The geochemical nature of the igneous rocks of the Sharbot Lake domain, Central Metasedimentary Belt, Ontario

2001 ◽  
Vol 38 (7) ◽  
pp. 1037-1057 ◽  
Author(s):  
T E Smith ◽  
M J Harris ◽  
C H Huang ◽  
P E Holm
Keyword(s):  
Trace Element ◽  
Volcanic Rocks ◽  
Tholeiitic Basalt ◽  
Igneous Rocks ◽  
Igneous Complex ◽  
Low Concentrations ◽  
Granitoid Rocks ◽  
High Concentrations ◽  
Back Arc ◽  
Low K

Two bimodal mafic-silicic suites of igneous rocks, the Sharbot Lake volcanic rocks and the Lavant Igneous Complex, are identified geochemically in the Sharbot Lake domain of the Central Metasedimentary Belt in Ontario, and their genesis and thermotectonic environment are evaluated. The Sharbot Lake volcanic rocks comprise a series of basalts characterized by light rare-earth element (LREE) depletion and relatively high concentrations of Σ Fe2O3, TiO2, MnO, V, and Y, together with rhyolites and silicic pyroclastic rocks. They are intruded by rocks of the Lavant Igneous Complex, which comprises tholeiitic gabbros characterized by LREE enrichment and low concentrations of Σ Fe2O3, TiO2, MnO, V, and Y, and granitoid rocks. The trace element signatures of the mafic rocks of the Sharbot Lake volcanic sequences are most like those of back-arc tholeiitic basalts, and those of the Lavant Igneous Complex are comparable to those of low-K tholeiitic basalt suites. The trace element signatures of the silicic rocks associated with both suites are typical of those formed by crustal melting. Volcanic sequences with trace-element signatures very similar to those of the Sharbot Lake suites have been previously described in the Belmont and Grimsthorpe domains of the Central Metasedimentary Belt, suggesting that the three domains all belong to the Bancroft – Elzevir – Mazinaw – Sharbot Lake superterrane. The lithological, structural, and igneous characteristics of this superterrane suggest that it represents part of a complex back-arc basin underlain by areas of rifted and attenuated continental crust and oceanic crust.

Trace element geochemistry of the Meen-Dempster greenstone belt, Uchi subprovince, Superior Province, Canada: back-arc development on the margins of an Archean protocontinent

2000 ◽  
Vol 37 (7) ◽  
pp. 1021-1038 ◽  
Author(s):  
Pete Hollings ◽  
Greg Stott ◽  
Derek Wyman
Keyword(s):  
Trace Element ◽  
Greenstone Belt ◽  
Volcanic Rocks ◽  
Tholeiitic Basalt ◽  
Pyroclastic Flows ◽  
Trace Element Geochemistry ◽  
Element Geochemistry ◽  
Lree Enrichment ◽  
Compositional Diversity ◽  
Back Arc

Comprehensive trace element analyses of mafic and felsic volcanic rocks from the 2.85-2.74 Ga Meen-Dempster greenstone belt reveal a wide compositional diversity. The ~2.85 Ga Kaminiskag assemblage is dominated by mafic tholeiite characterized by predominantly unfractionated REE (La/Smn = 0.8-1.1). Rare intermediate and felsic pyroclastic flows (SiO2 = 62-74) with moderate to pronounced LREE enrichment are intercalated with the tholeiite. The Kaminiskag assemblage is overlain by the ~2825 Ma Meen assemblage, comprising dominantly dacitic tuffs and pyroclastic breccia, displaying enriched LREE (La/Smn = 3.7-7.2) and moderately fractionated HREE, in conjunction with pronounced negative Nb anomalies. Five distinct suites have been recognized in the ~2740 Ma Confederation assemblage: (1) tholeiitic basalt with flat to smoothly depleted REE, (2) tholeiite with flat to weakly depleted LREE in conjunction with pronounced negative Nb anomalies, (3) Fe-rich basalt with elevated Ti and P contents, LREE enrichment, and fractionated HREE, (4) LREE enriched basalt and andesite with negative Nb anomalies, and (5) dacite and rhyolite with enriched LREE, moderately fractionated HREE, and variable high field strength element anomalies. The geochemistry and geochronology of the Kaminiskag and Meen assemblages are consistent with the formation of an oceanic back arc (Kaminiskag assemblage), which formed the basement for a subduction-related arc complex (Meen assemblage) after a 15 Ma hiatus. The Confederation assemblage is interpreted to represent an Archean back arc, where the complex interplay of mantle sources allows for the eruption of tholeiite, subduction-modified tholeiite, ocean island basalt-like basalt, and subduction-related arc-type volcanic rocks. The recognition of back-arc basins within the Meen-Dempster greenstone belt emphasizes a continuity of crustal growth processes from the Archean to the present day.

The tectonic significance of Ordovician basic igneous rocks in the Southern Uplands, southwest Scotland

1995 ◽  
Vol 132 (5) ◽  
pp. 549-556 ◽  
Author(s):  
E. R. Phillips ◽  
R. P. Barnes ◽  
R. J. Merriman ◽  
J. D. Floyd
Keyword(s):  
Volcanic Rocks ◽  
Accretionary Prism ◽  
Igneous Rocks ◽  
Geochemical Data ◽  
Published Data ◽  
Volcanic Material ◽  
Tectonic Significance ◽  
Arc Setting ◽  
Back Arc ◽  
Midocean Ridge

AbstractIn the northern part of the Southern Uplands, restricted volumes of basic igneous rocks occur at or near the base of the Ordovician sedimentary strata. These rocks have previously been interpreted as ocean-floor tholeiites representative of the subducted Iapetus oceanic plate, preserved as tectonic slivers in a fore-arc accretionary prism. The alternative, back-arc basin model proposed for the Southern Uplands on sedimentological evidence raises questions over the origin of these rocks. New geochemical data and previously published data clearly indicate that the volcanic material does not have a simple single source. The oldest (Arenig) volcanic rocks from the Moffat Shale Group associated with the Leadhills Fault include alkaline within-plate basalts and tholeiitic lavas which possibly display geochemical characteristics of midocean ridge basalts. In the northernmost occurrence, alkaline and tholeiitic basalts contained within the Caradoc Marchburn Formation are both of within-plate ocean island affinity. To the south, in the Gabsnout Burn area, the Moffat Shale Group contains lenticular bodies of dolerite and basalt which have characteristics of island-arc to transitional basalts. This complex association of basaltic volcanic rocks is, at the present time, difficult to reconcile with either a simple fore-arc or back-arc setting for the Southern Uplands. However, the increasing arc-related chemical influence on basic rock geochemistry towards the southeast may tentatively be used in support of a southern arc-terrane, and as a result, a back-arc situation for the Southern Uplands basin. An alternative is that these volcanic rocks may represent the local basement to the basin and include remnants of an arc precursor to the Southern Uplands basin.

The petrology of the basic and intermediate rocks of upper Swat, Pakistan

1973 ◽  
Vol 110 (3) ◽  
pp. 285-300 ◽  
Author(s):  
M. Qasim Jan ◽  
D. R. C. Kempe
Keyword(s):  
Volcanic Rocks ◽  
Age Determination ◽  
Tholeiitic Basalt ◽  
Amphibolite Facies ◽  
Igneous Rocks ◽  
Basalt Magma ◽  
Chemical Analyses

SummaryA series of metamorphosed (amphibolite facies) basic and intermediate igneous rocks from upper Swat, Pakistan, is described, with seven chemical analyses. The rocks intrude ?Palaeozoic metasediments and are partially bordered by other, later, intrusive and volcanic rocks. The group, now represented by, from S–N, epidote amphibolites, amphibolites, noritic and hypersthene gabbros, and quartz diorites, is considered to be derived from a series of plagioclase hypersthenites, norites, hypersthene gabbros, and hypersthene diorites. Variation diagrams are used to show that the series forms a differentiated sequence; FMA and lime-alkali diagrams suggest that it is similar to the rocks of the Garabal Hill–Loch Fyne area of Scotland. Some of the mineralogy of the group is briefly discussed, with five chemical analyses. A K/Ar age determination gives 67 Ma; thus the rocks probably derive from an early Himalayan (Alpine) tholeiitic basalt magma.

Temperature-induced functional deocclusion of thiols inhibitory for sheep erythrocyte K-Cl cotransport

1995 ◽  
Vol 269 (5) ◽  
pp. C1167-C1175 ◽  
Author(s):  
P. K. Lauf ◽  
N. C. Adragna
Keyword(s):  
Kinase Inhibitor ◽  
Sheep Erythrocyte ◽  
Inhibitory Effect ◽  
Temperature Treatment ◽  
Cell Swelling ◽  
Thiol Groups ◽  
Subsequent Removal ◽  
Low Concentrations ◽  
High Concentrations ◽  
Low K

In low-K sheep erythrocytes, K-Cl cotransport is activated by treatment with low concentrations of thiol reagents and by other interventions such as lowering of cellular free cytosolic Mg, hyposmotic cell swelling, the kinase inhibitor staurosporine, and hydroxylamine. High concentrations of N-ethylmaleimide or methylmethane thiolsulfonate reverse the activation through thiol groups and, as shown here, also the stimulation by non-thiol manipulations. The overriding inhibitory sites functionally associated with and different from those of the activating thiols (SHa) were further distinguished by temperature. Treatment with N-ethylmaleimide and its subsequent removal by dithiothreitol, both at 0 degrees C, prevented the inhibitory effect at 37 degrees C and thus the chemical modification of inhibitory thiols (SHi). Whereas stimulation through SHa closely followed the loss of glutathione, inhibition through SHi occurred only in glutathione-depleted cells. The reversal of K-Cl cotransport stimulation by all hitherto known interventions, which is strongest in metabolically depleted cells, suggests that the low temperature-protected SHi constitute crucial sites that, close to the transporter itself or at the cytoskeletal level, become functionally deoccluded upon temperature elevation.

The Ordovician volcanics of the Elmtree–Belledune inlier and their relationship to volcanics of the northern Miramichi Highlands, New Brunswick

1992 ◽  
Vol 29 (7) ◽  
pp. 1430-1447 ◽  
Author(s):  
J. A. Winchester ◽  
C. R. van Staal ◽  
J. P. Langton
Keyword(s):  
New Brunswick ◽  
Volcanic Rocks ◽  
Sedimentary Rocks ◽  
Late Ordovician ◽  
Igneous Rocks ◽  
Volcanic Arc ◽  
Middle Ordovician ◽  
Marginal Basin ◽  
Tectonic Mélange ◽  
Back Arc

An investigation of the geology and chemistry of the basic igneous rocks in the Elmtree and Belledune inliers in northern New Brunswick shows that the bulk of the Middle Ordovician rocks of the ophiolitic Fournier Group are best interpreted as the products of volcanism and sedimentation in an extensive ensimatic back-arc basin southeast of a volcanic arc. The oceanic back-arc-basin igneous rocks form the basement to renewed arc-related basaltic volcanism in late Middle to Late Ordovician time. The Fournier Group is separated from the structurally-underlying, shale-dominated Elmtree Formation of the Tetagouche Group by an extensive tectonic melange, which incorporates lenses of serpentinite, mafic volcanic rocks, and sedimentary rocks of both the Tetagouche and Fournier groups. The mafic volcanic rocks in the Elmtree Formation correlate best with those intercalated with the lithologically similar sediments of the Llandeilian–Caradocian Boucher Brook Formation in the northern Miramichi Highlands. The melange and the present structural amalgamation of the Tetagouche and Fournier groups result from closure of the marginal basin by northward-directed subduction at the end of the Ordovician. Most mafic suites in the Elmtree and Belledune inliers can be chemically correlated with similar suites in the northern Miramichi Highlands, showing that the two areas are not separated by a terrane boundary.

The age and origin of the garnet amphibolite underlying the Thetford Mines ophiolite, Quebec

1981 ◽  
Vol 18 (3) ◽  
pp. 469-486 ◽  
Author(s):  
David Clague ◽  
Jason Rubin ◽  
Russell Brackett
Keyword(s):  
Atlantic Ocean ◽  
Initial Phase ◽  
Tholeiitic Basalt ◽  
Garnet Amphibolite ◽  
Low Concentrations ◽  
Mineral Compositions ◽  
Midocean Ridge ◽  
North And South ◽  
Low K ◽  
Metamorphic Unit

The Thetford Mines ophiolite in southern Quebec is partially underlain by an 800 m thick amphibolite aureole. Rocks in the metamorphic unit grade inward towards the base of the ophiolite from chlorite–muscovite schist, epidote amphibolite, and garnet amphibolite to clinopyroxene-bearing garnet amphibolite closest to the fault contact with the basal tectonized peridotite unit of the ophiolite. The polydeformed metamorphic unit pinches out north and south of Belmina Ridge and is discordant with the overlying tectonized peridotite. Analyses of nine samples show a range of compositions, but the low K2O, P2O5, Rb, Zr, and Sr suggest that the amphibolite protolith was tholeiitic basalt, probably midocean ridge tholeiite.Microprobe mineral compositions determined for coexisting clinopyroxene–garnet–amphibole and garnet–amphibole suggest that amphibolites near the peridotite contact equilibrated at about 850 °C and that the temperatures decreased to about 380 °C 700 m from the contact. Geobarometers based on coexisting clinopyroxene and garnet, and Al and Na partitioning in amphibole yield variable results, but suggest that the pressure during formation of the amphibolite was probably greater than 5 kbar (5 × 105 kPa).Eight conventional K–Ar ages average 488 ± 11 Ma but show some scatter due to inaccuracy of K2O determinations at very low concentrations and, in some samples, possible inherited argon. A single 40Ar/39Ar incremental heating experiment gives concordant plateau and isochron ages of 491 ± 4 and 494 ± 4 Ma, respectively. The best weighted age of 491 ± 3 Ma probably dates the decoupling of the Thetford Mines ophiolite during the initial phase of closing of the Proto-Atlantic Ocean.

Mineralogical composition of and trace-element accumulation in lower Toarcian anoxic sediments: a case study from the Bilong Co. oil shale, eastern Tethys

2015 ◽  
Vol 153 (4) ◽  
pp. 618-634 ◽  
Author(s):  
XIUGEN FU ◽  
JIAN WANG ◽  
XINGLEI FENG ◽  
WENBIN CHEN ◽  
DONG WANG ◽  
...  
Keyword(s):  
Trace Elements ◽  
Trace Element ◽  
Oil Shale ◽  
Volcanic Rocks ◽  
Mineralogical Composition ◽  
Geochemical Data ◽  
Anoxic Sediments ◽  
Marine Influence ◽  
High Concentrations ◽  
Element Enrichment

AbstractThe sediments of organic-rich oil shales in the Bilong Co. area can be correlated with those of the early Toarcian anoxic black-shale events in Europe. The Bilong Co. sediments are rich in trace elements Se, Mo, Cd, As and Ni, and, to a lesser extent, Li, F, V, Co, Cu, Cs, Hg and Bi, in comparison to the upper continental crust. Thirty-two oil shale samples were collected from the Bilong Co. oil shale to evaluate the controlling factors of trace-element enrichment in the lower Toarcian anoxic sediments. Minerals identified in the Bilong Co. oil shale include calcite, quartz, illite, feldspar and dolomite, and trace amounts of siderite, magnesite, halite, haematite, zeolite, amphibole, gypsum, anhydrite, apatite, pyrite, sphalerite, barite and mixed-layer illite/smectite. Mineralogical and geochemical data show that seawater and hydrothermal activities are the dominant influences on the mineralogical composition and elevated trace-element concentrations in the oil shale. The clay minerals, quartz and feldspar in the Bilong Co. oil shale were derived from the Nadi Kangri volcanic rocks. Input of sediment from this source may have led to enrichment of trace elements Li, Cr and Cs in the oil shale. Carbonate minerals and nodular- and framboidal-pyrite are authigenic phases formed from seawater. The enrichment of V, Co, Ni, Cu, Mo, As, Se, Bi and U in the oil shale was owing to marine influence. Barite, sphalerite and fracture-filling pyrites were derived from hydrothermal solutions. High concentrations of F, Zn and Cd were probably derived from hydrothermal fluids.

Tectonic setting and regional correlation of Ordovician metavolcanic rocks of the Casco Bay Group, Maine: evidence from trace element and isotope geochemistry

2004 ◽  
Vol 141 (2) ◽  
pp. 125-140 ◽  
Author(s):  
DAVID P. WEST ◽  
RAYMOND A. COISH ◽  
PAUL B. TOMASCAK
Keyword(s):  
Trace Element ◽  
Continental Crust ◽  
Isotope Geochemistry ◽  
Tectonic Setting ◽  
Volcanic Rocks ◽  
Mafic Magma ◽  
Ocean Basin ◽  
Middle Ordovician ◽  
South Central ◽  
Back Arc

Ordovician metamorphic rocks of the Casco Bay Group are exposed in an approximately 170 km long NE-trending belt (Liberty-Orrington belt) in southern and south-central Maine. Geochemical analysis of rocks within the Spring Point Formation (469±3 Ma) of the Casco Bay Group indicate that it is an assemblage of metamorphosed bimodal volcanic rocks. The mafic rocks (originally basalts) have trace element and Nd isotopic characteristics consistent with derivation from a mantle source enriched by a crustal and/or subduction component. The felsic rocks (originally rhyolites and dacites) were likely generated through partial melting of continental crust in response to intrusion of the mafic magma. Relatively low initial εNd values for both the mafic (−1.3 to +0.6) and felsic (−4.1 to −3.8) rocks suggest interactions with Gander zone continental crust and support a correlation between the Casco Bay Group and the Bathurst Supergroup in the Miramichi belt of New Brunswick. This correlation suggests that elements of the Early to Middle Ordovician Tetagouche-Exploits back-arc basin can be traced well into southern Maine. A possible tectonic model for the evolution of the Casco Bay Group involves the initiation of arc volcanism in Early Ordovician time along the Gander continental margin on the eastern side of the Iapetus Ocean basin. Slab rollback and trenchward migration of arc magmatism initiated crustal thinning and rifting of the volcanic arc around 470 Ma and resulted in the eruption of the Spring Point volcanic rocks in a back-arc tectonic setting.

scholarly journals Evolution of Subduction Dynamics beneath West Avalonia in Middle to Late Ordovician Times

Lithosphere ◽  
2020 ◽  
Vol 2020 (1) ◽  
pp. 1-22
Author(s):  
Pierre Jutras ◽  
J. Brendan Murphy ◽  
Dennis Quick ◽  
Jaroslav Dostal
Keyword(s):  
Trace Element ◽  
Partial Melting ◽  
Volcanic Rocks ◽  
Upper Ordovician ◽  
The North ◽  
Trace Element Contents ◽  
Element Contents ◽  
Arc Setting ◽  
Back Arc ◽  
High Degree

Abstract Middle to Upper Ordovician volcanic rocks in the Arisaig area of Nova Scotia, Canada, constitute the only known record of volcanism in West Avalonia during that interval. Hence, they have been extensively studied to test paleocontinental reconstructions that consistently show Avalonia as a drifting microcontinent during that period. Identification of volcanic rocks with an intermediate composition (the new Seaspray Cove Formation) between upper Darriwilian bimodal volcanic rocks of the Dunn Point Formation and Sandbian felsic pyroclastic rocks of the McGillivray Brook Formation has led to a reevaluation of magmatic relationships in the Ordovician volcanic suite at Arisaig. Although part of the same volcanic construction, the three formations are separated by significant time-gaps and are shown to belong to three distinct magmatic subsystems. The tectonostratigraphic context and trace element contents of the Dunn Point Formation basalts suggest that they were produced by the high-degree partial melting of an E-MORB type source in a back-arc extensional setting, whereas trace element contents in intermediate rocks of the Seaspray Cove Formation suggest that they were produced by the low-degree partial melting of a subduction-enriched source in an arc setting. The two formations are separated by a long interval of volcanic quiescence and deep weathering, during which time the back-arc region evolved from extension to shortening and was eventually onlapped by arc volcanic rocks. Based on limited field constraints, paleomagnetic and paleontological data, this progradation of arc onto back-arc volcanic rocks occurred from the north, where an increasingly young Iapetan oceanic plate was being subducted at an increasingly shallow angle. Partial subduction of the Iapetan oceanic ridge is thought to have subsequently generated slab window magmatism, thus marking the last pulse of subduction-related volcanism in both East and West Avalonia.

Crustal assimilation in the Burnt Lake metavolcanics, Grenville Province, southeastern Ontario, and its tectonic significance

1997 ◽  
Vol 34 (9) ◽  
pp. 1272-1285 ◽  
Author(s):  
T. E. Smith ◽  
P. E. Holm ◽  
N. M. Dennison ◽  
M. J. Harris
Keyword(s):  
Rare Earth ◽  
Trace Element ◽  
Partial Melting ◽  
Continental Crust ◽  
Fractional Crystallization ◽  
Volcanic Rocks ◽  
Lake Area ◽  
Depleted Mantle ◽  
Mafic Magmas ◽  
Back Arc

Three intimately interbedded suites of volcanic rocks are identified geochemically in the Burnt Lake area of the Belmont Domain in the Central Metasedimentary Belt, and their petrogenesis is evaluated. The Burnt Lake back-arc tholeiitic suite comprises basalts similar in trace element signature to tholeiitic basalts emplaced in back-arc basins formed in continental crust. The Burnt Lake continental tholeiitic suite comprises basalts and andésites similar in trace element composition to continental tholeiitic sequences. The Burnt Lake felsic pyroclastic suite comprises rhyolitic pyroclastics having major and trace element compositions that suggest that they were derived from crustal melts. Rare earth element models suggest that the Burnt Lake back-arc tholeiitic rocks were formed by fractional crystallization of mafic magmas derived by approximately 5% partial melting of an amphibole-bearing depleted mantle, enriched in light rare earth elements by a subduction component. The modelling also suggests that the Burnt Lake continental tholeiitic rocks were formed by contamination – fractional crystallization of mixtures of mafic magmas, derived by ~3% partial melting of the subduction-modified source, and rhyolitic crustal melts. These models are consistent with the suggestion that the Belmont Domain of the Central Metasedimentary Belt formed as a back-arc basin by attenuation of preexisting continental crust above a westerly dipping subduction zone.

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