Greenschist-facies metamorphism of the Burgess Shale and its implications for models of fossil formation and preservation

2003 ◽  
Vol 40 (1) ◽  
pp. 13-25 ◽  
Author(s):  
Wayne Powell

Metamorphosed silty mudstones of the Burgess Shale and Stephen Shale formations record a poly metamorphic history. An early greenschist-facies event associated with burial by Paleozoic strata produced a nearly ubiquitous bedding-parallel cleavage (S1). Tectonic exhumation during the formation of the southern Canadian Rocky Mountains produced a domainal subgreenschist-facies retrograde overprint in which a high-angle crenulation cleavage (S2) was developed. Whereas all rocks have experienced these two events, the degree of deformation and fossil pre servation varies with position relative to the Cathedral Escarpment. This paleosubmarine cliff resulted in a zone of reduced deformation within adjacent strata by buttressing them during burial and deflecting deformation during orogenesis. Fossil-bearing strata are composed of a typical greenschist assemblage of muscovite–chlorite–quartz–albite, are devoid of clays, and contain an average of 0.28% organic carbon. This typical metamudstone assemblage is consistent with the typical whole-rock composition of these rocks which tends to be richer in K and Al and poorer in Fe relative to the Post-Archean Average Shale. These mineralogical–compositional characteristics suggest that the premetamorphic clay assemblage was likely illite–smectite–kaolinite, with no evidence of highly reactive species such as nontronite or Na-montmorillonite. This is contrary to the required conditions for taphonomic models involving organic preservation due to clay-related suppression of decomposition-related reactions. Metamorphism of the Burgess Shale has also re duced the total organic carbon content to <20% of initial values. This must be considered in any models that involve interpretation of organic carbon in diagenetic processes (e.g., fossil formation and determination of paleoredox conditions).

2018 ◽  
Vol 141 (1) ◽  
Author(s):  
Jianguo Wang ◽  
Daihong Gu ◽  
Wei Guo ◽  
Haijie Zhang ◽  
Daoyong Yang

By correcting both the positive and negative ΔlogR separation resulting from the resistivity in organic-deficient shales, the traditional ΔlogR correlation is modified, validated, and applied to determine the total organic carbon (TOC) content in shale formations. The TOC content is determined once the Fisher distribution, which represents the significance of each model, and Student's t-distribution, which denotes the significance of every variable in the models, have achieved values equal to or higher than their respective threshold values at a confidence level of 95%. Using a total of 45 sets of logging measurements, the newly proposed correlation is found to be able to reproduce the measured TOC values with a root mean-squared absolute difference (RMSAD) of 0.30 wt % and root mean-squared relative difference (RMSRD) of 23.8%, respectively. Uranium concentration, apart from interval transit time and resistivity, is found to be key in determining the TOC content in organic-rich shale without other radioactive minerals. By combining the reading of DGR (i.e., the difference between the spectral gamma ray with the radioactivity and the computed gamma ray without uranium), the traditional ΔlogR technique has now been improved and extended to the negative ΔlogR separation resulting from the resistivity in organic-deficient shale higher than that in organic-rich shale.


1987 ◽  
Vol 59 (2) ◽  
pp. 63-65
Author(s):  
Raina Niskanen ◽  
Väinö Mäntylahti

Drying of three mineral soil samples (clay content 4—58 %, organic carbon content 1—5 %) equilibrated at 75.5 % relative humidity was studied. The soils were dried in an oven at +50°C, +70°C and + 105°C for 4 and 8 hours and in a desiccator over pure concentrated H2SO4 and P2O5. Drying over desiccants for 8 hours removed less water than drying at + 50°C. Drying over desiccants for 3—7 days was as efficient as drying at +70°C, for 14—24 days as efficient as 4 hours of drying at + 105°C. Eight hours of drying at + 105°C seemed to be too drastic, because it caused a greater weight loss in the clay sample of 5 % organic carbon content than did prolonged desiccant-drying. Drying at + 70°Cremoved as much water from fine sand which contained 4 % clay as prolonged desiccant-drying.


2014 ◽  
Vol 675-677 ◽  
pp. 455-459
Author(s):  
Chang Wen Ma ◽  
Hong Yong Xie ◽  
Zhi Guo Sun

The retardation factor (R) expression was deduced for amended double-mode sorption isotherm of perchloroethylene (PCE) in low organic carbon content (0.080~0.090%) aquifer. The retardation effect varied with the solute concentration, the higher the concentration was, the lower the retardation factor. The values of R were determined and compared with the estimation values based on octanol-water partition coefficient (Kow), solubility data of a particular compound and Linear Free-Energy Relationships (LFER). It indicated that there were obvious discrepancy of R among the determinations and estimations. Although how to determine the exact value of R is still questioned, it may be advisable and feasible to understand the retardation effect using batch sorption tests in studying the transport of pollutant in aquifer, especially in mathematical simulation study.


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