alkaline and Na-alkaline rocks partially overlap in age but can be easily distinguished by their petrochemical characters. Mafic calc-alkaline igneous rocks show typical subduction-related petrological and geochemical affinities. They are both two-pyroxene or clinopyroxene and amphibole-bearing rocks, characterised by high LILE/HFSE values, with variable 87Sr/86Sri (0.70396–0.70539) and 143Nd/144Ndi (0.51260–0.51287). Mafic Na-alkaline igneous rocks are characterised by big olivine phenocrysts and show intraplate geochemical flavours, although some LILE depletion with respect to HFSE as well as variable 87Sr/86Sri (0.70347–0.70553) and 143Nd/144Ndi (0.51261–0.51291) isotopic compositions are present. These characteristics are suggestive for the occurrence, at some stage of their genesis, of a possible interaction with subduction-related reservoirs. The Kangal K-alkali basalts still show intraplate-like petrological and geochemical affinities with LILE/HFSE ratios similar to those of the Miocene Na-alkaline rocks, and largely variable 87Sr/86Sri (0.70425–0.70520) and 143Nd/144Ndi (0.51262–0.51277) isotopic compositions, overlapping the arrays observed in the earlier stages of volcanism. A general transition from calc-alkaline to Na-alkaline volcanic rocks is observed with time, according to the evolution of the geodynamics of the Anatolia region. Early to middle Miocene calc-alkaline magmas were derived by partial melting of the mantle wedge delimited by the subduction of the last oceanic branch of Neotethys. The Na-alkaline magmas, on the other hand, were generated within the asthenospheric mantle beneath the slab and migrated through slab tears into the mantle wedge where they mixed with subduction-related components. The subduction-related component decreased with time and transitional magmas are found in the youngest activity of Yamadağ and Kepez Dağ, shortly followed by clear within-plate lavas formed in the Arguvan volcanic field. The appearance of the youngest K-alkaline volcanic rocks in the Kangal basin represents an abrupt change in the magma supply at depth, although continental crustal contamination en-route to the surface played an important role in their genesis.


Author(s):  
Peter W. Lipman

ABSTRACTStructural and topographic relief along the eastern margin of the Rio Grande rift, northern New Mexico, provides a remarkable cross-section through the 26-Ma Questa caldera and cogenetic volcanic and plutonic rocks of the Latir field. Exposed levels increase in depth from mid-Tertiary depositional surfaces in northern parts of the igneous complex to plutonic rocks originally at 3–5 km depths in the S. Erosional remnants of an ash-flow sheet of weakly peralkaline rhyolite (Amalia Tuff) and andesitic to dacitic precursor lavas, disrupted by rift-related faults, are preserved as far as 45 km beyond their sources at the Questa caldera. Broadly comagmatic 26 Ma batholithic granitic rocks, exposed over an area of 20 by 35 km, range from mesozonal granodiorite to epizonal porphyritic granite and aplite; shallower and more silicic phases are mostly within the caldera. Compositionally and texturally distinct granites define resurgent intrusions within the caldera and discontinuous ring dikes along its margins; a batholithic mass of granodiorite extends 20 km S of the caldera and locally grades vertically to granite below its flat-lying roof. A negative Bouguer gravity anomaly (15–20 mgal), which encloses exposed granitic rocks and coincides with boundaries of the Questa caldera, defines boundaries of the shallow batholith, emplaced low in the volcanic sequence and in underlying Precambrian rocks. Palaeomagnetic pole positions indicate that successively crystallised granitic plutons cooled through Curie temperatures during the time of caldera formation, initial regional extension, and rotational tilting of the volcanic rocks. Isotopic ages for most intrusions are indistinguishable from the volcanic rocks. These relations indicate that the batholithic complex broadly represents the source magma for the volcanic rocks, into which the Questa caldera collapsed, and that the magma was largely liquid during regional tectonic disruption.Volcanic and plutonic magmas (1) changed from early high-K calc-alkaline to alkalic prior to caldera eruptions; (2) differentiated to a weakly peralkaline rhyolite and equivalent acmiteartvedsonite granite cap (underlain by calc-alkaline granite) when the caldera formed at 26·5 Ma; then (3) reverted to calc-alkaline compositions. Concentrations of alkalis and minor elements such as Rb, Th, U, Nb, Zr, and Y reached maxima at the caldera stage. The volcanic rocks constitute intermittently quenched samples of upper parts of Questa magma bodies at early stages of crystallisation; in contrast, the comagmatic granitic rocks preserve an integrated record of protracted crystallisation of the magmatic residue as eruptions diminished. Multiple differentiation processes were active during evolution of the Questa magmatic system: crystal fractionation, replenishment by mantle and lower crustal melts of varying chemical and isotopic character, mixing of evolved with more primitive magmas, upper crustal assimilation, and perhaps volatile-transfer processes. As a result, an evolving batholithic cluster of coalesced magma chambers generated diverse assemblages of broadly cogenetic rocks within a few million years. Evolution of the Questa magmatic system and similar high-level Tertiary granitic batholiths nearby in the southern Rocky Mountains provides broad insights into magmatic processes in continental regions such as the overall shapes of batholiths, time and compositional relations between cogenetic volcanic and plutonic rocks, density equilibration of magmas with country rocks, and thermal evolution of continental crust.


Author(s):  
Gejing Li ◽  
D. R. Peacor ◽  
D. S. Coombs ◽  
Y. Kawachi

Recent advances in transmission electron microscopy (TEM) and analytical electron microscopy (AEM) have led to many new insights into the structural and chemical characteristics of very finegrained, optically homogeneous mineral aggregates in sedimentary and very low-grade metamorphic rocks. Chemical compositions obtained by electron microprobe analysis (EMPA) on such materials have been shown by TEM/AEM to result from beam overlap on contaminant phases on a scale below resolution of EMPA, which in turn can lead to errors in interpretation and determination of formation conditions. Here we present an in-depth analysis of the relation between AEM and EMPA data, which leads also to the definition of new mineral phases, and demonstrate the resolution power of AEM relative to EMPA in investigations of very fine-grained mineral aggregates in sedimentary and very low-grade metamorphic rocks.Celadonite, having end-member composition KMgFe3+Si4O10(OH)2, and with minor substitution of Fe2+ for Mg and Al for Fe3+ on octahedral sites, is a fine-grained mica widespread in volcanic rocks and volcaniclastic sediments which have undergone low-temperature alteration in the oceanic crust and in burial metamorphic sequences.


2017 ◽  
Vol 34 (1) ◽  
pp. 45 ◽  
Author(s):  
Elizard González-Becuar ◽  
Efrén Pérez-Segura ◽  
Ricardo Vega-Granillo ◽  
Luigi Solari ◽  
Carlos Manuel González-León ◽  
...  

Plutonic rocks of the Puerta del Sol area, in central Sonora, represent the extension to the south of the El Jaralito batholith, and are part of the footwall of the Sierra Mazatán metamorphic core complex, whose low-angle detachment fault bounds the outcrops of plutonic rocks to the west. Plutons in the area record the magmatic evolution of the Laramide arc and the Oligo-Miocene syn-extensional plutonism in Sonora. The basement of the area is composed by the ca. 1.68 Ga El Palofierral orthogneiss that is part of the Caborca block. The Laramide plutons include the El Gato diorite (71.29 ± 0.45 Ma, U-Pb), the El Pajarito granite (67.9 ± 0.43 Ma, U-Pb), and the Puerta del Sol granodiorite (49.1 ± 0.46 Ma, U-Pb). The younger El Oquimonis granite (41.78 ± 0.32 Ma, U-Pb) is considered part of the scarce magmatism that in Sonora records a transition to the Sierra Madre Occidental magmatic event. The syn-extensional plutons are the El Garambullo gabbro (19.83 ± 0.18 Ma, U-Pb) and the Las Mayitas granodiorite (19.2 ± 1.2 Ma, K-Ar). A migmatitic event that affected the El Palofierral orthogneiss, El Gato diorite, and El Pajarito granite between ca. 68 and 59 Ma might be related to the emplacement of the El Pajarito granite. The plutons are metaluminous to slightly peraluminous, with the exception of El Oquimonis granite, which is a peraluminous two-mica, garnet-bearing granite. They are mostly high-K calc-alkaline with nearly uniform chondrite-normalized REE and primitive-mantle normalized multielemental patterns that are characteristic of continental margin arcs and resemble patterns reported for other Laramide granites of Sonora. The Laramide and syn-extensional plutons also have Sr, Nd and Pb isotopic ratios that plot within the fields reported for Laramide granites emplaced in the Caborca terrane in northwestern and central Sonora. Nevertheless, and despite their geochemical affinity to continental magmatic arcs, the El Garambullo gabbro and Las Mayitas granodiorite are syn-extensional plutons that were emplaced at ca. 20 Ma during development of the Sierra Mazatán metamorphic core complex. The 40Ar/39Ar and K-Ar ages obtained for the El Palofierral orthogneiss, the Puerta del Sol granodiorite, the El Oquimonis granite, and the El Garambullo gabbro range from 26.3 ± 0.6 to 17.4 ± 1.0 Ma and are considered cooling ages associated with the exhumation of the metamorphic core complex.


2021 ◽  
pp. 1-22
Author(s):  
Jia-Hao Jing ◽  
Hao Yang ◽  
Wen-Chun Ge ◽  
Yu Dong ◽  
Zheng Ji ◽  
...  

Abstract Late Mesozoic igneous rocks are important for deciphering the Mesozoic tectonic setting of NE China. In this paper, we present whole-rock geochemical data, zircon U–Pb ages and Lu–Hf isotope data for Early Cretaceous volcanic rocks from the Tulihe area of the northern Great Xing’an Range (GXR), with the aim of evaluating the petrogenesis and genetic relationships of these rocks, inferring crust–mantle interactions and better constraining extension-related geodynamic processes in the GXR. Zircon U–Pb ages indicate that the rhyolites and trachytic volcanic rocks formed during late Early Cretaceous time (c. 130–126 Ma). Geochemically, the highly fractionated I-type rhyolites exhibit high-K calc-alkaline, metaluminous to weakly peraluminous characteristics. They are enriched in light rare earth elements (LREEs) and large-ion lithophile elements (LILEs) but depleted in high-field-strength elements (HFSEs), with their magmatic zircons ϵHf(t) values ranging from +4.1 to +9.0. These features suggest that the rhyolites were derived from the partial melting of a dominantly juvenile, K-rich basaltic lower crust. The trachytic volcanic rocks are high-K calc-alkaline series and exhibit metaluminous characteristics. They have a wide range of zircon ϵHf(t) values (−17.8 to +12.9), indicating that these trachytic volcanic rocks originated from a dominantly lithospheric-mantle source with the involvement of asthenospheric mantle materials, and subsequently underwent extensive assimilation and fractional crystallization processes. Combining our results and the spatiotemporal migration of the late Early Cretaceous magmatic events, we propose that intense Early Cretaceous crust–mantle interaction took place within the northern GXR, and possibly the whole of NE China, and that it was related to the upwelling of asthenospheric mantle induced by rollback of the Palaeo-Pacific flat-subducting slab.


1972 ◽  
Vol 9 (1) ◽  
pp. 36-42 ◽  
Author(s):  
Calvert C. Bristol

X-ray powder diffraction methods, successful in quantitative determination of silicate minerals in fine-grained rocks, have been applied to the determination of calcite, dolomite, and magnesite in greenschist facies meta-volcanic rocks. Internal standard graphs employing two standards (NaCl and Mo) have been determined.Carbonate mineral modes (calcite and dolomite) for 6 greenschist facies meta-volcanic rocks obtained by the X-ray powder method have been compared to normative carbonate mineral contents calculated for the same rocks. This comparison showed a maximum variation of 7.7 wt.% between the X-ray modes and the normative carbonate mineral contents of the rocks. Maximum standard deviation for the X-ray modes of these rocks was equivalent to 4.4 wt.%.


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